摘要:
In a lithium secondary battery provided with a positive electrode, a negative electrode, and a non-aqueous electrolyte, a tungsten oxide W20O58 or W18O49, or the tungsten oxide to which lithium is added, or a tungsten composite oxide comprising a tungsten oxide containing at least one type of metal element selected from the group consisting of Mn, Cu, V, Cr, Fe, Co, and Ni and having a W20O58-type or W18O49-type crystal structure or the tungsten composite oxide to which lithium is added is used as a positive electrode active material for said positive electrode or a negative electrode active material for said negative electrode.
摘要:
In the present invention, a hydrogen absorbing alloy containing at least nickel, cobalt and aluminum, in which the sum a of the respective abundance ratios of cobalt atoms and aluminum atoms in a portion to a depth of 30 Å from its surface and the sum b of the respective abundance ratios of cobalt atoms and aluminum atoms in a bulk region inside thereof satisfy conditions of a/b≧1.30, or a hydrogen absorbing alloy containing at least nickel, cobalt, aluminum and manganese, in which the sum A of the respective abundance ratios of cobalt atoms, aluminum atoms and manganese atoms in a portion to a depth of 30 Å from its surface and the sum B of the respective abundance ratios of cobalt atoms, aluminum atoms and manganese atoms in a bulk region inside thereof satisfy conditions A/B≧1.20 is used for a hydrogen absorbing alloy electrode in an alkali secondary battery.
摘要:
A hydrogen absorbing alloy electrode is provided which has an excellent oxygen gas absorbing capacity and further improved in charge-discharge cycle characteristics and high-rate discharge characteristics. The electrode contains a powder prepared by mixing a hydrogen absorbing alloy powder with a powder of at least one complex oxide selected from the group consisting of a ZrO2—Y2O3 solid solution, ZrO2—CaO solid solution, CeO2—Gd2O3 solid solution, CeO2—La2O3 solid solution, ThO2—Y2O3 solid solution, Bi2O3—Y2O3 solid solution, Bi2O3—Gd2O3 solid solution, Bi2O3—Nb2O3 solid solution and Bi2O3—WO3 solid solution. Preferably the electrode contains 0.1 to 10 wt. % of the complex oxide powder based on the combined amount of the two powders.
摘要翻译:提供一种具有优异的氧气吸收能力并进一步提高充放电循环特性和高放电特性的吸氢合金电极。 电极含有通过将吸氢合金粉末与选自ZrO 2 -Y 2 O 3固溶体,ZrO 2-CaO固溶体,CeO 2 -Gd 2 O 3固溶体,CeO 2 -La 2 O 3中的至少一种复合氧化物的粉末混合而制备的粉末 固溶体,ThO2-Y2O3固溶体,Bi2O3-Y2O3固溶体,Bi2O3-Gd2O3固溶体,Bi2O3-Nb2O3固溶体和Bi2O3-WO3固溶体。 优选地,电极含有0.1-10wt。 基于两种粉末的组合量的复合氧化物粉末的%。
摘要:
A hydrogen absorbing alloy electrode is provided which is improved in hydrogen gas absorbing ability and in low-temperature discharge characteristics. The electrode contains a hydrogen absorbing alloy having a crystal structure of the CaCu5 type and represented by the stoichiometric ratio ABx, the hydrogen absorbing alloy being represented by MmNiaCobAlcMd wherein Mm is a misch metal, M is Mn and/or Cu, the atomic ratios a, b, c and d are in the respective ranges of 3.0≦a≦5.2, 0≦b≦1.2, 0.1≦c≦0.9, 0.1≦d≦0.8, wherein X is the sum of the atomic ratios a, b, c, and d, such that, X=a+b+c+d and, is in the range of 4.4≦X≦5.4. More specifically, the electrode contains a hydrogen absorbing alloy powder at least 5.0 in X, and a hydrogen absorbing alloy powder less than 5.0 in X.
摘要翻译:提供一种吸氢合金电极,其提高氢气吸收能力和低温放电特性。 该电极含有具有CaCu5型晶体结构且由化学计量比ABx表示的吸氢合金,该吸氢合金由MmNiaCobAlcMd表示,其中Mm为混合稀土金属,M为Mn和/或Cu,原子比a ,b,c和d分别在3.0 <= a <= 5.2,0 <= b <= 1.2,0.1 <= c <=0.9,0.1≤d≤0.8的范围内,其中X是 原子比a,b,c和d,使得X = a + b + c + d,并且在4.4 <= X <= 5.4的范围内。 更具体地说,电极含有X至少为5.0的吸氢合金粉末,X中的吸氢合金粉末小于5.0。
摘要:
A hydrogen storage alloy electrode for a battery is made of a hydrogen storage alloy powder which includes agglomerates of hydrogen storage alloy particles joined together through a metallic layer. A method of making the electrode includes forming agglomerates of hydrogen storage alloy particles joined together by a metallic layer which covers surface portions of the particles, and then forming the electrode using a resulting powder including the agglomerates.
摘要:
A positive-electrode active material for alkaline secondary battery according to the invention has an &agr;-Ni(OH)2 crystal structure which incorporates therein manganese and a trivalent metal other than manganese.
摘要:
Non-sintered nickel electrodes for alkaline storage batteries which can express high active material utilization efficiency not only at the time of charging at ordinary temperature but also at the time of charging in a high-temperature atmosphere are provided by using an active material powder composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound, and an outer coat layer covering the inner coat layer and comprising cobalt or a cobalt compound, or composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising cobalt or a cobalt compound, and an outer coat layer covering the inner coat layer and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound.
摘要:
Molded bodies of a hydrogen absorbing alloy accommodated in a hydrogen storage container are made readily replaceable to ensure stabilized supply of hydrogen gas. When exhibiting an impaired hydrogen absorbing-desorbing capacity, the molded bodies can be easily replaced by new molded bodies, whereby a specified hydrogen absorbing-desorbing capacity can be maintained. The hydrogen gas released from the storage container is partly utilized to heat the container and thereby maintain the alloy at a predetermined temperature, consequently assuring a device, such as a fuel cell, of stabilized supply of hydrogen from the container.
摘要:
A nonaqueous electrolyte secondary battery in which the decomposition of an electrolyte solution is reduced exhibits high coulombic efficiency and excellent charge and discharge cycle performance, and has high energy density. This nonaqueous electrolyte secondary battery includes a negative electrode that is formed by depositing a thin film of active material on a collector by a CVD method, sputtering, evaporation, thermal spraying, or plating, wherein the thin film of the active material can lithiate and delithiate and is divided into columns by cracks formed in the thickness direction, and the bottom of each column is adhered to the collector; a positive electrode that can lithiate and delithiate; and a nonaqueous electrolyte solution containing a lithium salt in a nonaqueous solvent. The electrolyte solution contains a compound expressed by a general formula (I). Rn-M=0 (I) (wherein, Rs are alkyl groups optionally having a substituent, may be identical or different from one another, may be independent substituents, or may be bound together to form a ring; M is S or P; and n is 2 when M is S and is 3 when M is P).
摘要:
A non-aqueous electrolyte secondary cell is provided with a positive electrode, a negative electrode, and a non-aqueous electrolyte solution, wherein said positive electrode comprises sulfur and said non-aqueous electrolyte solution comprises a room-temperature molten salt having a melting point of 60° C. or less.