摘要:
Provided herein are various methods for forming alkylaromatic sulfonate compositions and blended alkylaromatic sulfonate compositions, and such compositions themselves. The methods of various embodiments include obtaining a C8-C30 hydrocarbon mixture, optionally treating the mixture to concentrate the mixture in sulfonatable aromatics, and sulfonating the mixture to form the alkylaromatic sulfonates. The mixture or treated mixture may be blended with linear alkyl benzene (LAB) compositions and sulfonated, and/or the alkylaryl sulfonates may be blended with linear alkylbenzene sulfonate (LAS) compositions, to form the blended alkylaromatic sulfonates of some embodiments. These compositions and processes for making them may be tailored to serve a variety of end uses, such as detergents in cleaning solutions or for enhanced oil recovery operations, and/or as low foaming and/or hydrotropic additives in detergent formulations, and the like.
摘要:
A process for producing alkylaromatic compounds is described. The process involves utilizing at least a portion of the aromatic compound used to regenerate the alkylation catalyst in a spent alkylation reaction zone as a reactant in the active alkylation reaction zone. The process further includes utilizing a portion of the process stream leaving the alkylation zone as a recycle stream to the alkylation zone.
摘要:
A process for producing alkylaromatic compounds is described. The process involves utilizing at least a portion of the aromatic compound used to regenerate the alkylation catalyst in a spent alkylation reaction zone as a reactant in the active alkylation reaction zone.
摘要:
The present disclosure provides an ionic liquid compound of Formula (I) and its application in reactions such as alkylation, arylation, acylation, diels alder and oligomerization, The present disclosure also provides a process for preparing the ionic liquid compound of Formula (I) which involves preparing an ionic salt complex represented by Formula [(NR1R2R3)iM1]n+[Xj]n− by mixing an amine represented by Formula NR1R2R3 and a metal salt represented by formula M1Xj; and mixing the ionic salt complex and a metal salt represented by formula M2Yk to obtain the ionic liquid compound.
摘要:
The present disclosure provides an ionic liquid compound of Formula (I) and its application in reactions such as alkylation, arylation, acylation, diels alder and oligomerization, The present disclosure also provides a process for preparing the ionic liquid compound of Formula (I) which involves preparing an ionic salt complex represented by Formula [(NR1R2R3)iM1]n+[Xj]n− by mixing an amine represented by Formula NR1R2R3 and a metal salt represented by formula M1Xj; and mixing the ionic salt complex and a metal salt represented by formula M2Yk to obtain the ionic liquid compound.
摘要翻译:本公开内容提供了式(I)的离子液体化合物及其在诸如烷基化,芳基化,酰化,狄尔斯狄尔逊和低聚反应的反应中的应用。本公开还提供了制备式(I)的离子液体化合物的方法, 涉及通过将由式NR1R2R3表示的胺与由式M1Xj表示的金属盐混合来制备由式[(NR1R2R3)iM1] n + [Xj] n-表示的离子盐络合物; 并将离子盐络合物和式M2Yk所示的金属盐混合,得到离子液体化合物。
摘要:
The production of linear alkylbenzene from a natural oil is provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. The paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product.
摘要:
A linear alkyl benzene product and production of linear alkylbenzene from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. The paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product.
摘要:
A process for converting hydrocarbons comprising the step of contacting said hydrocarbons under conversion conditions with a crystalline molecular sieve having a pore size in the range of from about 2 to about 19 Å, said molecular sieve made by a method comprising the steps of (a) providing a mixture comprising at least one source of ions of tetravalent element (Y), at least one trivalent element hydroxide source (OH−), and water, said mixture having a solid-content in the range of from about 15 wt. % to about 50 wt. %. %, preferably of from about 20% to about 30%; and (b) treating said mixture to form the desired crystalline molecular sieve with stirring at crystallization conditions sufficient to obtain a weight hourly throughput from about 0.005 to about 1 hr−1, wherein said crystallization conditions comprise a temperature in the range of from about 200° C. to about 500° C. and a crystallization time less than 100 hr, wherein said crystalline molecular sieve has a zeolite framework type of MFI.
摘要:
In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound.
摘要:
Disclosed is a method for improving filtration in the preparation of an alkaline earth metal alkyltoluene sulfonate concentrate by selectively controlling the meta, ortho, para isomer distribution of the alkyl group of the alkyltoluene produced by the process comprising alkylating toluene with at least one isomerized normal alpha olefin, having from about 18 to about 30 carbon atoms and having from 20% to 100% branching in an alkylation process which includes monitoring % isomer formation and adjusting an alkylation process parameter in order to provide a target specified isomer content of less than 38% meta-isomer content; and thereafter sulfonating and neutralizing to produce a low base number sulfonated alkyltoluene concentrate having a Base Number of about 2 to 60 (ASTM D 2896).
摘要翻译:公开了一种通过选择性地控制烷基甲苯的烷基的间位,邻位,对位异构体分布来制备碱土金属烷基甲苯磺酸盐浓缩物的方法,该方法包括使甲苯与至少一种异构化的正常α 烯烃,其具有约18至约30个碳原子并且在烷基化方法中具有20%至100%的支化,其包括监测%异构体形成和调节烷基化方法参数,以提供小于38%的目标特异异构体含量, 间 - 异构体含量; 然后磺化和中和以产生碱值为约2至60(ASTM D 2896)的低碱值磺化烷基甲苯浓缩物。