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公开(公告)号：US5073284A
公开(公告)日：1991-12-17
申请号：US624877
申请日：1990-12-05
IPC分类号： C07F9/6581 , C10M105/74
CPC分类号： C07F9/65814 , C10M105/74 , C10M2223/00 , C10M2223/02 , C10M2223/049 , C10M2223/08 , C10N2240/08
摘要： A hydraulic fluid that remains solids-free at temperatures as low as about -30.degree. C. and has a pour point as low as about -42.degree. C. comprises a cyclic phosphazene oligomer mixture, the structural formula of each molecule of which contains 3 or 4 units selected at random from the group consisting of ##STR1## wherein R is a fluoroalkoxy group --OCH.sub.2 (CF.sub.2).sub.m CF.sub.2 Z, where Z is hydrogen or fluorine, and m is 0 or an integer from 1 to 10; R' and R" are different alkoxyalkyloxy groups in which linear or branched C.sub.1-12 alkoxy is substituted with linear or branched C.sub.1-12 alkoxy; with the proviso that all of R, R' and R" are present in the oligomer mixture.
摘要翻译： 在低至约-30℃的温度下保持无固体并且具有低至约-42℃的倾点的液压流体包含环状磷腈低聚物混合物，其每个分子的结构式含有3 或由4个单元组成的组，其中R是氟烷氧基-OCH 2（CF 2）m CF 2 Z，其中Z是氢或氟，m是0或1至10的整数; R'和R“是不同的烷氧基烷氧基，其中直链或支链C 1-12烷氧基被直链或支链C 1-12烷氧基取代; 条件是R，R'和R“全部存在于低聚物混合物中。
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公开(公告)号：US4898929A
公开(公告)日：1990-02-06
申请号：US265991
申请日：1988-11-02
IPC分类号： C08G79/02
CPC分类号： C08G79/025
摘要： Substantially linear organophosphazene polymers containing randomly distributed repeating units represented by the formulas: ##STR1## wherein R.sub.1 is a fluoroalkoxy group having the structure:F.sub.3 C--(CF.sub.2).sub.n --CH.sub.2 O--wherein n is 0 or an integer from 1 to 20 and X is fluorine and wherein at least 3 of the R.sub.1 units are different from each other and R.sub.2 represents a group with some unsaturation which enhances the curability of said polymers and represented by the formula: ##STR2## wherein R.sub.3 is an unsaturated monovalent group and R.sub.4 is selected from the group consisting of hydrogen, alkyl and alkoxy, the total number of said units ranging from 3 to about 100,000 and the R.sub.2 groups being present in an amount sufficient to enable cure of said polymers and in the range of about 0.01-50 mole percent of the total number of R.sub.1 and R.sub.2 groups are claimed. The polymers possess excellent solvent and chemical resistance as well as low volume swell properties especially when contacted with petroleum based fuels such as gasoline and particularly when contacted with oxygenated fuels such as gasohol. This makes these materials highly useful as seals such as gaskets and o-rings, hoses, coatings and the like.
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公开(公告)号：US4698439A
公开(公告)日：1987-10-06
申请号：US862000
申请日：1986-05-12
IPC分类号： C07F9/6581 , C08G79/02 , C10M105/74 , C07F9/00
CPC分类号： C10M105/74 , C07F9/65812 , C08G79/025 , C10M2223/02 , C10M2223/049 , C10N2240/08
摘要： A polyphosphazene hydraulic fluid that remains solids-free on storage at temperatures down to -30.degree. C. over an extended period can be made by reacting a solution of sodium phenoxide, sodium m-methylphenoxide, sodium p-methylphenoxide and sodium trifluoroethoxide with a small stoichiometric excess of cyclic phosphonitrilic chloride oligomer, mainly trimer, and then reacting the remaining replaceable chlorine atoms with a solution of sodium trifluoroethoxide.
摘要翻译： 通过使苯酚钠，间甲基苯酚钠，对甲基苯酚钠和三氟乙酸钠的溶液与小型的溶液反应，可以在长时间内在低至-30℃的温度下储存时保持无固体的聚磷腈液压流体 化学计量过量的环磷酰氯低聚物，主要是三聚体，然后使剩余的可替换氯原子与三氟乙酸钠溶液反应。
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公开(公告)号：US20100087620A1
公开(公告)日：2010-04-08
申请号：US12636250
申请日：2009-12-11
IPC分类号： C08G79/00
摘要： Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.
摘要翻译： 同时加入保持在约10℃或更低的反应区域的是溴化剂，卤化铝催化剂和具有大约2000-30,000的GPC Mn的阴离子苯乙烯聚合物溶液。 这些组件至少有两个单独的进料流。 进料成比例以维持（a）以所加入的聚合物中的芳族单体单元的量为基准，以约0.8摩尔％或更少的量加入卤化铝的量，和（b）溴化剂和未溴化聚合物的量 反应区，其产生含有约60-71重量％溴的最终洗涤和干燥的聚合物产物。 催化剂失活，溴化物离子和催化剂残余物从反应混合物中洗去，回收溴化阴离子苯乙烯聚合物并干燥。 干燥的聚合物具有约600ppm（wt / wt）或更低的挥发性溴苯含量以及其它有益特性。
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公开(公告)号：US06235831B1
公开(公告)日：2001-05-22
申请号：US09151110
申请日：1998-09-10
申请人： Jon S. Reed , Susan D. Landry , Daniel A. De Schryver , Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
发明人： Jon S. Reed , Susan D. Landry , Daniel A. De Schryver , Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
IPC分类号： C08L4700
摘要： A polyalkylene terephthalate polymer, such as polyethylene terephthalate, polybutylene terephthalate, blends or copolymers thereof, and analogous polyester-type engineering thermoplastics, with which has been blended a flame retardant amount of brominated styrenic polymer, such as brominated polystyrene, that, prior to blending, is characterized by (a) containing less than 700 ppm Cl and having a TGA temperature for 1% weight loss of 340° C. or higher; and/or (b) having an actual Mw which is within about 20%, and preferably within about 10%, of its calculated theoretical Mw, the theoretical Mw being based upon the actual bromine content of the brominated styrenic polymer and the Mw of the styrenic polymer reactant used to produce the brominated styrenic polymer; and/or (c) being essentially free of each of the following impurities: (1) ethylene dichloride, (2) bromodichloroethane, (3) dibromochloroethane, (4) dibromodichloroethane, and (5) tribrormochloroethane. These compositions most preferably also further comprise a reinforcing amount of glass fiber and/or a flame retardant synergist dispersed therein. It is now possible to provide polyalkylene terephthalate compositions that have a UL-94 rating of V-O using both {fraction (1/16)}-inch test specimens and {fraction (1/32)}-inch test specimens, and that have superior electrical resistance characteristics as reflected by a higher comparative tracking index and greater melt stability as determined by capillary rheometry.
摘要翻译： 聚对苯二甲酸亚烷基酯聚合物，例如聚对苯二甲酸乙二醇酯，聚对苯二甲酸丁二醇酯，它们的共混物或共聚物，以及类似的聚酯型工程热塑性塑料，其中共混有阻燃量溴化苯乙烯聚合物如溴化聚苯乙烯， 的特征在于（a）含有少于700ppm Cl且具有340℃或更高的1％重量损失的TGA温度; 和/或（b）具有在其计算的理论Mw的约20％，优选在约10％内的实际Mw，理论Mw基于溴化苯乙烯类聚合物的实际溴含量和 用于生产溴化苯乙烯聚合物的苯乙烯聚合物反应物; 和/或（c）基本上不含以下各种杂质：（1）二氯乙烷，（2）溴二氯乙烷，（3）二溴氯乙烷，（4）二溴二氯乙烷和（5）三溴氯乙烷。 这些组合物最优选还包含分散在其中的增强量的玻璃纤维和/或阻燃增效剂。 现在可以使用{分数（1/16）} - 英寸试样和{部分（1/32）} - 英寸试样提供具有UL-94等级VO的聚对苯二甲酸亚烷基酯组合物，并且具有优异的 电阻特性由较高的比较跟踪指数反映，并且通过毛细血管流变测定确定更高的熔体稳定性。
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公开(公告)号：US06207765B1
公开(公告)日：2001-03-27
申请号：US09291428
申请日：1999-04-13
申请人： Meng-Sheng Ao , Billie B. Dadgar , Charles H. Kolich , Donald E. Balhoff , Homer C. Lin , David R. Brackenridge , Thorsten W. Brockman
发明人： Meng-Sheng Ao , Billie B. Dadgar , Charles H. Kolich , Donald E. Balhoff , Homer C. Lin , David R. Brackenridge , Thorsten W. Brockman
IPC分类号： C08F822
摘要： This invention relates to the bromination of styrenic polymers by contacting same with a brominating agent in the presence of a bromination catalyst and, as a reaction solvent, bromochloro-methane.
摘要翻译： 本发明涉及通过在溴化催化剂和作为反应溶剂溴氯代甲烷的存在下与溴化剂接触来使苯乙烯聚合物溴化。
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公开(公告)号：US6133381A
公开(公告)日：2000-10-17
申请号：US66172
申请日：1998-04-24
申请人： Jon S. Reed , Charles H. Kolich , Billie B. Dadgar , Donald E. Balhoff , Meng-Sheng Ao , Homer C. Lin , Thorsten W. Brockmann , David R. Brackenridge
发明人： Jon S. Reed , Charles H. Kolich , Billie B. Dadgar , Donald E. Balhoff , Meng-Sheng Ao , Homer C. Lin , Thorsten W. Brockmann , David R. Brackenridge
摘要： This invention relates to a thermally stable brominated polystyrene composition which contains alkali metal base (e.g., NaOH) in an amount less than about 1 wt % such that if the flame retardant is dissolved in bromochloromethane and the resultant solution is extracted with water, the resultant water extract exhibits a pH of at least about 9.0. A preferred composition of this type even when heated to 315.degree. C. for one hour did not undergo darkening--the color remained tan. Comparative samples not containing the base turned black under these same conditions. Especially useful compositions additionally have less than 500 ppm, and better still, less than 100 ppm total Cl, and at least about 67 wt % bromine. Processes for producing the compositions are also described.
摘要翻译： 本发明涉及一种热稳定的溴化聚苯乙烯组合物，其含有少于约1重量％的碱金属碱（例如NaOH），使得如果将阻燃剂溶解在溴氯甲烷中，并将所得溶液用水萃取， 水提取物的pH至少约为9.0。 这种类型的优选组合物即使加热至315℃持续1小时也不会变暗，颜色仍然是棕褐色。 不含碱的比较样品在相同条件下变黑。 特别有用的组合物另外还具有小于500ppm，更好的是小于100ppm的总Cl和至少约67wt％的溴。 还描述了用于制备组合物的方法。
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公开(公告)号：US5916978A
公开(公告)日：1999-06-29
申请号：US41632
申请日：1998-03-13
申请人： Meng-Sheng Ao , Billie B. Dadgar , Charles H. Kolich , Donald E. Balhoff , Homer C. Lin , David R. Brackenridge , Thorsten W. Brockmann
发明人： Meng-Sheng Ao , Billie B. Dadgar , Charles H. Kolich , Donald E. Balhoff , Homer C. Lin , David R. Brackenridge , Thorsten W. Brockmann
CPC分类号： C08F8/20
摘要： This invention relates to the bromination of styrenic polymers by contacting same with a brominating agent in the presence of a bromination catalyst and, as a reaction solvent, bromochloromethane.
摘要翻译： 本发明涉及苯乙烯聚合物的溴化，其通过在溴化催化剂和作为反应溶剂的溴氯甲烷的存在下与溴化剂接触来进行。
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公开(公告)号：US5767203A
公开(公告)日：1998-06-16
申请号：US846156
申请日：1997-04-25
申请人： Meng-Sheng Ao , Billie B. Dadgar , Charles H. Kolich , Donald E. Balhoff , Homer C. Lin , David R. Brackenridge , Thorsten W. Brockmann
发明人： Meng-Sheng Ao , Billie B. Dadgar , Charles H. Kolich , Donald E. Balhoff , Homer C. Lin , David R. Brackenridge , Thorsten W. Brockmann
CPC分类号： C08F8/20
摘要： This invention relates to the bromination of styrenic polymers by contacting same with a brominating agent in the presence of a bromination catalyst and, as a reaction solvent, bromochloromethane.
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60.发明授权
公开(公告)号：US5210243A
公开(公告)日：1993-05-11
申请号：US787101
申请日：1991-11-04
申请人： Charles H. Kolich
发明人： Charles H. Kolich
CPC分类号： C07F15/0053 , B01J31/185 , C07C51/36 , B01J2231/645 , B01J2531/0266 , B01J2531/821
摘要： A ruthenium-phosphite complex having the formula ##STR1## wherein a is from 1 to 3; b is 1 or 2; c is from 0 to 3; and R is hydrogen, alkyl, aryl, halo, amino, acetylamino, or sulfo; and X is ##STR2## where R.sub.1, R.sub.2, and R.sub.3 are the same or different and are hydrogen or C.sub.1 to C.sub.6 linear or branched alkyl.This complex can be used to effect the reduction of unsaturated organic compounds or, when comprised of ligands having optical activity, can be used as the catalyst for effecting the asymmetric reduction of unsaturated organic compounds.
摘要翻译： 具有式IV的钌 - 亚磷酸酯络合物，其中a为1至3; b为1或2; c为0〜3; 和R是氢，烷基，芳基，卤素，氨基，乙酰氨基或磺基; 且X为
，其中R 1，R 2和R 3相同或不同，为氢或C 1至C 6直链或支链烷基。 该络合物可以用于还原不饱和有机化合物，或者当由具有光学活性的配体组成时，可用作用于实现不饱和有机化合物的不对称还原的催化剂。
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