-
公开(公告)号：US07666944B2
公开(公告)日：2010-02-23
申请号：US11928900
申请日：2007-10-30
申请人： Daniel A. De Schryver , Jon Shannon Reed , Douglas W. Luther , Samuel G. Thomas, Jr. , Arthur G. Mack
发明人： Daniel A. De Schryver , Jon Shannon Reed , Douglas W. Luther , Samuel G. Thomas, Jr. , Arthur G. Mack
IPC分类号： C08L67/02
CPC分类号： C08J3/226 , C08J2423/00 , C08J2467/00 , C08J2477/00 , C08L23/10 , C08L25/18 , C08L67/02 , C08L2203/12 , D01F1/07 , D01F6/46 , D01F6/90 , D01F6/92 , C08L2666/04
摘要： A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
摘要翻译： 提供由包含（a）至少一种成纤热塑性聚合物和（b）至少一种多溴化阴离子苯乙烯聚合物的成分形成的纤维或长丝。 多溴化阴离子苯乙烯聚合物的溴含量为至少约50重量％，GPC重均分子量在约5000至约40,000范围内，GPC重均分子量至少为约600,000。 当成纤热塑性聚合物是聚酯时，多溴化阴离子苯乙烯聚合物以阻燃或阻燃的量存在。 当成纤热塑性聚合物是聚酰胺时，多溴化阴离子苯乙烯聚合物是纤维或长丝的至少约2重量％。 当成纤热塑性聚合物是聚烯烃时，存在至少一种增效剂，多溴化阴离子苯乙烯聚合物不超过纤维或长丝的约15重量％。
-
公开(公告)号：US20080139752A1
公开(公告)日：2008-06-12
申请号：US11928900
申请日：2007-10-30
申请人： Daniel A. De Schryver , Jon Shannon Reed , Douglas W. Luther , Samuel G. Thomas , Arthur G. Mack
发明人： Daniel A. De Schryver , Jon Shannon Reed , Douglas W. Luther , Samuel G. Thomas , Arthur G. Mack
IPC分类号： C08G61/02
CPC分类号： C08J3/226 , C08J2423/00 , C08J2467/00 , C08J2477/00 , C08L23/10 , C08L25/18 , C08L67/02 , C08L2203/12 , D01F1/07 , D01F6/46 , D01F6/90 , D01F6/92 , C08L2666/04
摘要： A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
摘要翻译： 提供由包含（a）至少一种成纤热塑性聚合物和（b）至少一种多溴化阴离子苯乙烯聚合物的成分形成的纤维或长丝。 多溴化阴离子苯乙烯聚合物的溴含量为至少约50重量％，GPC重均分子量在约5000至约40,000范围内或GPC重均分子量至少为约600,000。 当成纤热塑性聚合物是聚酯时，多溴化阴离子苯乙烯聚合物以阻燃或阻燃的量存在。 当成纤热塑性聚合物是聚酰胺时，多溴化阴离子苯乙烯聚合物是纤维或长丝的至少约2重量％。 当成纤热塑性聚合物是聚烯烃时，存在至少一种增效剂，多溴化阴离子苯乙烯聚合物不超过纤维或长丝的约15重量％。
-
公开(公告)号：US07666943B2
公开(公告)日：2010-02-23
申请号：US11490300
申请日：2006-07-20
IPC分类号： C08L67/02
CPC分类号： D01F1/07 , C08K3/016 , C08L23/10 , C08L25/18 , C08L67/02 , C08L77/00 , C08L77/02 , C08L77/06 , D01F6/46 , D01F6/48 , D01F6/60 , D01F6/62 , D01F6/90 , D01F6/92 , C08L2666/06
摘要： A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer, and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
摘要翻译： 提供由包含（a）至少一种成纤热塑性聚合物和（b）至少一种多溴化阴离子苯乙烯类聚合物的成分形成的纤维或长丝。 多溴阴离子苯乙烯聚合物的溴含量为至少约50重量％。 当成纤热塑性聚合物是聚酯时，多溴化阴离子苯乙烯聚合物以阻燃或阻燃的量存在。 当成纤热塑性聚合物是聚酰胺时，多溴化阴离子苯乙烯聚合物是纤维或长丝的至少约2重量％。 当成纤热塑性聚合物是聚烯烃时，存在至少一种增效剂，多溴化阴离子苯乙烯聚合物不超过纤维或长丝的约15重量％。
-
公开(公告)号：US06617379B2
公开(公告)日：2003-09-09
申请号：US10005653
申请日：2001-12-04
IPC分类号： C08K534
CPC分类号： C08K5/34928 , C08K5/0066 , C08K5/5399
摘要： N,N′-piperazinebis(neopentylglycol)phosphoramidate is used in combination with at least one co-additive which is (i) melamine, (ii) one or more melamine compounds or derivatives, or (iii) both of (i) and (ii) to provide effective flame retardancy in thermoplastic polymers. With polymers that tend to release trace amounts of acid under thermal processing conditions, a hydrotalcite is preferably included in the composition. In acid-sensitive polymers such as polyesters, the N,N′-piperazinebis(neopentylglycol)phosphoramidate should be free or essentially free of acid species as determinable by use of nmr, mass spec, and/or HPLC.
摘要翻译： N，N'-哌嗪双（新戊二醇）氨基磷酸酯与至少一种共添加剂组合使用，所述共添加剂为（i）三聚氰胺，（ii）一种或多种三聚氰胺化合物或衍生物，或（iii）（i）和 ii）在热塑性聚合物中提供有效的阻燃性。 对于在热加工条件下倾向于释放痕量酸的聚合物，组合物中优选包括水滑石。 在酸敏感聚合物如聚酯中，N，N'-哌嗪二（新戊二醇）氨基磷酸酯应该是游离的或基本上不含酸性物质，可以通过使用nmr，质谱和/或HPLC来测定。
-
公开(公告)号：US06235831B1
公开(公告)日：2001-05-22
申请号：US09151110
申请日：1998-09-10
申请人： Jon S. Reed , Susan D. Landry , Daniel A. De Schryver , Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
发明人： Jon S. Reed , Susan D. Landry , Daniel A. De Schryver , Billie B. Dadgar , Donald E. Balhoff , Charles H. Kolich , Meng-Sheng Ao , Homer C. Lin
IPC分类号： C08L4700
摘要： A polyalkylene terephthalate polymer, such as polyethylene terephthalate, polybutylene terephthalate, blends or copolymers thereof, and analogous polyester-type engineering thermoplastics, with which has been blended a flame retardant amount of brominated styrenic polymer, such as brominated polystyrene, that, prior to blending, is characterized by (a) containing less than 700 ppm Cl and having a TGA temperature for 1% weight loss of 340° C. or higher; and/or (b) having an actual Mw which is within about 20%, and preferably within about 10%, of its calculated theoretical Mw, the theoretical Mw being based upon the actual bromine content of the brominated styrenic polymer and the Mw of the styrenic polymer reactant used to produce the brominated styrenic polymer; and/or (c) being essentially free of each of the following impurities: (1) ethylene dichloride, (2) bromodichloroethane, (3) dibromochloroethane, (4) dibromodichloroethane, and (5) tribrormochloroethane. These compositions most preferably also further comprise a reinforcing amount of glass fiber and/or a flame retardant synergist dispersed therein. It is now possible to provide polyalkylene terephthalate compositions that have a UL-94 rating of V-O using both {fraction (1/16)}-inch test specimens and {fraction (1/32)}-inch test specimens, and that have superior electrical resistance characteristics as reflected by a higher comparative tracking index and greater melt stability as determined by capillary rheometry.
摘要翻译： 聚对苯二甲酸亚烷基酯聚合物，例如聚对苯二甲酸乙二醇酯，聚对苯二甲酸丁二醇酯，它们的共混物或共聚物，以及类似的聚酯型工程热塑性塑料，其中共混有阻燃量溴化苯乙烯聚合物如溴化聚苯乙烯， 的特征在于（a）含有少于700ppm Cl且具有340℃或更高的1％重量损失的TGA温度; 和/或（b）具有在其计算的理论Mw的约20％，优选在约10％内的实际Mw，理论Mw基于溴化苯乙烯类聚合物的实际溴含量和 用于生产溴化苯乙烯聚合物的苯乙烯聚合物反应物; 和/或（c）基本上不含以下各种杂质：（1）二氯乙烷，（2）溴二氯乙烷，（3）二溴氯乙烷，（4）二溴二氯乙烷和（5）三溴氯乙烷。 这些组合物最优选还包含分散在其中的增强量的玻璃纤维和/或阻燃增效剂。 现在可以使用{分数（1/16）} - 英寸试样和{部分（1/32）} - 英寸试样提供具有UL-94等级VO的聚对苯二甲酸亚烷基酯组合物，并且具有优异的 电阻特性由较高的比较跟踪指数反映，并且通过毛细血管流变测定确定更高的熔体稳定性。
-
-
-
-
搜索结果
5 条记录 (耗时 0.02 秒)
