摘要:
Phenol derivatives of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, X, Y and Z have the meanings stated in the description, are used in particular in nonlinear optics.
摘要:
Methine dyes of the formula I ##STR1## where R is hydrogen, unsubstituted or substituted C.sub.1 -C.sub.10 -alkyl or unsubstituted or substituted phenyl, X is nitrogen or a radical of the formula CQ.sup.1, CH.dbd.CQ.sup.1 --CH, CH.dbd.CH--CH.dbd.CH--CH, ##STR2## where Q.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, chlorine or bromine and Q.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, and Y is a radical of the aniline, aminonaphthalene, indole, aminoquinoline, aminothiazole or aminothiophene series, the use thereof in nonlinear optics, and novel thiazole derivatives.
摘要:
Azo dyes of the formulaW(--X--Y--Chr).sub.n,wheren is 2 to 6,y is C.sub.1 -C.sub.6 -alkylene,Chr is the radical of a mono- or polyazo dye,X is a radical of the formula CO--O or O--CO andW is an n-valent radical which is derived from an unsubstituted or substituted C.sub.2 -C.sub.20 -alkane, an unsubstituted or substituted C.sub.4 -C.sub.7 -cycloalkane, an unsubstituted or substituted benzene or an unsubstituted or substituted naphthalene, or, if n is 4, is also silicon,and their use in nonlinear optics or for dyeing or printing textile materials are described.
摘要:
A process for preparing (meth)acrylate polymers with lateral non-linear optical chromophores and molecular weights of from 5000 to 500,000, comprises reacting polymers of (meth)acryloyl isocyanate in solution with D-.omega.-hydroxyalkyl chromophores of the formula (I) ##STR1## where D is an electron donor,A is an electron acceptor,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be identical or different and are each H, alkyl, cycloalkyl, alkoxy or R.sup.3 and R.sup.4 are each CN, NO.sub.2 or CHO or R.sup.1 and R.sup.2, or R.sup.3 and R.sup.4, together form a fused-on ring,X is CH and/or Nandm is an integer from 2 to 11.The products are suitable for optical components in communications technology.
摘要:
A liquid-crystalline polymer of virtually uniform molecular weight, obtainable by polymerizing identical or different monomers of the formula I ##STR1## where R is hydrogen, chlorine or methyl,A is a flexible, long-chain moiety which acts as a spacer, is a mesogenic moiety built up from at least two aromatic rings which are linked to one another in a linear or approximately linear manner, andC is an optically active, chiral moiety,in from 0.01 to 0.1 molar solution in an inert organic solvent in the presence of from 1 to 40 mol %, based on the monomers, of a free-radical initiator, at from 40.degree. to 60.degree. C. for from 100 to 140 hours, and subsequently isolating the polymerization product from the reaction mixture, and the use thereof for building up recording layers for laser-optical and electrical recording elements and for electrophotography and for building up liquid-crystalline display elements.
摘要:
One or more indoaniline dyes are transferred from a transfer to a sheet of plastic-coated paper by diffusion or sublimation with the aid of an energy source, said indoaniline dyes having the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each independently of the others hydrogen, methyl, fluorine or chlorine,X is fluorine or chlorine, andK is an aromatic radical.
摘要:
Thiopheneazo dyes of the formula ##STR1## where R.sup.1 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, phenylazo, phenylsulfonyl, formyl or the radical ##STR2## where R.sup.7 and R.sup.8 are independently of the other cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl, halogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are the radical (CH.sub.2).sub.3 --CO, which may be substituted by 1 or 2 methyl groups and whose carbonyl group is bonded to the thiophene ring in the ortho position relative to the sulfur atom,R.sup.3 is cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, cyclohexyl, phenoxy-C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, or substituted or unsubstituted thienyl,R.sup.5 is C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.7 -alkyl whose alkyl chain is interrupted by 1 or 2 oxygen atoms, or C.sub.1 -C.sub.4 -alkoxy andR.sup.6 is cyanoethyl, phenylethyl or C.sub.3 -C.sub.12 -alkyl whose alkyl chain is interrupted by from 1 to 4 oxygen atoms and which may be substituted by phenyl or phenoxy,with the proviso that, when R.sup.5 and R.sup.6 are each oxygen-interrupted alkyl, R.sup.6 has 2 or more carbon atoms more than R.sup.5, are used for dyeing textile fibers.
摘要:
Novel laser-optical recording elements which can be repeatedly erased and recorded on contain recording layers (a) which exhibit enantiotropic, ferroelectric smectic liquid crystalline (S.sub.c*) behavior, so that they can be switched back and forth between two thermodynamically stable, optically distinguishable ferroelectric smectic liquid crystalline S.sub.c* order states on exposure to a laser beam of sufficient luminous power, by applying an external electric field. The recording layers (a) themselves consist mainly or exclusively of novel polymers P having chiral mesogenic side groups. The novel polymers P are prepared using the novel monomers of the general formula I ##STR1## where R is hydrogen, chlorine or methyl, A is a flexible space-maintaining long-chain molecular moiety, and C is an optically active chiral molecular moiety and B is a mesogenic molecular moiety composed of at least three aromatic nuclei which are bonded linearly or virtually linearly to one another,or they are prepared using the novel monomers I which contain specially selected molecular moieties B in a novel combination with selected molecular moieties C.
摘要:
Azo dyes useful for thermotransfer printing have the formula ##STR1## where the substituents have the following meanings: X is a radical of the formula IIa or IIb ##STR2## R.sup.1 is H, C.sub.1 -C.sub.6 -alkyl or phenyl which may be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.2 -alkoxy, chlorine, bromine or cyano,R.sup.2 is H, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine or bromine, n is 1 or 2, K is a radical of a coupling component IIH--K III of the aniline, aminonaphthaline, pyrazole, diaminopyridine, hydroxypyridone or tetrahydroquinoline series.
摘要:
Malonic acid dyes capable of forming polycondensation products have the formula ##STR1## where R.sup.1 and R.sup.2 are each independently of the other hydroxyl, C.sub.1 -C.sub.6 -alkoxy, chlorine or bromine,R.sup.3 is hydrogen or C.sub.1 -C.sub.6 -alkyl,A is C.sub.1 -C.sub.20 -alkylene which may be interrupted by oxygen atoms or by imino or C.sub.1 -C.sub.4 -alkylimino groups, andChr is the radical of a chromophore derived from an anthraquinone, perylene, disazo or trisazo dye or else, when R.sup.3 is C.sub.1 -C.sub.6 -alkyl, from a monoazo dye.