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    Method and system for transporting flows of fluid hydrocarbons containing wax, asphaltenes, and/or other precipitating solids
    41.
    发明授权
    Method and system for transporting flows of fluid hydrocarbons containing wax, asphaltenes, and/or other precipitating solids 有权
    用于输送含有蜡，沥青质和/或其它沉淀固体的流体烃的流动的方法和系统

    公开(公告)号：US07261810B2

    公开(公告)日：2007-08-28

    申请号：US10703532

    申请日：2003-11-10

    Applicant: Carl B. Argo ,  Phaneendra Bollavaram ,  Kai W. Hjarbo ,  Taras Yurievich Makogon ,  Nita Oza ,  Marita Wolden ,  Are Lund ,  Roar Larsen

    Inventor： Carl B. Argo ,  Phaneendra Bollavaram ,  Kai W. Hjarbo ,  Taras Yurievich Makogon ,  Nita Oza ,  Marita Wolden ,  Are Lund ,  Roar Larsen

    IPC: C10G31/06

    CPC classification number: F17D1/088

    Abstract: A method and a system for transporting a flow of fluid hydrocarbons containing wax and/or asphaltenes or any other precipitating solids through a treatment and transportation system including a pipeline are disclosed. The flow of fluid hydrocarbons is introduced into a reactor (4), where it is mixed with another fluid flow having a temperature below a crystallization temperature for the wax and/or asphaltenes or other solids and containing particles or crystals acting as nucleating and/or growth cores for the wax and/or asphaltenes or other solids, the mixing temperature providing precipitation of the wax and/or asphaltenes or other solids from the flow of fluid hydrocarbons, and the effluent flow of hydrocarbons and particles is conveyed from the reactor (4) to a pipeline (6) for transportation.

    Abstract translation: 公开了一种用于通过包括管道的处理和运输系统输送含有蜡和/或沥青质或任何其它沉淀固体的流体烃流的方法和系统。 流体烃的流动被引入反应器（4）中，其中与蜡和/或沥青质或其它固体的温度低于结晶温度的另一种流体流混合，并且包含用作成核和/或 蜡和/或沥青质或其他固体的生长核心，混合温度提供了来自流体烃流的蜡和/或沥青质或其它固体的沉淀，并且烃和颗粒的流出物从反应器（4 ）到运输管道（6）。

    Fischer-Tropsch synthesis process
    42.
    发明授权
    Fischer-Tropsch synthesis process 有权
    费 - 托合成方法

    公开(公告)号：US07115670B2

    公开(公告)日：2006-10-03

    申请号：US10476799

    申请日：2002-05-17

    Applicant: John Richard Hensman ,  David Newton

    Inventor： John Richard Hensman ,  David Newton

    IPC: C07C27/00

    CPC classification number: C10G2/342 ,  B01J8/228 ,  B01J2208/00132 ,  B01J2208/00256 ,  B01J2208/003

    Abstract: A process for the conversion of synthesis gas to higher hydrocarbons by synthesis gas, at an elevated temperature and pressure, with a suspension of a particulate Fischer-Tropsch catalyst, in a system comprising at least one high shear mixing zone and a reactor vessel wherein the process comprises: (a) passing the suspension and the gaseous stream through the high shear mixing zone wherein the gaseous stream is broken down into gas bubbles and/or irregularly shaped gas voids; (b) discharging suspension having gas bubbles and/or irregularly shaped gas voids dispersed therein from the high shear mixing zone into the reactor vessel; and (c) maintaining the temperature of the suspension discharged into the reactor vessel at the desired reaction temperature by means of an internal heat exchanger positioned within the suspension in the reactor vessel. At least 5% of the exothermic heat of reaction is removed from the system by means of the internal heat exchanger. The remainder of the exothermic heat of reaction may be removed from the system by means of an external heat exchanger and/or through the introduction of a liquid coolant.

    Abstract translation: 一种在包括至少一个高剪切混合区和反应器容器的系统中，通过合成气在升高的温度和压力下与微量费 - 托催化剂的悬浮液将合成气转化为高级烃的方法，其中 方法包括：（a）使悬浮液和气流通过高剪切混合区，其中气流被分解成气泡和/或不规则形状的气体空隙; （b）将从高剪切混合区分散有气泡和/或不规则形状的气体空隙的悬浮液排出到反应器容器中; 和（c）通过位于反应器容器的悬浮液内部的内部热交换器将排放到反应器容器中的悬浮液的温度保持在所需的反应温度。 通过内部热交换器将至少5％的反应放热量从系统中除去。 反应放热的其余部分可以通过外部热交换器和/或通过引入液体冷却剂从系统中去除。

    Process for separating liquid hydrocarbons from a particulate fisher-tropsch catalyst
    43.
    发明授权
    Process for separating liquid hydrocarbons from a particulate fisher-tropsch catalyst 有权
    从颗粒捕捞催化剂中分离液态烃的方法

    公开(公告)号：US07112613B2

    公开(公告)日：2006-09-26

    申请号：US10476623

    申请日：2002-05-17

    Applicant: Timothy Douglas Gamlin ,  Carole Graham ,  John Richard Hensman ,  Barry Nay ,  David Newton

    Inventor： Timothy Douglas Gamlin ,  Carole Graham ,  John Richard Hensman ,  Barry Nay ,  David Newton

    IPC: C07C27/00

    CPC classification number: C10G2/32 ,  B03C1/288 ,  B03C2201/18 ,  C10G31/09

    Abstract: Process for converting synthesis gas to hydrocarbons which comprises contacting a gaseous stream comprising synthesis gas, at an elevated temperature and pressure, with a suspension comprising a particulate Fischer-Tropsch catalyst having a particle size in the range 5 microns to 500 microns, suspended in a liquid medium, in a system comprising at least one high shear mixing zone and a reactor vessel. The suspension and the gaseous stream is passed through the high shear mixing zone(s) wherein the gaseous stream is broken down into gas bubbles. The suspension having gas bubbles dispersed therein is discharged from the high shear mixing zone(s) into the reactor vessel, and suspension comprising the particulate Fischer-Tropsch catalyst suspended in the liquid medium and liquid hydrocarbon products is withdrawn from the reactor vessel and at least a portion of the suspension is recycled to the high shear mixing zone(s) via an external conduit at a flow rate of at least 10,000 m3 of suspension per hour. A side stream from the suspension flowing through the external conduit is taken and passed directly to a filtration unit.

    Abstract translation: 将合成气转化为烃的方法，其包括将包含合成气的气流在升高的温度和压力下与包含粒度在5微米至500微米范围内的颗粒状费 - 托催化剂的悬浮液悬浮在 液体介质，在包括至少一个高剪切混合区和反应器容器的系统中。 悬浮液和气流通过高剪切混合区，其中气流被分解成气泡。 将其中分散有气泡的悬浮液从高剪切混合区排出到反应器容器中，并且将悬浮在液体介质中的包含微量费 - 托催化剂的悬浮液和液体烃产物从反应器容器中取出并且至少 悬浮液的一部分通过外部管道以每小时至少10,000m 3 / h 3悬浮液的流速再循环到高剪切混合区。 取自流过外部导管的悬浮液的侧流，并直接通过过滤单元。

    Fischer-Tropsch synthesis process carried out on a floatable structure
    44.
    发明授权
    Fischer-Tropsch synthesis process carried out on a floatable structure 失效
    费托合成方法在可漂浮结构上进行

    公开(公告)号：US07037947B2

    公开(公告)日：2006-05-02

    申请号：US10476255

    申请日：2002-05-17

    Applicant: Josephus Johannes Helena Maria Font Freide ,  John Richard Hensman ,  David Newton

    Inventor： Josephus Johannes Helena Maria Font Freide ,  John Richard Hensman ,  David Newton

    IPC: C07C27/00 ,  E02B17/08 ,  E02D23/02

    CPC classification number: C10G2/342 ,  B01J8/22 ,  B01J19/26 ,  B01J2219/00006 ,  B63B35/44 ,  B63B2035/4473 ,  C10G2300/1025 ,  C10G2300/202 ,  C10G2300/4068 ,  C10G2300/4081 ,  C10G2300/44

    Abstract: A process for the conversion of natural gas to higher hydrocarbons in a system comprising (1) a synthesis gas production unit and (2) a Fischer-Tropsch synthesis unit comprising at least one high shear mixing zone and a reactor vessel wherein the units are located abroad a floatable structure. The process comprises the steps of: (a) converting the natural gas to synthesis gas in the synthesis gas production unit; and (b) converting the synthesis gas to higher hydrocarbons, at an elevated temperature and pressure, in the Fischer-Tropsch synthesis unit by (i) passing synthesis gas and a suspension comprising a particulate Fischer-Tropsch catalyst suspended in a liquid medium through the high shear mixing zone(s) wherein the synthesis gas is broken down into gas bubbles and/or irregularly shaped gas voids which are dispersed in the suspension, and (ii) discharging suspension containing the dispersed gas bubbles and/or irregularly shaped gas voids from the high shear mixing zone(s) into the reactor vessel.

    Abstract translation: 一种在系统中将天然气转化为高级烃的方法，包括（1）合成气生产单元和（2）包含至少一个高剪切混合区和反应器容器的费 - 托合成单元，其中所述单元位于 国外一个漂浮的结构。 该方法包括以下步骤：（a）将天然气转化为合成气生产单元中的合成气; 和（b）在费 - 托合成单元中通过以下步骤将合成气转化为高级烃：（i）将合成气和悬浮在液体介质中的包含悬浮在液体介质中的微量费 - 托催化剂的悬浮液通过 高剪切混合区，其中合成气被分解成分散在悬浮液中的气泡和/或不规则形状的气体空隙，和（ii）将含有分散的气泡和/或不规则形状的气体空隙的悬浮液从 高剪切混合区进入反应器容器。

    Process for treating an oil well
    46.
    发明授权
    Process for treating an oil well 失效
    油井处理方法

    公开(公告)号：US06939832B2

    公开(公告)日：2005-09-06

    申请号：US10175896

    申请日：2002-06-21

    Applicant: Ian Ralph Collins

    Inventor： Ian Ralph Collins

    IPC: C09K8/52 ,  C09K8/54 ,  C09K8/60 ,  C09K8/82 ,  C09K3/00 ,  E21B43/27

    CPC classification number: C09K8/82 ,  C09K8/52 ,  C09K8/54 ,  C09K8/602 ,  C09K2208/20 ,  C09K2208/22 ,  Y10S507/921

    Abstract: Method of treating a subterranean formation, comprising (A) injecting down a well bore into the formation an admixture of (a) an emulsion having an internal aqueous phase comprising a water-soluble oil of gas field chemical or an aqueous dispersion of a water-dispersible oil or gas field chemical and an external oil phase comprising a liquid hydrocarbon and an oil-soluble surfactant and (b) a demulsifier comprising a solution of a surfactant having a cloud point temperature of above 40° C. Alternatively, the method comprises separately injecting down a well bore into the formation emulsion (a) and demulsifier (b) and generating an admixture of emulsion (a) and demulsifier (b) within the formation.

    Abstract translation: 一种处理地下地层的方法，包括（A）将井眼注入地层中的混合物（a）具有内部水相的乳液，所述内部水相包含气田化学品的水溶性油或水溶性水分散体， 可分散的油或气田化学品和包含液体烃和油溶性表面活性剂的外部油相，和（b）包含浊点温度高于40℃的表面活性剂溶液的破乳剂。或者，该方法分开 将井眼注入地层乳液（a）和破乳剂（b）中，并在地层内产生乳液（a）和破乳剂（b）的混合物。

    Coated products and use thereof in oil fields
    47.
    发明申请
    Coated products and use thereof in oil fields 失效
    涂料产品及其在油田中的应用

    公开(公告)号：US20020128157A1

    公开(公告)日：2002-09-12

    申请号：US10092423

    申请日：2002-03-07

    Applicant: BP Exploration Operating Company Limited

    Inventor： Christopher Ian Bates ,  Ian Ralph Collins ,  Paul Derek Ravenscroft

    IPC: C09K003/00

    CPC classification number: C09K8/92 ,  C09K8/536 ,  C09K8/54 ,  Y10S507/901 ,  Y10S507/902 ,  Y10S507/906 ,  Y10S507/939

    Abstract: An oil field production chemical, especially a scale inhibitor, is in the form of particles thereof carrying a coating e.g. of a dispersing agent. The coating may be polymeric such as an oligomeric polyacid polyester, a polymeric alkoxylated alcohol or a fatty acid polyamine condensate or it may also be a surfactant and may be used in the form of a suspension in an inert oil, such as diesel oil or kerosene which may be injected into a subterranean formation to inhibit the formation of deposits, e.g. scale in oil wells over a longer period than compounds free of the coating.

    Abstract translation: 油田生产化学品，特别是防垢剂，是带有涂层的颗粒的形式。 的分散剂。 涂层可以是聚合物，例如低聚多酸聚酯，聚合烷氧基化醇或脂肪酸多胺缩合物，或者它也可以是表面活性剂，并且可以以惰性油如柴油或煤油中的悬浮液的形式使用 其可以被注入到地下地层中以抑制沉积物的形成，例如 比没有涂层的化合物更长的时间内在油井中测量。

    Self-degrading organogels
    49.
    发明授权
    Self-degrading organogels 有权

    公开(公告)号：US12203029B2

    公开(公告)日：2025-01-21

    申请号：US18173550

    申请日：2023-02-23

    Applicant: University of Maryland, College Park ,  BP Exploration Operating Company Limited

    Inventor： Faraz A. Burni ,  Srinivasa R. Raghavan ,  Joseph Wee ,  David Chappell ,  Shanshan Huang

    IPC: C09K8/42 ,  C09K8/03 ,  C09K8/035 ,  E21B21/00 ,  E21B33/138

    Abstract: The problem of lost circulation is pertinent to the oil industry. To prevent fluid loss, a lost circulation material (LCM), or more generally, a plugging material, can be used to effectively plug the fractures in the rock formation. If the fractures are in the production zone, it is also ideal to unplug them when the drilling operation is complete. Therefore, a material engineered to degrade after a desired period would be useful. In examples, a plugging material has been developed by gelling an oil-based fluid using a low molecular weight gelator, dibenzylidene sorbitol (DBS). DBS gels are robust and show plugging behavior. DBS is shown to chemically degrade in presence of an acid. Hence, a self-degrading gel can be synthesized by incorporating an acid into the system. Further, by varying the type and concentration of the acid, the degradation time of the gel can be controlled.

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