Composition of styrene-acrylonitrile copolymer matrix with particles of
graft copolymer and crosslinked copolymer
    52.
    发明授权
    Composition of styrene-acrylonitrile copolymer matrix with particles of graft copolymer and crosslinked copolymer 失效
    苯乙烯 - 丙烯腈共聚物基体与接枝共聚物和交联共聚物颗粒的组成

    公开(公告)号:US5631323A

    公开(公告)日:1997-05-20

    申请号:US567056

    申请日:1995-12-04

    摘要: Thermoplastic molding materials preparedA) from 35 to 99.5% by weight of a matrix copolymer (A) ofa.sub.1) from 50 to 95% by weight of styrene and/or .alpha.-methylstyrene,a.sub.2) from 5 to 50% by weight of acrylonitrile anda.sub.3) from 0 to 20% by weight of further comonomersB) from 0 to 50% by weight of a particulate graft copolymer (B) which is insoluble in (A), has a median particle diameter of from 0.03 to 1 .mu.m and preparedb.sub.1) from 30 to 80% by weight of a core comprising an elastomeric polymer having a glass transition temperature of less than -10.degree. C. andb.sub.2) from 20 to 70% by weight of a graft shell comprising a polymer which is compatible or partly compatible with (A)andC) from 0.5 to 30% by weight of a particulate crosslinked copolymer (C) which is insoluble in (A), has a median particle diameter of from 0.5 to 50 .mu.m and comprisesc.sub.1) from 50 to 89.95% by weight of styrene and/or .alpha.-methylstyrene,c.sub.2) from 10 to 50% by weight of acrylonitrile,c.sub.3) from 0.05 to 5% by weight of a polyfunctional, crosslinking monomer,c.sub.4) from 0 to 10% by weight of a monomer which contains acidic or basic groups andc.sub.5) from 0 to 20% by weight of further comonomers.

    摘要翻译: 制备的热塑性成型材料A)35至99.5重量%的a1)的基质共聚物(A),50-95重量%的苯乙烯和/或α-甲基苯乙烯,a2)5-50重量%的丙烯腈 和a3)0至20重量%的另外的共聚单体B)0至50重量%的不溶于(A)的颗粒接枝共聚物(B),其中值粒径为0.03至1μm 并且制备b1)30至80重量%的芯,其包含玻璃化转变温度低于-10℃的弹性体聚合物,和b2)20至70重量%的包含聚合物的接枝壳,所述聚合物是 与(A)和C)相容或部分相容的0.5至30重量%的不溶于(A)的颗粒状交联共聚物(C),其中值粒径为0.5至50μm,并包含c1) 苯乙烯和/或α-甲基苯乙烯的50至89.95重量%,c2)10至50重量%的丙烯腈,c 3)0.05至5重量% t的多官能交联单体,c4)0至10重量%的含酸性或碱性基团的单体,和c 5)0至20重量%的其它共聚单体。