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公开(公告)号:US20220098091A1
公开(公告)日:2022-03-31
申请号:US17480394
申请日:2021-09-21
Applicant: CORNING INCORPORATED
Inventor: Xiaoju Guo , Jason Thomas Harris , Kevin Barry Reiman
Abstract: Glass-based articles comprise stress profiles providing improved drop performance. A glass-based substrate comprises: a glass transition temperature (Tg), a liquid fragility index (m), and fictive temperature (Tf), wherein Tg is less than or equal to 650° C., a value of Tf minus Tg is greater than or equal to −30° C., and m is greater than or equal to 25. A stress relaxation rate is greater than or equal to 10%, or 20% or more. The articles can comprise a lithium-based aluminosilicate composition and a fracture toughness that is greater than or equal to 0.75 MPa*m0.5. The stress profiles comprise: a spike region extending from the first surface to a knee; and a tail region extending from the knee to a center of the glass-based article, the tail region comprising: a negative curvature region wherein a second derivative of stress as a function of depth is negative; a depth of compression (DOC) that is greater than or equal to 0.22t, and a parabolic region originating at the DOC and extending to the center of the glass-based article.
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52.
公开(公告)号:US11214515B2
公开(公告)日:2022-01-04
申请号:US16204348
申请日:2018-11-29
Applicant: CORNING INCORPORATED
Inventor: Jason Thomas Harris , Kevin Barry Reiman , Rostislav Vatchev Roussev , Ross Johnson Stewart
IPC: C03C21/00 , C03B27/03 , C03C10/00 , G06F1/16 , C03C27/10 , B32B17/06 , C03B23/203 , C03B17/06 , C03B17/02
Abstract: Glass-based articles having defined stress profiles and methods for manufacturing such glass-based articles are provided. A non-limiting glass-based article comprises an outer region extending from the surface to a depth of compression, wherein the outer region is under a neutral stress or a first compressive stress, a core region under a second compressive stress, the second compressive stress defining a compression peak having a maximum compression value and a maximum width at zero stress in a range of from about 1 micrometer to about 200 micrometers, and an intermediate region disposed between the surface and the core region, wherein the intermediate region is under a tensile stress.
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公开(公告)号:US11149613B2
公开(公告)日:2021-10-19
申请号:US16316906
申请日:2017-07-13
Applicant: Corning Incorporated
Inventor: Rajesh Yogesh Bhargava , Dana Craig Bookbinder , Curtis Richard Cowles , Jacob George , Jason Thomas Harris , Seth Thomas Nickerson , Pushkar Tandon
Abstract: Exhaust gas treatment articles and methods of manufacturing the same are disclosed herein. An exhaust gas treatment article includes a porous ceramic honeycomb body with multiple channel walls defining cell channels that extend in an axial direction and an outer peripheral surface that extends in the axial direction. The exhaust gas treatment article further includes a metal layer that surrounds the porous ceramic honeycomb body and that is in direct contact with at least a portion of the outer peripheral surface of the porous ceramic honeycomb body. The metal layer includes a joint. The exhaust gas treatment article includes a shim that is located under the joint and that is in direct contact with at least a portion of the outer peripheral surface of the porous ceramic honeycomb body.
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54.
公开(公告)号:US11034134B2
公开(公告)日:2021-06-15
申请号:US15773981
申请日:2016-11-04
Applicant: Corning Incorporated
Inventor: Jason Thomas Harris , Guangli Hu , Po-Jen Shih , Bin Zhang , Chunfeng Zhou
IPC: B32B15/04 , B32B17/06 , C03C3/091 , C03C17/02 , C03C21/00 , B32B37/15 , B32B37/14 , C03B17/02 , C03B17/06
Abstract: A laminated glass article includes a glass core layer having a core modulus Ecore and a glass cladding layer adjacent to the core layer and having a cladding modulus Eclad. Eclad can be at least 5 GPa less than Ecore. A modulus ratio Ecore/Eclad can be at least 1.08. The cladding layer can have a compressive stress resulting from a coefficient of thermal expansion (CTE) contrast between the core layer and the cladding layer and/or subjecting the laminated glass article to an ion exchange treatment to form an ion exchanged region at an outer surface of the cladding layer.
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公开(公告)号:US11028014B2
公开(公告)日:2021-06-08
申请号:US16482035
申请日:2018-01-31
Applicant: CORNING INCORPORATED
Inventor: Jason Thomas Harris , Guangli Hu
Abstract: A glass-based substrate having a Young's modulus, a first surface, and a second surface. A coating, on at least one of the first and second surfaces, having a Young's modulus equal to or greater than the substrate Young's modulus. A compressive region having a compressive stress CS of from 750 MPa to 1200 MPa at a surface and extending to a depth of compression (DOC). The compressive region having a first portion and a second portion, the first portion extending from the first surface up to a first depth, the second portion extending from the first depth to the DOC, points in the first portion comprise a tangent having a slope that is less than −15 MPa/micrometers and greater than −60 MPa/micrometers, and points in the second portion comprise a tangent having a slope that is less than or equal to −1 MPa/micrometers and greater than −12 MPa/micrometers.
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公开(公告)号:US20190225538A1
公开(公告)日:2019-07-25
申请号:US16337137
申请日:2017-09-25
Applicant: CORNING INCORPORATED
Inventor: Jason Thomas Harris , Vijay Subramanian , Wei Xu
Abstract: Strengthened glass-based substrates having a first outer region compressive stress and a first side having first coating thereon are disclosed. The first coating comprising a material selected to have a first coating Young's modulus value, a first coating thickness, and a first coating stress that is either neutral or compressive, such that the absolute value of first outer region compressive stress is greater than the absolute value of the first coating stress. Methods of making glass-based articles are provided, and glass-based articles having coatings that provide different strength values and/or reliability on different sides of the glass-based articles are also disclosed.
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57.
公开(公告)号:US20180326704A1
公开(公告)日:2018-11-15
申请号:US15773981
申请日:2016-11-04
Applicant: Corning Incorporated
Inventor: Jason Thomas Harris , Guangli Hu , Po-Jen Shih , Bin Zhang , Chunfeng Zhou
CPC classification number: B32B17/06 , B32B37/144 , B32B2250/03 , B32B2307/546 , B32B2457/20 , B32B2605/00 , C03B17/02 , C03B17/064 , C03C3/091 , C03C17/02 , C03C21/002
Abstract: A laminated glass article includes a glass core layer having a core modulus Ecore and a glass cladding layer adjacent to the core layer and having a cladding modulus Eclad. Eclad can be at least 5 GPa less than Ecore. A modulus ratio Ecore/Eclad can be at least 1.08. The cladding layer can have a compressive stress resulting from a coefficient of thermal expansion (CTE) contrast between the core layer and the cladding layer and/or subjecting the laminated glass article to an ion exchange treatment to form an ion exchanged region at an outer surface of the cladding layer.
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58.
公开(公告)号:US20180304588A1
公开(公告)日:2018-10-25
申请号:US15767789
申请日:2016-10-12
Applicant: Corning Incorporated
Inventor: Jason Thomas Harris , Guangli Hu , John Christopher Mauro
CPC classification number: B32B17/06 , B32B37/144 , B32B2250/03 , B32B2250/40 , C03C21/002
Abstract: A glass laminate includes a glass core layer having a core coefficient of thermal expansion (CTE) and a glass cladding layer adjacent to the core layer and having a cladding CTE that is less than the core CTE such that the core layer is in tension and the cladding layer is in compression. A stress profile of the glass laminate includes a compressive peak disposed between an outer surface of the cladding layer and an inner surface of the cladding layer.
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