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    Formylaminophenylsulfonylureas, preparation processes and use as herbicides and plant growth regulators
    51.
    发明授权
    Formylaminophenylsulfonylureas, preparation processes and use as herbicides and plant growth regulators 失效
    甲酰氨基苯基磺酰脲，制备方法和用作除草剂和植物生长调节剂

    公开(公告)号：US5747421A

    公开(公告)日：1998-05-05

    申请号：US453978

    申请日：1995-05-30

    申请人： Gerhard Schnabel ,  Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer ,  Christopher Rosinger

    发明人： Gerhard Schnabel ,  Lothar Willms ,  Klaus Bauer ,  Hermann Bieringer ,  Christopher Rosinger

    IPC分类号： C07D251/16 ,  A01N47/36 ,  C07D239/42 ,  C07D251/46 ,  C07D251/50 ,  C07D405/12 ,  C07D521/00 ,  C07D239/69 ,  A01N43/54

    CPC分类号： C07D521/00 ,  A01N47/36

    摘要： Formylaminophenylsulfonylureas; processes for their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) ##STR1## in which R.sup.1 is H, a substituted or unsubstituted hydrocarbon radical or an unsubstituted or substituted heterocyclic radical, R.sup.2 is H, (C.sub.1 -C.sub.6)-alkyl or (C.sub.1 -C.sub.6)-alkoxy, R.sup.3 is halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy, (C.sub.1 -C.sub.6)-haloalkyl, (C.sub.1 -C.sub.6)-haloalkoxy, NO.sub.2, CN, NH.sub.2, (C.sub.1 -C.sub.4) -mono- or dialkylamino, each independently of other radicals R.sup.3 if n is 2 or 3, n is 0, 1, 2 or 3, W is an oxygen atom or a sulfur atom, X and Y independently of one another are halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy or (C.sub.1 -C.sub.6)-alkylthio, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C.sub.1 -C.sub.4)-alkoxy and (C.sub.1 -C.sub.4)-alkylthio, or are (C.sub.3 -C.sub.6)-cycloalkyl, (C.sub.2 -C.sub.6)-alkenyl, (C.sub.2 -C.sub.6)-alkynyl, (C.sub.2 -C.sub.6)-alkenyloxy, (C.sub.2 -C.sub.6)-alkynyloxy, mono- or di�(C.sub.1 -C.sub.4 -alkyl)!amino, and Z is CH or N, are suitable as herbicides and plant growth regulators. The compounds (I) can be prepared by processes analogous to known processes whereby some novel intermediates of formula (II) are used.

    摘要翻译： 甲酰氨基苯基磺酰脲 其制备方法及其作为除草剂和植物生长调节剂的用途式（I）取代烃基或未取代或取代的杂环基的化合物，R2是H，（C1-C6） - 烷基或（C1-C6） - 烷氧基，R 3为卤素，（C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基，（C 1 -C 6） - 卤代烷基，（C 1 -C 6） - 卤代烷氧基，NO 2，CN，NH 2，（C 1 -C 4） 单或二烷基氨基，如果n为2或3，各自独立地为其它基团，n为0,1,2或3，W为氧原子或硫原子，X和Y彼此独立地为卤素，（C1 （C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基或（C 1 -C 6） - 烷硫基，三个最后提到的基团中的每一个是未取代的或被一个或多个选自卤素，（C1- 或（C 1 -C 6） - 烷硫基，或者是（C 3 -C 6） - 环烷基，（C 2 -C 6） - 烯基，（C 2 -C 6） - 炔基，（C 2 -C 6） - 炔基氧基，（C 2 -C 6） C6） - 炔氧基，单或二[（C1-C4烷基）]氨基，Z为CH或N，适合作为除草剂和植物生长调节剂。 化合物（I）可以通过类似于已知方法的方法制备，由此使用一些新的式（II）中间体。

    Methods of Controlling Undesirable Vegetation with Imidazolinone Herbicides and Adjuvants in Herbicide Resistant Crop Plants
    54.
    发明申请
    Methods of Controlling Undesirable Vegetation with Imidazolinone Herbicides and Adjuvants in Herbicide Resistant Crop Plants 审中-公开
    防除除草剂作物植物中咪唑啉酮除草剂和佐剂的不良植被控制方法

    公开(公告)号：US20140336051A1

    公开(公告)日：2014-11-13

    申请号：US14362271

    申请日：2012-11-14

    申请人： Gerhard Schnabel ,  Matthias Pfenning ,  Joerg Polzin ,  Hagen Bremer

    发明人： Gerhard Schnabel ,  Matthias Pfenning ,  Joerg Polzin ,  Hagen Bremer

    IPC分类号： A01N25/30 ,  A01N43/50

    CPC分类号： A01N25/30 ,  A01N43/50 ,  A01N2300/00

    摘要： A herbicidal composition comprising: a) a herbicide compound A, which is selected from the group of imidazolinones; and b) an adjuvant B, which is a surfactant selected from the groups b1 to b5: b1) a nonionic surfactant of the formula R1Xn and polyalkoxylated derivatives thereof, wherein R1 is selected from aliphatic or aromatic residues having at least eight carbon atoms; X is selected from hydroxy, —O—(C1-C6-alkyl), —O—(C3-C6-alkenyl), amine, amide, or ester; and n is 1, 2, 3, 4, 5 or 6; b2) an anionic surfactant of the formula R1Yn, wherein R1 is selected from aliphatic or aromatic residues having at least eight carbon atoms; Y is selected from carboxylate, sulfonate, sulfate, phosphate, or phosphonate; and n is 1, 2, 3, 4, 5 or 6; b3) a cationic surfactant; b4) a zwitterionic surfactant; or b5) a polymeric surfactant; and wherein the weight ratio of the herbicide compound A and the adjuvant B is from 2:1 to 1:60; and the use of the said compositions for controlling undesirable vegetation.

    摘要翻译： 一种除草组合物，其包含：a）除草剂化合物A，其选自咪唑啉酮; 和b）佐剂B，其为选自b1至b5族的表面活性剂：b1）式R1Xn的非离子表面活性剂和其聚烷氧基化衍生物，其中R1选自具有至少8个碳原子的脂族或芳族残基; X选自羟基，-O-（C 1 -C 6 - 烷基），-O-（C 3 -C 6 - 烯基），胺，酰胺或酯; n为1,2,3,4,5或6; b2）式R1Yn的阴离子表面活性剂，其中R 1选自具有至少8个碳原子的脂族或芳族残基; Y选自羧酸盐，磺酸盐，硫酸盐，磷酸盐或膦酸盐; n为1,2,3,4,5或6; b3）阳离子表面活性剂; b4）两性离子表面活性剂; 或b5）聚合物表面活性剂; 并且其中除草剂化合物A和佐剂B的重量比为2:1至1:60; 以及使用所述组合物来控制不期望的植被。

    Copolymers of N-vinylcarboxamide and diallyldialkylammonium salt as dispersant for agrochemical formulations
    56.
    发明申请
    Copolymers of N-vinylcarboxamide and diallyldialkylammonium salt as dispersant for agrochemical formulations 审中-公开
    N-乙烯基甲酰胺和二烯丙基二烷基铵盐的共聚物作为农业化学制剂的分散剂

    公开(公告)号：US20140080702A1

    公开(公告)日：2014-03-20

    申请号：US14122469

    申请日：2012-05-24

    申请人： Gerhard Schnabel ,  Ruth Wirschem ,  Paul Klingelhoefer ,  Lucelena Patricio Cardoso

    发明人： Gerhard Schnabel ,  Ruth Wirschem ,  Paul Klingelhoefer ,  Lucelena Patricio Cardoso

    IPC分类号： A01N25/10 ,  C05G3/02 ,  A01N43/56

    CPC分类号： A01N25/10 ,  A01N25/04 ,  A01N25/30 ,  A01N43/56 ,  A01N47/24 ,  C05G3/02 ,  A01N57/20 ,  A01N2300/00

    摘要： The present invention relates to a composition comprising an agrochemical active substance and a copolymer which comprises an N-vinylcarboxamide and a diallyldialkylammonium salt incorporated into the polymer. The invention furthermore relates to a method of preparing this composition; to the use of this composition for dispersing agrochemical active substances; to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and furthermore to seed comprising the composition.

    摘要翻译： 本发明涉及包含农药活性物质和共聚物的组合物，其包含N-乙烯基甲酰胺和掺入聚合物中的二烯丙基二烷基铵盐。 本发明还涉及一种制备该组合物的方法; 使用该组合物分散农药活性物质; 涉及一种控制植物病原真菌和/或不期望的植物生长和/或不期望的昆虫或螨攻击和/或调节植物生长的方法，其中允许组合物作用于相应的害虫，其环境或作物植物上 在相应的有害生物，土壤和/或不需要的植物和/或作物植物和/或其环境上受到保护; 以及包含该组合物的种子。

    Composition Comprising a Pesticide and an Alkoxylate of Iso-nonylamine
    57.
    发明申请
    Composition Comprising a Pesticide and an Alkoxylate of Iso-nonylamine 有权
    包含农药和异壬胺的烷氧基化物的组合物

    公开(公告)号：US20110230342A1

    公开(公告)日：2011-09-22

    申请号：US13048946

    申请日：2011-03-16

    申请人： Paul Klingelhoefer ,  Sophie Vogel ,  Kevin Huyghe ,  Gerd Haderlein ,  Gerhard Schnabel ,  Marc Nolte ,  Richard Roger Evans

    发明人： Paul Klingelhoefer ,  Sophie Vogel ,  Kevin Huyghe ,  Gerd Haderlein ,  Gerhard Schnabel ,  Marc Nolte ,  Richard Roger Evans

    IPC分类号： A01N57/18 ,  A01C1/06 ,  A01P13/00

    CPC分类号： A01N25/30 ,  A01N25/22 ,  A01N57/20

    摘要： The present invention relates to a composition comprising a pesticide and an alkoxylate. Moreover, the invention relates to the alkoxylate, to a process for its preparation and to its use as adjuvant in pesticide-comprising spray mixtures. The invention furthermore relates to a method of controlling phytopathogenic fungi and/or undesired vegetation and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the plants to be protected from the respective pest, on the soil and/or on undesirable plants and/or the crop plants and/or their environment. Furthermore, the invention relates to seed comprising the composition.

    摘要翻译： 本发明涉及包含农药和烷氧基化物的组合物。 此外，本发明涉及烷氧基化物，其制备方法及其作为含农药喷雾混合物中的佐剂的用途。 本发明还涉及一种控制植物病原真菌和/或不期望的植物和/或不期望的昆虫或螨攻击和/或调节植物生长的方法，其中允许组合物作用于相应的害虫，其环境或 要保护的植物免受相应的害虫，土壤和/或不合需要的植物和/或作物植物和/或其环境的影响。 此外，本发明涉及包含该组合物的种子。

    Agrochemical Formulations Comprising A Pesticide, An Organic UV-Photoprotective Filter And Coated Metal-Oxide Nanoparticles
    58.
    发明申请
    Agrochemical Formulations Comprising A Pesticide, An Organic UV-Photoprotective Filter And Coated Metal-Oxide Nanoparticles 有权
    农药组合物，有机紫外光保护性过滤器和涂层金属氧化物纳米粒子

    公开(公告)号：US20110111957A1

    公开(公告)日：2011-05-12

    申请号：US12999912

    申请日：2009-06-15

    申请人： Michael Ishaque ,  Gerhard Schnabel ,  Douglas D. Anspaugh

    发明人： Michael Ishaque ,  Gerhard Schnabel ,  Douglas D. Anspaugh

    IPC分类号： A01N25/26 ,  A01N25/32 ,  A01P3/00 ,  A01P5/00 ,  A01P7/04 ,  A01P13/00

    CPC分类号： A01N25/22 ,  A01N25/04 ,  A01N25/28 ,  A01N47/34 ,  A01N59/16

    摘要： The present invention relates to an agrochemical formulation comprising a pesticide, an organic UV photoprotective filter and coated metal oxide nanoparticles. It also relates to a method for preparing said formulation. Further on, it also relates to the use of a mixture of an organic UV photoprotective filter and coated metal oxide nanoparticles in agrochemical formulations and the use of a agrochemical formulation according to the invention for stabilizing a pesticide against UV irradiation. Further on, it relates to a method of combating harmful insects and/or phytopathogenic fungi, which comprises contacting plants, soil or habitat of plants in or on which the harmful insects and/or phytopathogenic fungi are growing or may grow, plants or soil to be protected from attack or infestation by said harmful insects and/or phytopathogenic fungi with an effective amount of the formulation according to the invention, to a method of controlling undesired vegetation, which comprises allowing a herbicidal effective amount of said formulation to act on plants, their habitat.

    摘要翻译： 本发明涉及包含农药，有机UV光保护性过滤器和被覆金属氧化物纳米粒子的农药制剂。 它还涉及制备所述制剂的方法。 此外，它还涉及在农业化学制剂中使用有机UV光保护性过滤器和包被的金属氧化物纳米颗粒的混合物，以及使用根据本发明的农药制剂来稳定农药抗紫外线照射。 此外，它涉及一种防治有害昆虫和/或植物病原真菌的方法，其包括将有害昆虫和/或植物病原真菌正在生长或可能生长的植物，植物或土壤的植物，土壤或栖息地接触植物或土壤， 通过有效量的根据本发明的制剂的有害昆虫和/或植物病原性真菌的侵害或侵扰来防止不期望的植物的防治方法，其包括使除草有效量的所述制剂作用于植物， 他们的栖息地

    Processes for preparing aminophenylsulfonylureas, and intermediates therefor
    60.
    发明授权
    Processes for preparing aminophenylsulfonylureas, and intermediates therefor 失效

    公开(公告)号：US07057043B2

    公开(公告)日：2006-06-06

    申请号：US10936180

    申请日：2004-09-08

    申请人： Gerhard Schnabel ,  Jan Vermehren ,  Lothar Willms

    发明人： Gerhard Schnabel ,  Jan Vermehren ,  Lothar Willms

    IPC分类号： C07D239/02

    CPC分类号： C07D521/00 ,  A01N47/36 ,  H01R33/06 ,  Y02A40/143

    摘要： The invention relates to the preparation of compounds (I) in which A=H or acyl and R1, R2, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) R*═OH, R**═NR1R2  (II) R*═NR1R2, R**═Cl  (III) R*═NR1R2, R**═NH2  (IV) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)-Het, where Ar=phenyl, M=H or cation and Het=heterocycle from formula (I), to give compounds (I) (A=H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A=H), or c) reaction of (III) with cyanates and amines (V) of the formula HNR3−Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A=H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A=H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.