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51.发明授权
公开(公告)号：US5994255A
公开(公告)日：1999-11-30
申请号：US114109
申请日：1998-07-11
IPC分类号： C07F17/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F10/00 , B01V31/00 , B01J37/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/619 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , Y10S526/943
摘要： Catalysts for olefin polymeriztion comprising metal complexes corresponding to the formula: ##STR1## or a dimer, solvated adduct, chelated derivative or mixture thereof, wherein:L is a cyclic group or Y*, that is bound to M by means of a delocalized .pi.-bond, said group containing up to 50 nonhydrogen atoms;L' is a cyclic group or Y* that is bound to M by means of a delocalized .pi.-bond, said group containing up to 50 nonhydrogen atoms;M is a metal of Group 4 of the Periodic Table of the Elements;Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, --(ER.sub.2).sub.m --, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of hydrocarbyl, hydrocarbyloxy, silyl, and germyl of up to 20 atoms other than hydrogen, and m is an integer from 1 to 3;Y* is an allyl or a hydrocarbyl-, silyl- or germyl-substituted allyl group containing up to 20 nonhydrogen atoms bonded to Z and bonded via an .eta..sup.3 -.pi. bond to M;where Y' is an allyl group or a hydrocarbyl-, silyl-, or germyl-substituted allyl group containing up to 20 nonhydrogen atoms bonded via an .eta..sup.3 -.pi. bond to M;X' is a neutral conjugated diene ligand having up to 20 non-hydrogen atoms;X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl group;n is a number from 0 to 3; andp is an integer from 0 to 2.
摘要翻译： 用于烯烃聚合的催化剂，其包含对应于下式的金属络合物：二聚体，溶剂化加合物，螯合衍生物或其混合物，其中：L是通过离域π键与M结合的环状基团或Y * 该基团含有多达50个非氢原子; L'是通过离域pi键与M结合的环状基团或Y *，所述基团含有多达50个非氢原子; M是元素周期表第4族的金属; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地每次出现为碳，硅或锗，R各自独立地选自 烃基，烃氧基，甲硅烷基和除氢以外的至多20个原子的甲锗烷基，m是1至3的整数; Y *是含有至多20个非氢原子的烯丙基或烃基 - 甲硅烷基或甲锗烷基取代的烯丙基，其与Z键合并通过η3键连接至M; 其中Y'是含有至多20个非氢原子的烯基或烃基，甲硅烷基或或锗基取代的烯丙基，其通过η3键与M键合; X'是具有至多20个非氢原子的中性共轭二烯配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X 一起形成二价烃基; n是从0到3的数字; p为0〜2的整数。
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公开(公告)号：US5670680A
公开(公告)日：1997-09-23
申请号：US638256
申请日：1996-04-26
申请人： Thomas H. Newman , Jerzy Klosin , Peter N. Nickias
发明人： Thomas H. Newman , Jerzy Klosin , Peter N. Nickias
CPC分类号： C07F17/00 , Y10S526/943
摘要： Octahydrofluorenyl metal complexes, such as octahydrofluorenyltitanium trichloride, or ring substituted octahydrofluorenyl metal complexes wherein the metal is in the +2, +3 or +4 formal oxidation state are prepared by reduction of tetra- or hexa-hydrofluorenyl metal complexes. The reduction reaction may be carried out at ambient pressure and temperature in the presence of a catalyst. The process of the present invention permits preparation of octahydrofluorenyltitanium metal complexes from a series of high yield reactions starting with fluorene.
摘要翻译： 八氢芴基三氯化钛的八氢芴基金属络合物或其中金属为+2，+3或+4形式氧化态的环取代的八氢芴基金属络合物通过还原四或六氢芴基金属络合物来制备。 还原反应可以在环境压力和温度下在催化剂存在下进行。 本发明的方法允许从芴开始的一系列高产率反应制备八氢芴基钛金属络合物。
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53.发明授权Process for preparing addition polymerization catalysts via metal center oxidation 失效通过金属中心氧化制备添加剂聚合催化剂的方法
公开(公告)号：US5189192A
公开(公告)日：1993-02-23
申请号：US642111
申请日：1991-01-16
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/6592 , Y10S526/943
摘要： Addition polymerization catalysts comprising a derivative of a Group 4-8 metal compound prepared by metal center oxidation.
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