Lithium secondary battery comprising tungsten composite oxide
    41.
    发明授权
    Lithium secondary battery comprising tungsten composite oxide 有权
    包含钨复合氧化物的锂二次电池

    公开(公告)号:US06403258B1

    公开(公告)日:2002-06-11

    申请号:US09533670

    申请日:2000-03-23

    IPC分类号: H01M450

    摘要: In a lithium secondary battery provided with a positive electrode, a negative electrode, and a non-aqueous electrolyte, a tungsten oxide W20O58 or W18O49, or the tungsten oxide to which lithium is added, or a tungsten composite oxide comprising a tungsten oxide containing at least one type of metal element selected from the group consisting of Mn, Cu, V, Cr, Fe, Co, and Ni and having a W20O58-type or W18O49-type crystal structure or the tungsten composite oxide to which lithium is added is used as a positive electrode active material for said positive electrode or a negative electrode active material for said negative electrode.

    摘要翻译: 在设置有正极,负极和非水电解质的锂二次电池中,添加有氧化钨W20O58或W18O49,或者添加有锂的氧化钨,或包含含有氧化钨的钨复合氧化物 使用选自Mn,Cu,V,Cr,Fe,Co和Ni中的至少一种类型的具有W20O58型或W18O49型晶体结构的金属元素或添加了锂的钨复合氧化物 作为所述正极的正极活性物质或所述负极的负极活性物质。

    Hydrogen absorbing alloy electrode, method of fabricating hydrogen absorbing alloy electrode, and alkali secondary battery
    42.
    发明授权
    Hydrogen absorbing alloy electrode, method of fabricating hydrogen absorbing alloy electrode, and alkali secondary battery 失效
    吸氢合金电极,制备吸氢合金电极的方法和碱二次电池

    公开(公告)号:US06358647B1

    公开(公告)日:2002-03-19

    申请号:US09374998

    申请日:1999-08-16

    IPC分类号: H01M438

    CPC分类号: H01M4/383 Y10S420/90

    摘要: In the present invention, a hydrogen absorbing alloy containing at least nickel, cobalt and aluminum, in which the sum a of the respective abundance ratios of cobalt atoms and aluminum atoms in a portion to a depth of 30 Å from its surface and the sum b of the respective abundance ratios of cobalt atoms and aluminum atoms in a bulk region inside thereof satisfy conditions of a/b≧1.30, or a hydrogen absorbing alloy containing at least nickel, cobalt, aluminum and manganese, in which the sum A of the respective abundance ratios of cobalt atoms, aluminum atoms and manganese atoms in a portion to a depth of 30 Å from its surface and the sum B of the respective abundance ratios of cobalt atoms, aluminum atoms and manganese atoms in a bulk region inside thereof satisfy conditions A/B≧1.20 is used for a hydrogen absorbing alloy electrode in an alkali secondary battery.

    摘要翻译: 在本发明中,至少含有镍,钴和铝的吸氢合金,其中钴原子和铝原子的相应丰度比从其表面到深度的一部分的总和a与总和b 在其内部的本体区域中的钴原子和铝原子的相应丰度比满足a / b> = 1.30的条件,或至少含有镍,钴,铝和锰的吸氢合金,其中, 在其表面深度为一部分的钴原子,铝原子和锰原子的丰度比例以及其内部的本体区域中钴原子,铝原子和锰原子的相应丰度比的总和B满足条件 A / B> = 1.20用于碱性二次电池中的吸氢合金电极。

    Hydrogen absorbing alloy electrode and process for producing same
    43.
    发明授权
    Hydrogen absorbing alloy electrode and process for producing same 失效
    吸氢合金电极及其制造方法

    公开(公告)号:US06342318B1

    公开(公告)日:2002-01-29

    申请号:US09460426

    申请日:1999-12-14

    IPC分类号: H01M458

    摘要: A hydrogen absorbing alloy electrode is provided which has an excellent oxygen gas absorbing capacity and further improved in charge-discharge cycle characteristics and high-rate discharge characteristics. The electrode contains a powder prepared by mixing a hydrogen absorbing alloy powder with a powder of at least one complex oxide selected from the group consisting of a ZrO2—Y2O3 solid solution, ZrO2—CaO solid solution, CeO2—Gd2O3 solid solution, CeO2—La2O3 solid solution, ThO2—Y2O3 solid solution, Bi2O3—Y2O3 solid solution, Bi2O3—Gd2O3 solid solution, Bi2O3—Nb2O3 solid solution and Bi2O3—WO3 solid solution. Preferably the electrode contains 0.1 to 10 wt. % of the complex oxide powder based on the combined amount of the two powders.

    摘要翻译: 提供一种具有优异的氧气吸收能力并进一步提高充放电循环特性和高放电特性的吸氢合金电极。 电极含有通过将吸氢合金粉末与选自ZrO 2 -Y 2 O 3固溶体,ZrO 2-CaO固溶体,CeO 2 -Gd 2 O 3固溶体,CeO 2 -La 2 O 3中的至少一种复合氧化物的粉末混合而制备的粉末 固溶体,ThO2-Y2O3固溶体,Bi2O3-Y2O3固溶体,Bi2O3-Gd2O3固溶体,Bi2O3-Nb2O3固溶体和Bi2O3-WO3固溶体。 优选地,电极含有0.1-10wt。 基于两种粉末的组合量的复合氧化物粉末的%。

    Hydrogen absorbing alloy electrode and process for producing same
    44.
    发明授权
    Hydrogen absorbing alloy electrode and process for producing same 有权
    吸氢合金电极及其制造方法

    公开(公告)号:US06329100B1

    公开(公告)日:2001-12-11

    申请号:US09468297

    申请日:1999-12-21

    IPC分类号: H01M458

    CPC分类号: H01M4/383 Y10S420/90

    摘要: A hydrogen absorbing alloy electrode is provided which is improved in hydrogen gas absorbing ability and in low-temperature discharge characteristics. The electrode contains a hydrogen absorbing alloy having a crystal structure of the CaCu5 type and represented by the stoichiometric ratio ABx, the hydrogen absorbing alloy being represented by MmNiaCobAlcMd wherein Mm is a misch metal, M is Mn and/or Cu, the atomic ratios a, b, c and d are in the respective ranges of 3.0≦a≦5.2, 0≦b≦1.2, 0.1≦c≦0.9, 0.1≦d≦0.8, wherein X is the sum of the atomic ratios a, b, c, and d, such that, X=a+b+c+d and, is in the range of 4.4≦X≦5.4. More specifically, the electrode contains a hydrogen absorbing alloy powder at least 5.0 in X, and a hydrogen absorbing alloy powder less than 5.0 in X.

    摘要翻译: 提供一种吸氢合金电极,其提高氢气吸收能力和低温放电特性。 该电极含有具有CaCu5型晶体结构且由化学计量比ABx表示的吸氢合金,该吸氢合金由MmNiaCobAlcMd表示,其中Mm为混合稀土金属,M为Mn和/或Cu,原子比a ,b,c和d分别在3.0 <= a <= 5.2,0 <= b <= 1.2,0.1 <= c <=0.9,0.1≤d≤0.8的范围内,其中X是 原子比a,b,c和d,使得X = a + b + c + d,并且在4.4 <= X <= 5.4的范围内。 更具体地说,电极含有X至少为5.0的吸氢合金粉末,X中的吸氢合金粉末小于5.0。

    Non-sintered nickel electrode for alkaline storage battery
    47.
    发明授权
    Non-sintered nickel electrode for alkaline storage battery 失效
    碱性蓄电池用非烧结镍电极

    公开(公告)号:US6077625A

    公开(公告)日:2000-06-20

    申请号:US97679

    申请日:1998-06-16

    IPC分类号: H01M4/52 H01M4/32

    CPC分类号: H01M4/52

    摘要: Non-sintered nickel electrodes for alkaline storage batteries which can express high active material utilization efficiency not only at the time of charging at ordinary temperature but also at the time of charging in a high-temperature atmosphere are provided by using an active material powder composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound, and an outer coat layer covering the inner coat layer and comprising cobalt or a cobalt compound, or composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising cobalt or a cobalt compound, and an outer coat layer covering the inner coat layer and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound.

    摘要翻译: 通过使用由以下组成的活性物质粉末,可以提供不仅在常温充电时也能在高温气氛中充电的情况下表现出高活性物质利用效率的碱性蓄电池用非烧结镍电极 每个复合颗粒包含含有氢氧化镍的底物颗粒,覆盖基质颗粒并包含钇,钪或镧系元素的内涂层,或钇,钪或镧系元素化合物的外涂层和覆盖内涂层的外涂层, 或钴化合物,或由包含含有氢氧化镍的基底颗粒的复合颗粒或覆盖基材颗粒并包含钴或钴化合物的内涂层以及覆盖内涂层并包含钇,钪的外涂层的复合颗粒组成 或镧系元素,或钇,钪或镧系元素化合物。

    Hydrogen storage containers
    48.
    发明授权
    Hydrogen storage containers 失效
    储氢容器

    公开(公告)号:US5987895A

    公开(公告)日:1999-11-23

    申请号:US96386

    申请日:1998-06-12

    IPC分类号: F17C11/00

    摘要: Molded bodies of a hydrogen absorbing alloy accommodated in a hydrogen storage container are made readily replaceable to ensure stabilized supply of hydrogen gas. When exhibiting an impaired hydrogen absorbing-desorbing capacity, the molded bodies can be easily replaced by new molded bodies, whereby a specified hydrogen absorbing-desorbing capacity can be maintained. The hydrogen gas released from the storage container is partly utilized to heat the container and thereby maintain the alloy at a predetermined temperature, consequently assuring a device, such as a fuel cell, of stabilized supply of hydrogen from the container.

    摘要翻译: 容纳在储氢容器中的吸氢合金的成型体容易替换,以确保稳定的氢气供应。 当表现出吸收解吸能力受损时,可以容易地用新的成型体代替成型体,由此能够保持规定的吸氢解吸能力。 从储存容器释放的氢气部分地用于加热容器,从而将合金保持在预定温度,从而确保诸如燃料电池的装置从容器稳定地供应氢气。

    Nonaqueous electrolyte solution for secondary battery and nonaqueous electrolyte secondary battery
    49.
    发明授权
    Nonaqueous electrolyte solution for secondary battery and nonaqueous electrolyte secondary battery 失效
    二次电池和非水电解质二次电池用非水电解液

    公开(公告)号:US08323839B2

    公开(公告)日:2012-12-04

    申请号:US11234239

    申请日:2005-09-26

    IPC分类号: H01M6/04

    摘要: A nonaqueous electrolyte secondary battery in which the decomposition of an electrolyte solution is reduced exhibits high coulombic efficiency and excellent charge and discharge cycle performance, and has high energy density. This nonaqueous electrolyte secondary battery includes a negative electrode that is formed by depositing a thin film of active material on a collector by a CVD method, sputtering, evaporation, thermal spraying, or plating, wherein the thin film of the active material can lithiate and delithiate and is divided into columns by cracks formed in the thickness direction, and the bottom of each column is adhered to the collector; a positive electrode that can lithiate and delithiate; and a nonaqueous electrolyte solution containing a lithium salt in a nonaqueous solvent. The electrolyte solution contains a compound expressed by a general formula (I). Rn-M=0  (I) (wherein, Rs are alkyl groups optionally having a substituent, may be identical or different from one another, may be independent substituents, or may be bound together to form a ring; M is S or P; and n is 2 when M is S and is 3 when M is P).

    摘要翻译: 其中电解液的分解降低的非水电解质二次电池显示出高的库仑效率和优异的充放电循环性能,并且具有高的能量密度。 该非水电解质二次电池包括通过CVD法,溅射法,蒸镀法,热喷镀法或电镀法将活性物质薄膜沉积在集电体上形成的负极,其中活性物质的薄膜可以锂化和脱锂 并通过在厚度方向上形成的裂纹分成列,并且每列的底部粘附到集电体; 可以锂化和脱锂的正极; 以及在非水溶剂中含有锂盐的非水电解液。 电解质溶液含有由通式(I)表示的化合物。 Rn-M = 0(I)(其中,R 5是任选具有取代基的烷基可以相同或不同,可以是独立的取代基,或者可以结合在一起形成环; M是S或P; 当M为S时n为2,M为P时为3)。