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    Process and apparatus for alkylation of aromatic compound with aliphatic mono-olefin compound of 8 to 18 carbon atoms
    61.
    发明授权
    Process and apparatus for alkylation of aromatic compound with aliphatic mono-olefin compound of 8 to 18 carbon atoms 有权
    芳族化合物与8至18个碳原子的脂族单烯烃化合物烷基化的方法和装置

    公开(公告)号：US07692054B2

    公开(公告)日：2010-04-06

    申请号：US11872786

    申请日：2007-10-16

    申请人： Mark G. Riley

    发明人： Mark G. Riley

    IPC分类号： C07C2/56

    CPC分类号： C07C2/66 ,  C07C15/107

    摘要： Continuous processes for monoalkylating aromatic compound with an aliphatic feedstock comprising aliphatic olefin of 8 to 18 carbon atoms per molecule are effected using at least 3 reaction zones in series, each containing solid alkylation catalyst with effluent cooling between reaction zones, each of which reaction zones is supplied a portion of the fresh aliphatic feedstock, such that the Reaction Zone Delta T in each reaction zone is less than about 15° C. The overall aromatic compound to olefin molar ratio is less than about 20:1. The alkylation product has desirable linearity and low amounts of dimers, dealkylated compounds and diaryl compounds even though a low aromatic compound to olefin molar ratio is used.

    摘要翻译： 使烷基化芳族化合物与包含每个分子具有8至18个碳原子的脂族烯烃的单烷基化的连续方法使用至少3个串联的反应区进行，每个反应区均含有固体烷基化催化剂，反应区之间的流出物冷却，每个反应区为 提供一部分新鲜的脂肪原料，使得每个反应区中的反应区Delta T小于约15℃。芳族化合物与烯烃的总摩尔比小于约20:1。 尽管使用低芳族化合物与烯烃的摩尔比，烷基化产物具有所需的线性和低二聚体，脱烷基化合物和二芳基化合物的量。

    Energy Integrated Processes including alkylation and transalkylation for Making Detergent Range Alkylbenzenes
    64.
    发明申请
    Energy Integrated Processes including alkylation and transalkylation for Making Detergent Range Alkylbenzenes 有权
    能量综合过程包括用于制备洗涤剂范围烷基苯的烷基化和烷基转移

    公开(公告)号：US20080194894A1

    公开(公告)日：2008-08-14

    申请号：US11673908

    申请日：2007-02-12

    申请人： Stephen W. Sohn ,  Mark G. Riley

    发明人： Stephen W. Sohn ,  Mark G. Riley

    IPC分类号： C07C15/04

    CPC分类号： C07C15/107 ,  C07C6/126 ,  Y02P20/125

    摘要： Integrated, energy efficient process for making detergent range alkylbenzenes, heavies coproduced during the alkylation of benzene with olefin using a solid, acidic catalyst are transalkylated. Spent benzene from regeneration of the solid, acidic catalyst used for alkylation provides at least about 50 percent of the benzene provided for the transalkylation. The integrated processes thus reduce the load on the benzene distillation assembly used in the alkylbenzene refining system.

    摘要翻译： 用于制备洗涤剂范围烷基苯的综合的能量高效方法，在使用固体，酸性催化剂的烯烃烷基化烷基化过程中共同生成的重质烃被转烷基化。 由用于烷基化的固体酸性催化剂的再生产生的苯提供至少约50％的用于烷基转移的苯。 因此，综合方法减少了在烷基苯精制系统中使用的苯蒸馏装置的负荷。