公开(公告)号：US4417025A

公开(公告)日：1983-11-22

申请号：US337335

申请日：1982-01-06

申请人： Hirotaka Toba ,  Masatoshi Mikumo ,  Masahiro Asami

发明人： Hirotaka Toba ,  Masatoshi Mikumo ,  Masahiro Asami

IPC分类号： C08F2/24 ,  C08F251/02 ,  C08G59/02 ,  C08L1/08

CPC分类号： C08F251/02

摘要： A resin composition is prepared by emulsion-polymerizing a cellulose ester and at least one radical-polymerizable unsaturated monomer in the aqueous medium under the presence of a dispersion stabilizer, said cellulose ester having been modified by chemically bonding thereonto a polymeric chain compatible with a polymer obtained from said radical-polymerizable unsaturated monomer.

摘要翻译： 通过在分散稳定剂的存在下在水性介质中将纤维素酯和至少一种可自由基聚合的不饱和单体进行乳液聚合来制备树脂组合物，所述纤维素酯已经通过化学键合在与聚合物相容的聚合物链上进行改性 由所述可自由基聚合的不饱和单体获得。

公开(公告)号：US06232055B1

公开(公告)日：2001-05-15

申请号：US09281075

申请日：1999-03-10

申请人： Katsuhisa Ohzeki ,  Masahiro Asami ,  Takuya Yokokawa ,  Hideaki Naruse

发明人： Katsuhisa Ohzeki ,  Masahiro Asami ,  Takuya Yokokawa ,  Hideaki Naruse

IPC分类号： G03C146

CPC分类号： G03C8/4013 ,  G03C1/0051 ,  G03C7/3835 ,  G03C8/404 ,  G03C2200/03

摘要： Disclosed is a silver halide color photographic photosensitive material in which the photosensitive layer of the photosensitive material comprising a silver halide emulsion, a developing agent and a coupler is put together with the processing layer of a processing material so that these layers are heated to form a color image in the photosensitive material, said silver halide grains in the photosensitive layer having a silver chloride content of 50 mol% or more, wherein (1) the silver halide grains, in which 50% or more of the exterior faces of the grain is made up of a (111) plane, account for 50% or more of the total projected area of the silver halide grains of the emulsion, and the developing agent has a specific molecular structure, or (2) the tabular silver halide grains having an aspect ratio of 2 or more, which have the exterior faces of the grain made up of a (100) plane and a plane of projection of the grain in a shape of a rectangle with a length to width ratio ranging from 1:1 to 1:2, or which have the exterior faces of the grain made up of a (111) plane and a plane of projection in the shape of a hexagon with the ratio of the lengths of the neighboring sides ranging from 1:1 to 1:10, account for 50% or more of the total projected area of the silver halide grains of the emulsion, and the coupler is a pyrazolotriazole coupler having a specific molecular structure.

摘要翻译： 公开了一种卤化银彩色感光材料，其中包含卤化银乳剂，显影剂和成色剂的感光材料的感光层与处理材料的处理层放在一起，使得这些层被加热形成 在感光材料中的彩色图像，感光层中的卤化银颗粒的氯化银含量为50摩尔％以上，其中，（1）其中外观面的50％以上的卤化银颗粒为 由（111）面构成，占乳液的卤化银颗粒总投影面积的50％以上，显影剂具有特定的分子结构，或者（2）具有 纵横比为2以上，其具有由（100）面构成的谷物的外表面和谷物的投影平面，其长度与宽度之比为 1：1至1：2，或者其具有由（111）面构成的颗粒的外表面和具有六边形形状的突起平面，其相邻长度的比例范围为1： 1至1:10，占乳液的卤化银颗粒总投影面积的50％或更多，并且成色剂是具有特定分子结构的吡唑并三唑成色剂。

公开(公告)号：US06228556B1

公开(公告)日：2001-05-08

申请号：US08827253

申请日：1997-03-28

申请人： Masahiro Asami ,  Kazuhiko Matsumoto ,  Toshiki Taguchi

发明人： Masahiro Asami ,  Kazuhiko Matsumoto ,  Toshiki Taguchi

IPC分类号： G03C836

CPC分类号： G03C8/4006 ,  G03C1/0051 ,  G03C1/42 ,  G03C1/49827 ,  G03C5/261 ,  G03C5/263 ,  G03C7/3022 ,  G03C7/413 ,  G03C8/402 ,  G03C8/404 ,  G03C8/4086 ,  G03C2007/3034

摘要： Disclosed is a silver halide color photographic light-sensitive material which is capable of forming an image by: after exposing a light-sensitive material, which comprises a first support having thereon at least one photographic light-sensitive layer comprising a light-sensitive silver halide emulsion, a developing agent, a compound capable of forming a dye upon coupling reaction with an oxidation product of the developing agent and a binder; attaching said light-sensitive material to a processing material, which comprises a second support having thereon a base and/or a base precursor, in such a way that the coated surfaces of the two materials faced each other, in the presence of a small amount of water which corresponds to from {fraction (1/10)} to 1 time water necessary for giving maximum swelling of all coated layers constituting the light-sensitive material and the processing material; and then heating the light-sensitive material and the processing material, wherein at least one said light-sensitive layer contains an emulsion having silver halide grains having a silver chloride content of 50 mol % or more, wherein the silver halide grains are tabular grains having (i) a main outer surface constituted by (100) faces, (ii) having a rectangular shape with adjacent major face (projection plane) edge ratios being from 1:1 to 1:2, and (iii) having an aspect ratio of 2 or more.

摘要翻译： 公开了一种能够通过以下方式形成图像的卤化银彩色照相感光材料：在曝光感光材料之后，该感光材料包括其上具有至少一个包含感光卤化银的照相感光层的第一支持体 乳液，显影剂，能够与显影剂和粘合剂的氧化产物偶联反应形成染料的化合物; 将所述感光材料附着到处理材料上，所述处理材料包括其上具有基底和/或基底前体的第二支撑体，使得两种材料的涂覆表面在少量存在下彼此面对 对于构成感光材料和处理材料的所有涂层的最大溶胀所必需的从{部分（1/10）}到1次水的水; 然后加热感光材料和处理材料，其中至少一个所述感光层含有具有氯化银含量为50摩尔％以上的卤化银颗粒的乳液，其中卤化银颗粒是具有 （i）由（100）面构成的主外表面，（ii）具有相邻主面（投影面）边比例为1:1〜1:2的矩形形状，（iii）纵横比为 2以上。

公开(公告)号：US5457007A

公开(公告)日：1995-10-10

申请号：US274576

申请日：1994-07-13

申请人： Masahiro Asami

发明人： Masahiro Asami

IPC分类号： G03B27/73 ,  G03C5/08 ,  G03C7/00 ,  G03C7/30 ,  G03C7/18 ,  G03C7/384

CPC分类号： G03C7/30 ,  Y10S430/145 ,  Y10S430/146

摘要： The image forming process of the present invention includes subjecting a photosensitive material having at least one dye-forming layer for each of the three primary colors on a support to scanning exposure using light sources modulated in accordance with the image data, thereby reproducing a full color image of quality in which delicate shades in a high density color developed portion of high purity are reproduced stably. For the exposure dynamic range of the photosensitive material that the density of color generation of one dye-forming layer exhibiting the highest sensitivity to the light beam from at least one light source varies beyond the visual threshold with respect to a change of a modulation control minimum unit in the exposure quantity of said at least one light source, said one dye-forming layer is color generated by exposure to the light beam from another light source to which another dye-forming layer exhibits the highest sensitivity such that a variation of the color generation density of said one dye-forming layer may be below said visual threshold.

摘要翻译： 本发明的图像形成方法包括使用根据图像数据调制的光源对具有至少一个染料形成层的感光材料对载体进行扫描曝光，从而再现全色 可以稳定地再现高纯度高密度显色部分的细腻色调的品质图像。 对于感光材料的曝光动态范围，对于来自至少一个光源的光束表现出最高灵敏度的一个染料形成层的颜色产生密度相对于调制控制最小值的变化超出视觉阈值 所述一个染料形成层通过暴露于来自另一个光源的光束而产生颜色，其中另一个染料形成层显示出最高的灵敏度，使得颜色的变化 所述一个染料形成层的产生密度可以低于所述视觉阈值。

公开(公告)号：US5415978A

公开(公告)日：1995-05-16

申请号：US181255

申请日：1994-01-13

申请人： Masahiro Asami ,  Nobuharu Nozaki ,  Yoji Okazaki

发明人： Masahiro Asami ,  Nobuharu Nozaki ,  Yoji Okazaki

IPC分类号： B41J2/525 ,  G03B27/73 ,  G03C1/00 ,  G03C1/10 ,  G03C5/08 ,  G03C7/00 ,  G03C7/30 ,  H04N1/50

CPC分类号： H04N1/50 ,  G03C7/3041 ,  Y10S430/146 ,  Y10S430/164

摘要： An image is formed in a color photosensitive material through scanning exposure by using at least one semiconductor laser excited solid laser including a semiconductor laser, a non-linear optical element and means for controlling the temperature thereof as a light source for producing a laser beam. The laser beam is modulated by an external modulator in accordance with the image to be formed. Among the combinations of photosensitive layers and laser beams, at least two laser beam light sources are such that a laser beam has a wavelength falling within .+-.20 nm from the maximum wavelength in the spectral sensitivity distribution of the corresponding photosensitive layer. Each photosensitive layer has a spectral sensitivity distribution with a peak width of up to 40 nm. The method enables to form an image in a conventional silver halide photosensitive material having spectral sensitivity in the visible region using a cost effective light source, the resulting image having color generated to a satisfactory density, free of a density variation, and hence of high quality.

摘要翻译： 通过使用包括半导体激光器，非线性光学元件的至少一个半导体激光激光固体激光器和用于控制其温度作为用于产生激光束的光源的装置的扫描曝光，在彩色感光材料中形成图像。 激光束根据要形成的图像由外部调制器调制。 在感光层和激光束的组合中，至少两个激光束光源使得激光束的波长在对应的感光层的光谱灵敏度分布中与最大波长相差+/- 20nm。 每个感光层具有峰值宽度高达40nm的光谱灵敏度分布。 该方法能够使用成本有效的光源在可见光区域中具有光谱灵敏度的常规卤化银感光材料形成图像，所得到的图像产生的密度达到令人满意的密度，没有密度变化，因此具有高质量 。

公开(公告)号：US5284743A

公开(公告)日：1994-02-08

申请号：US261447

申请日：1988-10-19

申请人： Naoto Ohshima ,  Masahiro Asami

发明人： Naoto Ohshima ,  Masahiro Asami

IPC分类号： G03C1/035 ,  G03C1/015 ,  G03C1/09 ,  G03C1/26 ,  G03C1/34 ,  G03C7/30

CPC分类号： G03C1/015 ,  G03C1/09 ,  G03C1/26 ,  G03C1/346 ,  G03C2001/0153 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/03576 ,  G03C2001/093 ,  G03C2001/095 ,  G03C2200/33 ,  G03C2200/40 ,  G03C2200/53 ,  G03C7/3022

摘要： A silver halide photographic material comprising at least one photosensitive emulsion layer contains silver halide grains on a support. In the silver halide photographic material, (1) the silver halide grains are prepared in the presence of iridium compounds, (2) the silver halide grains consist of silver chlorobromide which is essentially free of silver iodide, (3) at least 90 mol% of all silver halide from which the silver halide grains are made is silver chloride, (4) the silver halide grains have localized phase in which the silver bromide content exceeds at least 20 mol%, (5) the localized phase is precipitated together with at least 50% of all the iridium which is added during the preparation of the silver halide grains, and (6) the surface of the silver halide grains is chemically sensitized to the extent that the grains are essentially of the surface latent image type.

摘要翻译： 包含至少一个感光乳剂层的卤化银照相材料在载体上含有卤化银颗粒。 在卤化银照相材料中，（1）在铱化合物的存在下制备卤化银颗粒，（2）卤化银颗粒由基本上不含碘化银的氯溴化银组成，（3）至少90mol％ 所有卤化银颗粒由卤化银制成的是氯化银，（4）卤化银颗粒具有溴化银含量超过20摩尔％的局部相，（5）局部相与 在制备卤化银颗粒期间加入的所有铱的至少50％，和（6）卤化银颗粒的表面被化学增感至颗粒基本上是表面潜像型的程度。

公开(公告)号：US5204234A

公开(公告)日：1993-04-20

申请号：US595290

申请日：1990-10-10

申请人： Masahiro Asami

发明人： Masahiro Asami

IPC分类号： G03C1/035 ,  G03C1/08

CPC分类号： G03C1/035 ,  G03C1/08

摘要： There is disclosed a silver halide photographic material having at least one photosensitive emulsion layer containing silver halide emulsion of surface latent image type. The silver halide emulsion comprises high-silver-chloride emulsion grains that have a localized phase containing iron ions in a limited amount. According to the disclosure a silver halide photographic material can be attained that is excellent in rapid processability and high in sensitivity and contrast.

公开(公告)号：US5173395A

公开(公告)日：1992-12-22

申请号：US417618

申请日：1989-10-05

申请人： Masahiro Asami

发明人： Masahiro Asami

IPC分类号： G03C7/407 ,  G03C1/035 ,  G03C7/30 ,  G03C7/392 ,  G03C7/413

CPC分类号： G03C7/3003 ,  G03C7/3041 ,  G03C7/413 ,  G03C2001/03517 ,  G03C2001/03558 ,  Y10S430/164

摘要： A method for forming a color image which comprises developing an imagewise exposed silver halide color photographic material with a color developer containing at least one aromatic primary amine developing agent, wherein said silver halide color photographic material comprises a reflective support, whose transmission density in the red region ranges from 0.2 to 0.9, having thereon at least one light-sensitive emulsion layer containing at least one coupler capable of forming a dye on coupling with an oxidation product of the developing agent and silver chlorobromide grains comprising at least 80 mol % of silver chloride and containing substantially no silver iodide, said support having further provided thereon a dye represented by formula (A): ##STR1## wherein R.sub.101 and R.sub.102 each represents --OR.sub.105, --COOR.sub.105, ##STR2## --COR.sub.105, --CN or --R.sub.107, wherein R.sub.105 and R.sub.106 each represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, and R.sub.107 represents an alkyl group or an alkyl group substituted with a halogen atom, etc.; R.sub.103 and R.sub.104 each represents an alkyl, aralkyl or aryl group substituted with at least one of a sulfo group and a carboxyl group; and L.sub.101 represents a substituted or unsubstituted methine group, and the color developer contains from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/l of chloride ion and from 3.0.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/l of bromide ion.

摘要翻译： 一种形成彩色图像的方法，其包括用含有至少一种芳族伯胺显影剂的显色剂显影成像曝光的卤化银彩色照相材料，其中所述卤化银彩色照相材料包括反射性载体，其透射密度在红色 区域范围为0.2至0.9，其上具有至少一个感光乳剂层，该感光乳剂层含有至少一种能够与显影剂的氧化产物偶联形成染料的成色剂和包含至少80mol％氯化银的氯化银银粒子 并且基本上不含有碘化银，所述载体还在其上提供由式（A）表示的染料：其中R 101和R 102各自表示-OR 105，-COOR 105，-COR 105，-CN或 - R107，其中R105和R106各自表示氢原子，取代或未取代的烷基或取代或未取代的芳基，以及 R107表示烷基或被卤原子取代的烷基等; R 103和R 104各自表示被至少一个磺基和羧基取代的烷基，芳烷基或芳基; L101表示取代或未取代的次甲基，彩色显影剂含有3.5×10-2〜1.5×10-1 mol / l的氯离子和3.0×10-5〜1.0×10-3 mol / l的溴离子。

公开(公告)号：US4879206A

公开(公告)日：1989-11-07

申请号：US290201

申请日：1988-12-27

申请人： Masahiro Asami

发明人： Masahiro Asami

IPC分类号： G03C1/005 ,  G03C1/12 ,  G03C7/30 ,  G03C7/34

CPC分类号： G03C7/3003 ,  G03C7/346 ,  G03C1/0051 ,  G03C1/12 ,  G03C2007/348 ,  G03C7/34

摘要： A silver halide color photographic material which comprises a support having provided thereon at least one silver halide emulsion layer containing a cyan dye image-forming coupler represented by the following general formula (I), wherein the emulsion layer comprises silver bromide grains or silver chloro-bromide grains in which tabular grains having a mean aspect ratio of 5 or more amount to 50% or more based on the total projection area of the whole grains, and which are spectrally sensitized with a cyanine dye of the trimethine or pentamethine type or a merocyanine dye, which dye has a desensitization degree of 10 or more, thereby achieving high sensitivity and excellent fastness of photographic images and ensuring uniform quality in mass production: ##STR1## wherein R.sub.1 and R.sub.2 each represents a substituted or ubsubstituted aliphatic, aromatic or heterocyclic group; R.sub.3 represents a hydrogen atom, a halogen atom, a substituted or unsubstituted aliphatic or aromatic group or an acylamino group, and further R.sub.3 may be non-metallic atomic groups which form with R.sub.2 a nitrogen-containing 5- or 6-membered ring; Y.sub.1 represents a hydrogen atom, or a group which is eliminable upon an oxidative coupling reaction with a developing agent; and n represents 0 or 1; and further the coupler may take a polymeric form, including a dimeric form, via a group represented by R.sub.1, R.sub.2 or Y.sub.1.

摘要翻译： 一种卤化银彩色照相材料，其包括其上提供有至少一个含有由以下通式（I）表示的青色染料影像形成成色剂的卤化银乳剂层的载体，其中乳液层包含溴化银颗粒或氯化银 - 其中平均纵横比为5以上的片状颗粒相对于全谷粒的总投影面积为50％以上，并且用三甲基或五甲氧基型花青染料或部花青素进行光谱增感的溴化物颗粒 染料，该染料的脱敏度为10以上，从而获得高灵敏度和优异的摄影图像牢度，并确保大量生产的均匀质量：其中R 1和R 2各自表示取代或未取代的脂族芳族 或杂环基; R 3表示氢原子，卤素原子，取代或未取代的脂肪族或芳香族基团或酰基氨基，另外R 3可以是与R 2形成含氮的5元或6元环的非金属原子团; Y1表示氢原子，或与显影剂的氧化偶联反应时可除去的基团; n表示0或1; 此外，成色剂可以经由由R 1，R 2或Y 1表示的基团取聚合形式，包括二聚体形式。

公开(公告)号：USH583H

公开(公告)日：1989-02-07

申请号：US503

申请日：1987-01-05

申请人： Masahiro Asami

发明人： Masahiro Asami

IPC分类号： G03C7/26 ,  G03C1/005 ,  G03C1/035 ,  G03C1/12 ,  G03C1/29 ,  G03C1/30

CPC分类号： G03C1/305 ,  G03C1/29

摘要： A silver halide color photographic material having, on a support, at least one light-sensitive emulsion layer containing a silver chlorobromide emulsion (having a chloride content of 80 mol % or less) substantially free of iodide, with the silver chlorobromide emulsion being spectrally sensitized with a combination of at least two kinds of spectral sensitizing dyes having specified formulae, and with the silver chlorobromide emulsion layer being hardened with at least one 1,3,5-triazine derivative having specified formula, whereby achieving inhibition for increase in fog upon long-range preservation thereof as finished goods without attended by decrease in developing speed.