Thiazolemethine dyes
    52.
    发明授权
    Thiazolemethine dyes 失效
    噻唑甲染料

    公开(公告)号:US5714616A

    公开(公告)日:1998-02-03

    申请号:US722246

    申请日:1996-10-24

    CPC分类号: C09B23/06 C09B23/0091

    摘要: Methine dyes of the formula I ##STR1## where R is hydrogen, unsubstituted or substituted C.sub.1 -C.sub.10 -alkyl or unsubstituted or substituted phenyl, X is nitrogen or a radical of the formula CQ.sup.1, CH.dbd.CQ.sup.1 --CH, CH.dbd.CH--CH.dbd.CH--CH, ##STR2## where Q.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, chlorine or bromine and Q.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, and Y is a radical of the aniline, aminonaphthalene, indole, aminoquinoline, aminothiazole or aminothiophene series, the use thereof in nonlinear optics, and novel thiazole derivatives.

    摘要翻译: PCT No.PCT / EP95 / 01348 Sec。 371日期:1996年10月24日 102(e)日期1996年10月24日PCT提交1995年4月12日PCT公布。 公开号WO95 / 29958 日期:1995年11月9日,式I化合物(I)的甲基染料其中R为氢,未取代或取代的C 1 -C 10 - 烷基或未被取代或取代的苯基,X为氮或式CQ1,CH = CQ1 -CH,CH = CH-CH = CH-CH,其中Q1是氢,C1-C4-烷基,氯或溴,Q2是氢或C1-C4-烷基,Y是苯胺基, 氨基萘,吲哚,氨基喹啉,氨基噻唑或氨基噻吩系列,其在非线性光学中的应用,以及新的噻唑衍生物。

    Preparation of polymers with NLO-active side groups and the use thereof
    54.
    发明授权
    Preparation of polymers with NLO-active side groups and the use thereof 失效
    制备具有NLO-活性侧基的聚合物及其用途

    公开(公告)号:US5483005A

    公开(公告)日:1996-01-09

    申请号:US145601

    申请日:1993-11-04

    摘要: A process for preparing (meth)acrylate polymers with lateral non-linear optical chromophores and molecular weights of from 5000 to 500,000, comprises reacting polymers of (meth)acryloyl isocyanate in solution with D-.omega.-hydroxyalkyl chromophores of the formula (I) ##STR1## where D is an electron donor,A is an electron acceptor,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be identical or different and are each H, alkyl, cycloalkyl, alkoxy or R.sup.3 and R.sup.4 are each CN, NO.sub.2 or CHO or R.sup.1 and R.sup.2, or R.sup.3 and R.sup.4, together form a fused-on ring,X is CH and/or Nandm is an integer from 2 to 11.The products are suitable for optical components in communications technology.

    摘要翻译: 制备具有侧向非线性光学发色团(分子量为5000至500,000)的(甲基)丙烯酸酯聚合物的方法包括使溶液中的(甲基)丙烯酰基异氰酸酯的聚合物与式(I)的D-ω-羟烷基发色团反应, (I)其中D是电子给体,A是电子受体,R 1,R 2,R 3和R 4可以相同或不同,并且各自为H,烷基,环烷基,烷氧基或R 3和R 4各自为CN,NO 2或 CHO或R1和R2或R3和R4一起形成稠合环,X为CH和/或N,m为2至11的整数。该产品适用于通信技术中的光学组件。

    Liquid-crystalline polymers of virtually uniform molecular weight
    55.
    发明授权
    Liquid-crystalline polymers of virtually uniform molecular weight 失效
    几乎均匀分子量的液晶聚合物

    公开(公告)号:US5332520A

    公开(公告)日:1994-07-26

    申请号:US880578

    申请日:1992-05-08

    CPC分类号: C09K19/3857 C08F20/30

    摘要: A liquid-crystalline polymer of virtually uniform molecular weight, obtainable by polymerizing identical or different monomers of the formula I ##STR1## where R is hydrogen, chlorine or methyl,A is a flexible, long-chain moiety which acts as a spacer, is a mesogenic moiety built up from at least two aromatic rings which are linked to one another in a linear or approximately linear manner, andC is an optically active, chiral moiety,in from 0.01 to 0.1 molar solution in an inert organic solvent in the presence of from 1 to 40 mol %, based on the monomers, of a free-radical initiator, at from 40.degree. to 60.degree. C. for from 100 to 140 hours, and subsequently isolating the polymerization product from the reaction mixture, and the use thereof for building up recording layers for laser-optical and electrical recording elements and for electrophotography and for building up liquid-crystalline display elements.

    摘要翻译: 通过聚合相同或不同的式I的单体得到的具有实质上均匀分子量的液晶聚合物,其中R是氢,氯或甲基,A是作为间隔基的柔性长链部分, 是由至少两个芳族环构成的介晶部分,其以线性或近似线性的方式彼此连接,C是光学活性的手性部分,在惰性有机溶剂中的0.01至0.1摩尔溶液 在40至60℃下,在100至140小时内,以单体为基础,存在1至40摩尔%的自由基引发剂,随后从反应混合物中分离出聚合产物, 其用于建立用于激光光学和电气记录元件的记录层和用于电子照相和用于构建液晶显示元件。

    Thiopheneazo dye based on a coupling component of the thiazole series
    57.
    发明授权
    Thiopheneazo dye based on a coupling component of the thiazole series 失效
    噻吩偶氮染料基于噻唑系的偶联成分

    公开(公告)号:US5216139A

    公开(公告)日:1993-06-01

    申请号:US620457

    申请日:1990-12-04

    IPC分类号: C09B29/00 C09B29/36 C09B31/14

    摘要: Thiopheneazo dyes of the formula ##STR1## where R.sup.1 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, phenylazo, phenylsulfonyl, formyl or the radical ##STR2## where R.sup.7 and R.sup.8 are independently of the other cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl, halogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are the radical (CH.sub.2).sub.3 --CO, which may be substituted by 1 or 2 methyl groups and whose carbonyl group is bonded to the thiophene ring in the ortho position relative to the sulfur atom,R.sup.3 is cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, cyclohexyl, phenoxy-C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, or substituted or unsubstituted thienyl,R.sup.5 is C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.7 -alkyl whose alkyl chain is interrupted by 1 or 2 oxygen atoms, or C.sub.1 -C.sub.4 -alkoxy andR.sup.6 is cyanoethyl, phenylethyl or C.sub.3 -C.sub.12 -alkyl whose alkyl chain is interrupted by from 1 to 4 oxygen atoms and which may be substituted by phenyl or phenoxy,with the proviso that, when R.sup.5 and R.sup.6 are each oxygen-interrupted alkyl, R.sup.6 has 2 or more carbon atoms more than R.sup.5, are used for dyeing textile fibers.

    摘要翻译: 其中R 1为氰基,C 1 -C 4 - 烷氧基羰基,苯偶氮,苯磺酰基,甲酰基或基团,其中R 7和R 8独立于其它氰基或C 1 -C 4 - 烷氧基羰基,R 2为C 1的噻吩偶氮染料 -C 1-4烷基,苯基,卤素,C 1 -C 4 - 烷氧基或C 1 -C 4烷氧基羰基,或者R 1和R 2一起是可被1或2个甲基取代的基团(CH 2)3 -CO,其羰基 R 3是氰基或C 1 -C 4烷氧基羰基,R 4是C 1 -C 8 - 烷基,环己基,苯氧基-C 1 -C 4烷基,取代或未取代的苯基,或 取代或未取代的噻吩基,R 5是C 1 -C 4 - 烷基,其烷基被1或2个氧原子间隔的C 3 -C 7 - 烷基或C 1 -C 4 - 烷氧基,R 6是氰基乙基,苯基乙基或C 3 -C 12 - 链被1至4个氧原子中断并且可以被苯基或苯氧基取代,条件是当R5和R6各自为氧中断的烷基时 l,R6具有比R5多2个或更多个碳原子,用于染色纺织纤维。

    Monomers and their use for the production of a laser-optical recording
element which can be repeatedly erased and recorded on
    58.
    发明授权
    Monomers and their use for the production of a laser-optical recording element which can be repeatedly erased and recorded on 失效
    单体及其用于生产可以反复擦除并记录的激光光学记录元件

    公开(公告)号:US5212027A

    公开(公告)日:1993-05-18

    申请号:US814517

    申请日:1991-12-30

    摘要: Novel laser-optical recording elements which can be repeatedly erased and recorded on contain recording layers (a) which exhibit enantiotropic, ferroelectric smectic liquid crystalline (S.sub.c*) behavior, so that they can be switched back and forth between two thermodynamically stable, optically distinguishable ferroelectric smectic liquid crystalline S.sub.c* order states on exposure to a laser beam of sufficient luminous power, by applying an external electric field. The recording layers (a) themselves consist mainly or exclusively of novel polymers P having chiral mesogenic side groups. The novel polymers P are prepared using the novel monomers of the general formula I ##STR1## where R is hydrogen, chlorine or methyl, A is a flexible space-maintaining long-chain molecular moiety, and C is an optically active chiral molecular moiety and B is a mesogenic molecular moiety composed of at least three aromatic nuclei which are bonded linearly or virtually linearly to one another,or they are prepared using the novel monomers I which contain specially selected molecular moieties B in a novel combination with selected molecular moieties C.

    摘要翻译: 可以重复地擦除并记录包含记录层(a)的新型激光 - 光学记录元件,其表现出对称性,铁电近晶液晶(Sc *)行为,使得它们可以在两个热力学稳定的光学可区分之间来回切换 通过施加外部电场,暴露于具有足够发光功率的激光束的铁电近晶液晶Sc *阶数。 记录层(a)本身主要或全部由具有手性介晶侧基的新型聚合物P组成。 新型聚合物P使用通式I(I)的新型单体制备,其中R是氢,氯或甲基,A是柔性保持空间的长链分子部分,C是光学活性的手性 分子部分和B是由至少三个芳族核组成的介晶分子部分,其彼此线性或实质上线性地键合,或者它们使用含有特定选择的分子部分B的新型单体I与选择的分子 部分C.

    Azo dyes for thermotransfer printing
    59.
    发明授权
    Azo dyes for thermotransfer printing 失效
    用于热转印打印的AZO染色

    公开(公告)号:US5200386A

    公开(公告)日:1993-04-06

    申请号:US708371

    申请日:1991-05-31

    摘要: Azo dyes useful for thermotransfer printing have the formula ##STR1## where the substituents have the following meanings: X is a radical of the formula IIa or IIb ##STR2## R.sup.1 is H, C.sub.1 -C.sub.6 -alkyl or phenyl which may be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.2 -alkoxy, chlorine, bromine or cyano,R.sup.2 is H, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine or bromine, n is 1 or 2, K is a radical of a coupling component IIH--K III of the aniline, aminonaphthaline, pyrazole, diaminopyridine, hydroxypyridone or tetrahydroquinoline series.

    摘要翻译: 可用于热转印印刷的偶氮染料具有式(I)其中取代基具有以下含义:X是式IIa或IIb的基团R 1 O(CH 2)或者IIa IIb R 1是H,C 1 -C 6烷基 或可被C 1 -C 4 - 烷基,C 1 -C 2 - 烷氧基,氯,溴或氰基取代的苯基,R 2为H,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,氯或溴,n为1或2 K是苯胺,氨基萘,吡唑,二氨基吡啶,羟基吡啶酮或四氢喹啉系的偶联组分II HK III的基团。

    Malonic acid dyes and polycondensation products thereof
    60.
    发明授权
    Malonic acid dyes and polycondensation products thereof 失效
    马来酸染料及其聚合产品

    公开(公告)号:US5162545A

    公开(公告)日:1992-11-10

    申请号:US596385

    申请日:1990-10-12

    摘要: Malonic acid dyes capable of forming polycondensation products have the formula ##STR1## where R.sup.1 and R.sup.2 are each independently of the other hydroxyl, C.sub.1 -C.sub.6 -alkoxy, chlorine or bromine,R.sup.3 is hydrogen or C.sub.1 -C.sub.6 -alkyl,A is C.sub.1 -C.sub.20 -alkylene which may be interrupted by oxygen atoms or by imino or C.sub.1 -C.sub.4 -alkylimino groups, andChr is the radical of a chromophore derived from an anthraquinone, perylene, disazo or trisazo dye or else, when R.sup.3 is C.sub.1 -C.sub.6 -alkyl, from a monoazo dye.

    摘要翻译: 能够形成缩聚产物的丙烯酸染料具有式“IMAGE”,其中R 1和R 2各自独立地为其它羟基,C 1 -C 6烷氧基,氯或溴,R 3为氢或C 1 -C 6烷基,A为C1- 可以被氧原子或亚氨基或C 1 -C 4烷基亚氨基封闭的C 20 - 亚烷基,Chr是衍生自蒽醌,苝,二偶氮或三偶氮染料的发色团的基团,或者当R 3是C 1 -C 6 - 烷基,来自单偶氮染料。