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    Thienylmethyl-thiophosphoric acid esters
    61.
    发明授权
    Thienylmethyl-thiophosphoric acid esters 失效
    噻吩甲基 - 硫代磷酸酯

    公开(公告)号：US4268506A

    公开(公告)日：1981-05-19

    申请号：US54862

    申请日：1979-07-05

    申请人： Annegrit Baumann ,  Heinrich Adolphi

    发明人： Annegrit Baumann ,  Heinrich Adolphi

    IPC分类号： C07D333/18 ,  C07D333/28 ,  C07F9/6553 ,  A61K31/38 ,  C07D333/14

    CPC分类号： C07D333/18 ,  C07D333/28 ,  C07F9/655345

    摘要： New thienylmethyl-thiophosphoric acid esters of the formula ##STR1## where R.sup.1 denotes methyl or ethyl, R.sup.2 denotes linear or branched alkyl of a maximum of 5 carbon atoms, X denotes oxygen or sulfur, Y denotes sulfur or --NH--, Z denotes halogen, and n denotes one of the integers 0, 1, 2 and 3, which are effective against pests, especially insects, Arachnida and Nemathelminthes, and pesticides containing these compounds as active ingredients.

    摘要翻译： 式中，R1表示甲基或乙基的新的噻吩基甲基硫代磷酸酯，R2表示最多5个碳原子的直链或支链烷基，X表示氧或硫，Y表示硫或-NH-，Z表示卤素 ，n表示整数0,1,2和3之一，它们有效对抗害虫，特别是昆虫，蛛形纲和线虫，以及含有这些化合物作为活性成分的农药。

    Pyridazinonyl-(di)(thio)-phosphoric (phosphonic) acid esters as pesticides
    62.
    发明授权
    Pyridazinonyl-(di)(thio)-phosphoric (phosphonic) acid esters as pesticides 失效
    哒嗪酮基 - （二）（硫代） - 磷酸（膦酸）酯作为农药

    公开(公告)号：US4260604A

    公开(公告)日：1981-04-07

    申请号：US82161

    申请日：1979-10-05

    申请人： Annegrit Baumann ,  Heinrich Adolphi ,  Rolf Huber ,  Karl Kiehs

    发明人： Annegrit Baumann ,  Heinrich Adolphi ,  Rolf Huber ,  Karl Kiehs

    IPC分类号： A01N57/08 ,  C07F9/6509 ,  C07F9/65 ,  A01N57/24 ,  A01N57/32 ,  A01N57/16

    CPC分类号： A01N57/08 ,  C07F9/650929

    摘要： New pyridazinonyl-(di)(thio)-phosphoric (phosphonic) acid esters of the formula ##STR1## where X and Y each denote oxygen or sulfur, R.sup.1 denotes linear or branched alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, mono- or dialkylamino of 1 to 4 carbon atoms in each alkyl, phenyl, or benzyl, R.sup.2 denotes linear or branched alkyl of 1 to 4 carbon atoms, phenyl or benzyl, R.sup.3 denotes linear or branched alkyl of 1 to 4 carbon atoms or phenyl, R.sup.4 denotes linear or branched alkyl of 1 to 4 carbon atoms, or R.sup.3 and R.sup.4, together with the oxygen and the carbon atom whose substituents they are, form a 5- or 6 membered saturated ring which may be substituted by alkyl of 1 to 4 carbon atoms, which are effective against pests, especially insects and Arachnida, pesticides containing these pyridazinonyl-(di)(thio)-phosphoric (phosphonic) acid esters as active ingredients, and a process for combating pests with these active ingredients.The present invention relates to new pyridazinonyl-(di) (thio)-phosphoric (phosphonic) acid esters, a process for their manufacture, and pesticides, especially insecticides and acaricides, containing these compounds as active ingredients.

    摘要翻译： 新的哒嗪酮基 - （二）（硫代） - 磷酸（膦酸）酯，其中X和Y各自表示氧或硫，R 1表示1至4个碳原子的直链或支链烷基，烷氧基为1 至4个碳原子，每个烷基，苯基或苄基中具有1至4个碳原子的单或二烷基氨基，R 2表示1至4个碳原子的直链或支链烷基，苯基或苄基，R3表示1至 4个碳原子或苯基，R4表示1至4个碳原子的直链或支链烷基，或R3和R4与氧和其取代基的碳原子一起形成可被取代的5或6元饱和环 具有1至4个碳原子的烷基，它们有效防止害虫，特别是昆虫和蛛形纲，含有这些哒嗪酮基 - （二）（硫代） - 磷酸（膦酸）酸酯的农药作为活性成分，以及用这些方法对抗害虫的方法 有效成分。 本发明涉及新的哒嗪酮基 - （二）（硫代） - 磷酸（膦酸）酯，其制备方法，以及含有这些化合物作为活性成分的杀虫剂，特别是杀虫剂和杀螨剂。

    Phosphoric acid esters, composition and use
    63.
    发明授权
    Phosphoric acid esters, composition and use 失效
    磷酸酯，组成和用途

    公开(公告)号：US4203977A

    公开(公告)日：1980-05-20

    申请号：US948152

    申请日：1978-10-03

    申请人： Karl Kiehs ,  Heinrich Adolphi

    发明人： Karl Kiehs ,  Heinrich Adolphi

    IPC分类号： C07F9/165 ,  A01N57/02 ,  C07F9/173 ,  C07F9/24 ,  C07F9/36 ,  C07F9/38 ,  C07F9/40 ,  C07F9/6533 ,  A01N9/36

    CPC分类号： C07F9/6533 ,  A01N57/02 ,  C07F9/173 ,  C07F9/2408 ,  C07F9/4075

    摘要： Phosphoric (phosphonic) acid esters of the formula ##STR1## where R.sup.1 denotes linear or branched alkyl of up to 4 carbon atoms, R.sup.2 denotes linear or branched alkyl, alkoxy or alkylthio, each of up to 4 carbon atoms, mono- or dialkylamino of up to 4 carbon atoms in each alkyl, or phenyl, R.sup.3 denotes linear or branched alkoxy or alkylthio of up to 4 carbon atoms, amino, mono- or dialkylamino of up to 4 carbon atoms in each alkyl, alkylalkoxyalkylamino of up to 4 carbon atoms in each alkyl or alkoxyalkyl, dialkoxyalkylamino of up to 4 carbon atoms in each alkoxyalkyl, alkylalkenylamino of up to 4 carbon atoms in each alkyl or alkenyl, alkylalkynylamino of up to 4 carbon atoms in each alkyl or alkynyl, N-methyl-N-methoxyamino, N-(2-methoxyethyl)-N-(2-cyanoethyl), a 5- or 6-membered nitrogenous heterocyclic ring which may contain several nitrogen atoms and optionally oxygen as ring members, R.sup.4 denotes unsubstituted or halogen-substituted acyl of up to 4 carbon atoms, alkylsulfonyl or haloalkylsulfonyl of up to 4 carbon atoms in each alkyl or haloalkyl, the group --CO--NR.sup.5 R.sup.6, R.sup.5 and R.sup.6 denoting hydrogen, linear or branched alkyl of up to 4 carbon atoms, or - but not simultaneously - phenyl, or R.sup.5 and R.sup.6 denoting, together with the nitrogen atom whose substituents they are, a 5- or 6-membered heterocyclic ring with further nitrogen atoms and an oxygen atom as ring members, or R.sup.4 denotes the group --CO--Y--R.sup.7, R.sup.7 denoting linear or branched alkyl of up to 4 carbon atoms, phenyl or benzyl, and Y denoting oxygen or sulfur, and X denotes oxygen or sulfur, which are effective against pests, especially insects, mites and ticks; pesticides containing these phosphoric (phosphonic) acid esters as active ingredients; a process for producing these active ingredients; and a process for combating pests with these active ingredients.

    摘要翻译： 其中R 1表示多至4个碳原子的直链或支链烷基，R 2表示直链或支链烷基，烷氧基或烷硫基，各自至多4个碳原子，单或二烷基氨基， 每个烷基中至多4个碳原子，或苯基，R3表示多至4个碳原子的直链或支链烷氧基或烷硫基，氨基，每个烷基中至多4个碳原子的单或二烷基氨基，最多4个碳原子的烷基烷氧基烷基氨基 在每个烷基或烷氧基烷基中，每个烷氧基烷基中至多4个碳原子的二烷氧基烷基氨基，每个烷基或烯基中至多4个碳原子的烷基链烯基氨基，每个烷基或炔基中至多4个碳原子的烷基炔基氨基，N-甲基-N-甲氧基氨基 ，N-（2-甲氧基乙基）-N-（2-氰基乙基），可含有若干氮原子和任选的氧作为环成员的5-或6-元含氮杂环，R4表示未取代的或卤素取代的酰基 至4个碳原子，烷基磺酰基或卤代烷基 每个烷基或卤代烷基中至多4个碳原子的磺酰基，基团-CO-NR 5 R 6，R 5和R 6表示氢，最多4个碳原子的直链或支链烷基或 - 但不同时 - 苯基，或R5和R6表示 与其取代基的氮原子一起为具有另外的氮原子和氧原子作为环成员的5-或6-元杂环，或R4表示基团-CO-Y-R7，R7表示直链或支链烷基 至多4个碳原子，苯基或苄基，Y表示氧或硫，X表示氧或硫，可有效对抗害虫，特别是昆虫，螨虫和蜱虫; 含有这些磷酸（膦酸）酸酯作为活性成分的农药; 一种生产这些活性成分的方法; 以及与这些活性成分对抗害虫的方法。