公开(公告)号：US07741002B2

公开(公告)日：2010-06-22

申请号：US11558736

申请日：2006-11-10

申请人： Osamu Uchinokura ,  Fumihiro Sasaki ,  Satoshi Mochizuki ,  Hidetoshi Noda ,  Tsuyoshi Fukushima ,  Koutaro Kitano

发明人： Osamu Uchinokura ,  Fumihiro Sasaki ,  Satoshi Mochizuki ,  Hidetoshi Noda ,  Tsuyoshi Fukushima ,  Koutaro Kitano

IPC分类号： G03G9/08

CPC分类号： G03G9/0806 ,  G03G9/0815 ,  G03G9/0819 ,  G03G9/08797

摘要： The present invention provides a method for producing a toner including preparing an emulsified dispersion which contains emulsion particles by emulsifying or dispersing an oil phase containing at least a pigment and any one of a binder resin and a binder resin precursor in an aqueous medium, and granulating toner base particles by converging the emulsified dispersion, wherein the Casson yield value of the single oil phase before being emulsified or dispersed in the aqueous medium is 0.5 Pa to 20 Pa; and the temperature Tn of the emulsified dispersion in the preparation of the emulsified dispersion, the temperature Ts of the emulsified dispersion in the granulation of the toner base particles, and the glass transition temperature Tg of the toner base particles satisfy the relation Tn

摘要翻译： 本发明提供了一种调色剂的制造方法，其包括通过将至少含有颜料的油相和粘合剂树脂和粘合剂树脂前体中的任一种乳化分散在水性介质中而制备含有乳液粒子的乳化分散体， 调色剂基础颗粒通过使乳化分散体收敛，其中在乳化或分散在水性介质中单油相的Casson屈服值为0.5Pa至20Pa; 乳化分散液的制造中的乳化分散液的温度Tn，调色剂母粒的造粒中的乳化分散液的温度Ts和调色剂母粒的玻璃化转变温度Tg满足关系式Tn

公开(公告)号：US07368213B2

公开(公告)日：2008-05-06

申请号：US11081738

申请日：2005-03-17

申请人： Shinya Nakayama ,  Fumihiro Sasaki ,  Satoshi Mochizuki ,  Akihiro Kotsugai ,  Yasuo Asahina ,  Osamu Uchinokura ,  Hisashi Nakajima ,  Sonoh Matsuoka ,  Takuya Saito ,  Tomoyuki Ichikawa ,  Koichi Sakata

发明人： Shinya Nakayama ,  Fumihiro Sasaki ,  Satoshi Mochizuki ,  Akihiro Kotsugai ,  Yasuo Asahina ,  Osamu Uchinokura ,  Hisashi Nakajima ,  Sonoh Matsuoka ,  Takuya Saito ,  Tomoyuki Ichikawa ,  Koichi Sakata

IPC分类号： G03G9/00

CPC分类号： G03G9/0825 ,  G03G9/09328 ,  G03G9/09335 ,  G03G9/09392

摘要： A toner containing toner particles having a core-shell structure containing a binder resin, a colorant and a release agent. The toner particles are prepared by dissolving or dispersing at least one of the binder resin and a precursor thereof in an organic solvent or a polymeric monomer and reacting the resultant in an aqueous medium for reaction, wherein the toner satisfies the following relationship: ΔTm=Tm1−Tm2>10 ° C., wherein Tm1 represents half efflux temperature of the toner and Tm2 represents half efflux temperature of a toner which is prepared by melting and kneading the toner particles and wherein a content of the release agent existing close to the surface portion of the toner particles is from 7 to 30% by volume based on an entire portion close to the surface portion of the toner particles when the content is determined by Fourier Transform Infrared Spectroscopy Attenuated Total Reflection (FTIR-ATR) method.

摘要翻译： 含有具有含有粘合剂树脂，着色剂和脱模剂的核 - 壳结构的调色剂颗粒的调色剂。 调色剂颗粒通过将粘合剂树脂及其前体中的至少一种溶解或分散在有机溶剂或聚合单体中而制备，并将所得物在水性介质中反应，其中调色剂满足以下关系：DeltaTm = Tm 1-Tm 2> 10℃，其中Tm 1表示调色剂的半流出温度，Tm 2表示通过熔融和捏合调色剂颗粒而制备的调色剂的半流出温度，并且其中脱模剂的含量存在 当通过傅里叶变换红外光谱衰减全反射（FTIR-ATR）方法确定含量时，基于调色剂颗粒的表面部分附近的整个部分，调色剂颗粒的表面部分为7至30体积％。

公开(公告)号：US20060029433A1

公开(公告)日：2006-02-09

申请号：US11192051

申请日：2005-07-29

申请人： Takuya Saito ,  Koichi Sakata ,  Tomoyuki Ichikawa ,  Shinya Nakaya ,  Hisashi Nakajima ,  Sonoh Matsuoka ,  Akihiro Kotsugai ,  Yasuo Asahina ,  Fumihiro Sasaki ,  Satoshi Mochizuki ,  Osamu Uchinokura

发明人： Takuya Saito ,  Koichi Sakata ,  Tomoyuki Ichikawa ,  Shinya Nakaya ,  Hisashi Nakajima ,  Sonoh Matsuoka ,  Akihiro Kotsugai ,  Yasuo Asahina ,  Fumihiro Sasaki ,  Satoshi Mochizuki ,  Osamu Uchinokura

IPC分类号： G03G15/08

CPC分类号： G03G15/0879 ,  G03G15/0877

摘要： A toner for an image forming apparatus having a volume average diameter of from 2 to 8 μm is manufactured by reacting an aqueous dispersion comprising at least one pigment, a polymer and/or a mixture of monomers to form fine toner particles wherein the amount of fine particles having a diameter of one-half the average number diameter are present in an amount of 20% by number or less, a toner cartridge containing the toner and a method for using the toner.

摘要翻译： 通过使包含至少一种颜料的水性分散体，聚合物和/或单体混合物的水分散体反应，制造体积平均直径为2至8μm的图像形成装置的调色剂，以形成精细调色剂颗粒，其中精细量 直径为平均数量直径的一半的颗粒的含量为20％以下，含有调色剂的调色剂盒和使用该调色剂的方法。

公开(公告)号：US06828075B2

公开(公告)日：2004-12-07

申请号：US10153627

申请日：2002-05-24

申请人： Kousuke Suzuki ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Hideki Sugiura ,  Minoru Masuda ,  Tomomi Tamura

发明人： Kousuke Suzuki ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Hideki Sugiura ,  Minoru Masuda ,  Tomomi Tamura

IPC分类号： G03G900

CPC分类号： G03G9/1133 ,  G03G9/1136

摘要： A carrier for electrophotographic developer comprising carrier particles, each carrier particle having at least one surface-coating layer by resin material, wherein the surface-coating layer containing an acrylic resin and a silicone resin, the acrylic resin is in an amount ranging 10 to 90 wt. % based on the total amount of resin coating ingredients. The carrier shows no accumulation of toner-spents, therefore can obtain a stable electric charge, and has no layer scraping in binder resin layer, therefore can obtain a stable electric resistance, hence occurs no deterioration of images reproduced, by using acrylic resin having high anti-abrasive and high surface energy, whereas it has strong adhesiveness and high fragility, in combination use of silicone resin having poor anti-abrasive and small adhesiveness but has low fragility, thus is hard to cause a toner spent and hard to integrate the spent constituents due to its low surface energy.

摘要翻译： 包含载体颗粒的电子照相显影剂载体，每个载体颗粒具有至少一个树脂材料的表面涂层，其中含有丙烯酸树脂和有机硅树脂的表面涂层的丙烯酸树脂的量为10至90 重量 基于树脂涂料成分的总量％。 载体不显示调色剂的积累，因此可以获得稳定的电荷，并且在粘合剂树脂层中没有层刮擦，因此可以获得稳定的电阻，因此通过使用具有高的丙烯酸树脂而不会再现图像的劣化 耐磨性高，表面能高，而且具有很强的粘合性和高脆性，组合使用具有差的抗磨损性和粘合性小的有机硅树脂，但脆性低，因此很难使调色剂花费并难以整合 成分由于其低表面能。

公开(公告)号：US06818369B2

公开(公告)日：2004-11-16

申请号：US10059240

申请日：2002-01-31

申请人： Hideki Sugiura ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Minoru Masuda ,  Kohsuke Suzuki ,  Tomomi Tamura

发明人： Hideki Sugiura ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Minoru Masuda ,  Kohsuke Suzuki ,  Tomomi Tamura

IPC分类号： G03G9087

CPC分类号： G03G9/087 ,  G03G9/0821 ,  G03G9/08753 ,  G03G9/08755 ,  G03G9/08759 ,  G03G9/08762 ,  G03G9/08782 ,  G03G9/08795 ,  G03G9/08797

摘要： A toner for electrostatic image development in which the weight concentration of polar-solvent-soluble material is 1000 &mgr;g/g or less, based on the toner, and an image forming method comprising a step of forming a toner image by developing a latent electrostatic image by using the toner for electrostatic image development.

摘要翻译： 一种用于静电图像显影的调色剂，其中极性溶剂可溶物质的重量浓度基于调色剂为1000mug / g或更小，以及包括通过显影静电潜像形成调色剂图像的步骤的图像形成方法 通过使用用于静电图像显影的调色剂。

公开(公告)号：US06770411B2

公开(公告)日：2004-08-03

申请号：US10107157

申请日：2002-03-28

申请人： Minoru Masuda ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Hideki Sugiura ,  Kohsuke Suzuki ,  Tomomi Tamura

发明人： Minoru Masuda ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Hideki Sugiura ,  Kohsuke Suzuki ,  Tomomi Tamura

IPC分类号： G03G9097

CPC分类号： G03G9/0812 ,  G03G9/09783

摘要： A toner including a binder resin, a colorant, and a product of an iron compound containing an aromatic hydroxylcarboxylic acid as a ligand and represented by the formula (I) described in the specification, wherein the product has such a characteristic that a filtrate obtained by filtering a dispersion of 10 g of the product dispersed in 200 ml of purified water provides an electric conductivity of not greater than 600 &mgr;S/cm.

摘要翻译： 一种调色剂，其包含粘合剂树脂，着色剂和含有芳族羟基羧酸作为配体并由本说明书中描述的式（I）表示的铁化合物的产物，其中该产物具有以下特征：将由 过滤分散在200ml纯水中的10g产物的分散体，提供不大于600μS/ cm的电导率。

公开(公告)号：US07611815B2

公开(公告)日：2009-11-03

申请号：US10618640

申请日：2003-07-15

申请人： Hideki Sugiura ,  Satoshi Mochizuki ,  Kazuhiko Umemura ,  Shinya Nakayama ,  Yasuo Asahina

发明人： Hideki Sugiura ,  Satoshi Mochizuki ,  Kazuhiko Umemura ,  Shinya Nakayama ,  Yasuo Asahina

IPC分类号： G03G9/08 ,  C09C1/28 ,  C01B33/113

CPC分类号： B82Y30/00 ,  C01G9/00 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/043 ,  C09C1/3045 ,  C09C1/3081 ,  C09C3/12 ,  G03G9/09716 ,  G03G9/09725

摘要： An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30 nm to 300 nm in number average, a standard deviation σ of a particle size distribution of the primary particle diameter satisfies a relation of: R/4≦σ≦R, in which the R expresses the primary particle diameter,the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125; SF1=(L2/A)×(π/4)×100  equation (1) SF2=(P2/A)×(1/4π)×100  equation (2), in the equations, “L” expresses the absolute maximum length of the oxide fine particles; “A” expresses a projected area of the oxide fine particles; and “P” expresses a maximum perimeter of the oxide fine particles.

摘要翻译： 用于电子照相的调色剂的外部添加剂，其包含含有氧化物细颗粒的氧化物细颗粒，其中氧化物细颗粒的初级粒径为数均粒径为30nm至300nm，主要颗粒尺寸分布的标准偏差σ为 颗粒直径满足以下关系：其中R表示一次粒径的R / 4 <=σ= R，氧化物微粒基本上是球形的，其具有如式（1）所定义的圆形度SF1为100-130，和 定义为等式（2）为100至125的圆形度SF2; SF1 =（L2 / A）×（pi / 4）×100等式（1）SF2 =（P2 / A）×（1 / 4pi）×100方程式（2）在等式中，“L”表示绝对最大长度 氧化物微粒; “A”表示氧化物微粒的投影面积; “P”表示氧化物微粒的最大周长。

公开(公告)号：US07169522B2

公开(公告)日：2007-01-30

申请号：US10385719

申请日：2003-03-12

申请人： Hideki Sugiura ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Minoru Masuda ,  Tomomi Tamura

发明人： Hideki Sugiura ,  Satoshi Mochizuki ,  Yasuo Asahina ,  Kazuhiko Umemura ,  Minoru Masuda ,  Tomomi Tamura

IPC分类号： G03G9/09

CPC分类号： G03G9/0819 ,  G03G9/0827 ,  G03G9/08748 ,  G03G9/08753 ,  G03G9/08759 ,  G03G9/08762 ,  G03G9/09 ,  G03G9/0926

摘要： The toner for developing a latent electrostatic image to form an image contains a binder resin and 2% by weight to 15% by weight of a coloring agent. The coverage of the toner with the coloring agent on a surface of the toner is 1.5% by atom to 15% by atom. The toner prevents scatterings and toner deposition on the background of images and provides high quality images even after printing several tens of sheets at high temperature and in high humidity.

摘要翻译： 用于显影静电潜像以形成图像的调色剂含有粘合剂树脂和2重量％至15重量％的着色剂。 调色剂表面上的着色剂的调色剂的覆盖率为1.5原子％至15原子％。 调色剂防止图像背景上的散射和调色剂沉积，并且即使在高温和高湿度下打印数十张纸后也能提供高质量的图像。

公开(公告)号：US20070059063A1

公开(公告)日：2007-03-15

申请号：US11519057

申请日：2006-09-12

申请人： Shinya Nakayama ,  Hisashi Nakajima ,  Hideki Sugiura ,  Fumihiro Sasaki ,  Akihiro Kotsugai ,  Satoshi Mochizuki

发明人： Shinya Nakayama ,  Hisashi Nakajima ,  Hideki Sugiura ,  Fumihiro Sasaki ,  Akihiro Kotsugai ,  Satoshi Mochizuki

IPC分类号： G03G15/20

CPC分类号： G03G15/2007 ,  G03G9/0827 ,  G03G9/09708 ,  G03G9/09716 ,  G03G9/09725 ,  G03G15/2064 ,  G03G2215/0602 ,  G03G2215/2016 ,  G03G2215/2032 ,  G03G2215/2035

摘要： To provide an image forming method including forming a latent electrostatic image on a latent electrostatic image bearing member, developing the latent electrostatic image using a toner to form a visible image, transferring the visible image to a recording medium, and fixing a transfer image transferred on the recording medium, wherein the toner includes a toner base particle containing at least a binder resin, a colorant and an inorganic fine particle, and a charge control agent; and wherein the condition Xsurf>Xtotal is satisfied (where Xsurf is an average proportion of the inorganic fine particles in a near-surface region of the toner base particle, Xtotal is an average proportion of inorganic fine particles in the whole toner base particle.

摘要翻译： 为了提供一种图像形成方法，包括在静电潜像承载部件上形成静电潜像，使用调色剂显影静电潜像以形成可见图像，将可视图像转印到记录介质上，并将转印的转印图像 所述记录介质，其中所述调色剂包括至少含有粘合剂树脂，着色剂和无机细颗粒的调色剂基础颗粒和电荷控制剂; 并且其中满足条件X> surf >> X X X satisfied（（（surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface surface 调色剂基础颗粒的区域，X总计是整个调色剂基础颗粒中无机细颗粒的平均比例。

公开(公告)号：US06861191B2

公开(公告)日：2005-03-01

申请号：US10059239

申请日：2002-01-31

申请人： Satoshi Mochizuki ,  Hideki Sugiura ,  Kazuhiko Umemura ,  Minoru Masuda ,  Kohsuke Suzuki ,  Tomomi Suzuki ,  Yasuo Asahina

发明人： Satoshi Mochizuki ,  Hideki Sugiura ,  Kazuhiko Umemura ,  Minoru Masuda ,  Kohsuke Suzuki ,  Tomomi Suzuki ,  Yasuo Asahina

IPC分类号： G03G9/087

CPC分类号： G03G9/08753 ,  G03G9/08755

摘要： A dry toner for developing electrostatic images, including a colorant and a binder resin which comprises a copolymer resin having (A) a polyol resin moiety having a main chain of polyoxyalkylene and obtained by reaction of (a) an epoxy resin, (b) a dihydric phenol, and (c) an alkylene oxide adduct of a dihydric phenol or a glycidyl ether thereof; and (B) a polyester resin moiety obtained by reacting an alkylene oxide adduct of a dihydric phenol or a glycidyl ether thereof with a polycarboxylic acid, wherein the weight ratio of the epoxy resin of the polyol resin moiety (A) to the polyester resin moiety (B) is 95:5 to 60:40, wherein the epoxy resin includes at least two kinds of bisphenol epoxy resins having different number-average molecular weights, and wherein the binder resin has an acid value of not greater than 5.

摘要翻译： 一种用于显影静电图像的干燥调色剂，包括着色剂和粘合剂树脂，其包含共聚物树脂，其具有（A）具有聚氧化烯主链的多元醇树脂部分并通过（a）环氧树脂反应获得，（b） 二元酚，（c）二元酚或其缩水甘油醚的烯化氧加成物; 和（B）通过使二元酚或其缩水甘油醚的烯化氧加合物与多元羧酸反应得到的聚酯树脂部分，其中多元醇树脂部分（A）的环氧树脂与聚酯树脂部分的重量比 （B）为95:5〜60:40，其中环氧树脂包括至少两种具有不同数均分子量的双酚环氧树脂，其中粘合剂树脂的酸值不大于5。