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公开(公告)号：US07871675B2
公开(公告)日：2011-01-18
申请号：US11972762
申请日：2008-01-11
IPC分类号： C08G77/26
CPC分类号： C08G65/336 , C08G18/718 , C08G18/8025 , Y10T428/31663
摘要： Moisture curable compositions which cure to produce hard coatings contain prepolymers bearing alkoxysilyl groups of the formula —X—CH2—Si(OR)3-xR1x where X is —O— or —O—CO—NR″—. The compositions are storage stable and can be cured without use of tin catalysts.
摘要翻译： 固化生产硬涂层的湿固化组合物含有具有式-X-CH2-Si（OR）3-xR1x（其中X是-O-或-O-CO-NR“ - ）的烷氧基甲硅烷基的预聚物。 该组合物是储存稳定的，可以在不使用锡催化剂的情况下固化。
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62.发明授权公开(公告)号：US07674840B2
公开(公告)日：2010-03-09
申请号：US10468633
申请日：2002-01-24
IPC分类号： C08G77/22
CPC分类号： C08J9/146 , C08G18/10 , C08G18/718 , C08G18/778 , C08G2101/00 , C08G2101/0025 , C08G2190/00 , C08J2375/04 , C09K3/30 , C08G18/289
摘要： Isocyanate-free foamable mixtures suitable for filling construction voids and for other uses, comprise isocyanate-free, alkoxysilane-terminated prepolymers (A) which have a silane end group of the formula [1], where X and Y are each an oxygen atom, an N—R3 group or a sulfur atom, R1 is an alkyl, cycloalkyl, alkenyl or aryl radical having 1-10 carbon atoms, R2 is an alkyl radical having 1-2 carbon atoms or an ω-oxyalkylalkyl radical having a total of 2-10 carbon atoms, R3 is a hydrogen atom, an alkyl, alkenyl or aryl radical having 1-10 carbon atoms or a —CH2—SiR1z(OR2)3-z group, and z is 0 or 1, with the proviso that at least one of the two groups X and Y is an NH function, and (B) blowing agents.
摘要翻译： 适用于填充构造空隙和其它用途的不含异氰酸酯的可发泡混合物包括具有式[1]硅烷端基的无异氰酸酯的烷氧基硅烷封端的预聚物（A），其中X和Y各自为氧原子， N-R3基或硫原子，R1是具有1-10个碳原子的烷基，环烷基，烯基或芳基，R2是具有1-2个碳原子的烷基或具有总共2个碳原子的ω-烷氧基烷基 -10个碳原子，R3是氢原子，具有1-10个碳原子的烷基，烯基或芳基或-CH2-SiR1z（OR2）3-z基团，z是0或1，条件是在 两组X和Y中的至少一个是NH官能团，和（B）发泡剂。
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63.发明申请公开(公告)号：US20090227792A1
公开(公告)日：2009-09-10
申请号：US11720891
申请日：2005-11-17
IPC分类号： C07F7/10
CPC分类号： C07F7/1804
摘要： α-aminoalkoxysilanes wherein the α-amino group is a tertiary amino group, and which also contains a further reactive group, display excellent reactivity of the alkoxy groups while remaining stable with respect to decomposition and byproduct formation, particularly through cleavage of the Si-C bond. The α-aminosilanes are particularly useful for preparing alkoxysilyl-terminated prepolymers which exhibit high cure rates in the presence of moisture, and for functionalizing particles reactive therewith.
摘要翻译： α-氨基烷氧基硅烷，其中α-氨基是叔氨基，并且还含有另外的反应性基团，表现出优异的烷氧基反应性，同时在分解和副产物形成方面保持稳定，特别是通过Si-C的裂解 键。 α-氨基硅烷特别可用于制备在水分存在下表现出高固化速率的烷氧基甲硅烷基封端的预聚物，以及用于官能化与其反应的颗粒。
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公开(公告)号：US20080051482A1
公开(公告)日：2008-02-28
申请号：US11854567
申请日：2007-09-13
申请人： Volker Stanjek , Oliver Schaefer , Bernd Pachaly
发明人： Volker Stanjek , Oliver Schaefer , Bernd Pachaly
CPC分类号： C08G18/61 , C08G2101/0008 , C08G2101/0083
摘要： Both flexible and rigid foams may be prepared by reacting di- or polyisocyanates with organopolysiloxanes which are prepared by reaction of silanol-terminated organopolysiloxanes with organosilicon compounds containing alkyleneoxy or alkylenamino groups bonded on both ends to silicon, thus resulting in organopolysiloxanes having 95% or more of aminoalkyl or hydroxyalkyl terminal groups.
摘要翻译： 柔性和刚性泡沫体可以通过使二 - 或多异氰酸酯与有机聚硅氧烷反应来制备，所述有机聚硅氧烷是通过硅烷醇封端的有机聚硅氧烷与两端键合的含有亚烷基氧基或亚烷基氨基的有机硅化合物与硅反应而制备的，从而得到具有95％或更高的有机聚硅氧烷 的氨基烷基或羟烷基端基。
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65.发明授权Polymer compositions based on alkoxysilane-terminated polymers with adjustable cure rate 有权基于烷基硅烷封端聚合物的聚合物组合物，具有可调整的固化速度公开(公告)号：US07332541B2
公开(公告)日：2008-02-19
申请号：US10524473
申请日：2003-08-07
申请人： Wolfram Schindler , Volker Stanjek
发明人： Wolfram Schindler , Volker Stanjek
CPC分类号： C08G65/336 , C08G18/10 , C08G18/289 , C08G18/718
摘要： Condensation curable systems employ ordinarily highly reactive polymers bearing methylene-linked alkoxysilyl groups. By limiting the amounts of activating compounds during the preparation of such polymers, the reactivity is sharply decreased, yet can be increased by addition of suitable catalysts. As a result, the polymers may be easily processed, yet the moisture curing times may be adjusted readily.
摘要翻译： 缩合固化体系使用通常具有亚甲基连接的烷氧基甲硅烷基的高反应性聚合物。 通过在制备这种聚合物期间限制活化化合物的量，反应性急剧降低，但可通过加入合适的催化剂而增加。 结果，可以容易地处理聚合物，但可以容易地调节湿气固化时间。
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公开(公告)号：US20070123644A1
公开(公告)日：2007-05-31
申请号：US11668207
申请日：2007-01-29
CPC分类号： C07F7/1804
摘要： Blocked silyl isocyanates contain a methylene group between the blocked isocyanate group and silicon. The blocked isocyanates are easily prepared in high yield and purity.
摘要翻译： 封闭的甲硅烷基异氰酸酯在封端异氰酸酯基和硅之间含有亚甲基。 封闭的异氰酸酯容易以高产率和纯度制备。
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公开(公告)号：US20070100111A1
公开(公告)日：2007-05-03
申请号：US10595010
申请日：2004-06-03
IPC分类号： C08G18/00
CPC分类号： C09J175/04 , C08G18/12 , C08G18/6674 , C08G18/289
摘要： Alkoxysilyl-terminated preopolymers prepared by reacting an alkoxysilane with a prepolymer prepared by reacting a di- or polyisocyanate with both a low molecular weight diol or polyol and a high molecular weight polyol, the respective polyol components present within a specific ratio range, and giving rise to an increased content of urethane groups, and an inhomogenous distribution thereof exhibit high tensile strength and elongation, even without the use of fillers.
摘要翻译： 通过使烷氧基硅烷与通过使二异氰酸酯或多异氰酸酯与低分子量二元醇或多元醇和高分子量多元醇反应制备的预聚物制备的烷氧基甲硅烷基封端的预聚物，相应的多元醇组分存在于特定比例范围内，并产生 增加氨基甲酸酯基团的含量，并且其不均匀分布表现出高拉伸强度和伸长率，即使不使用填料。
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公开(公告)号：US20050131088A1
公开(公告)日：2005-06-16
申请号：US10506025
申请日：2003-01-23
申请人： Volker Stanjek , Oliver Schafer , Bernd Pachaly
发明人： Volker Stanjek , Oliver Schafer , Bernd Pachaly
IPC分类号： C08G18/61 , C08G101/00 , C08J9/00
CPC分类号： C08G18/61 , C08G2101/0008 , C08G2101/0083
摘要： Both flexible and rigid foams may be prepared by reacting di- or polyisocyanates with organopolysiloxanes which are prepared by reaction of silanol-terminated organopolysiloxanes with organosilicon compounds containing alkyleneoxy or alkylenamino groups bonded on both ends to silicon, thus resulting in organopolysiloxanes having 95% or more of aminoalkyl or hydroxyalkyl terminal groups.
摘要翻译： 柔性和刚性泡沫体可以通过使二 - 或多异氰酸酯与有机聚硅氧烷反应来制备，所述有机聚硅氧烷是通过硅烷醇封端的有机聚硅氧烷与两端键合的含有亚烷基氧基或亚烷基氨基的有机硅化合物与硅反应而制备的，从而得到具有95％或更高的有机聚硅氧烷 的氨基烷基或羟烷基端基。
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公开(公告)号：US06440328B1
公开(公告)日：2002-08-27
申请号：US09552448
申请日：2000-04-18
IPC分类号： C09K1920
CPC分类号： C07C67/31 , C07C67/317 , C07C69/92
摘要： The invention relates to a one-step process for the preparation of acryloyl group-containing liquid-crystalline monomers of the general formula (1) (Z—Y1—A2—Y2—)mM(—O—A1-acrylate)n (1) in which mesogenic alcohols of the general formula (2) (Z—Y1—A2—Y2—)mM(OH)n (2) are reacted with esters of 3-chloropropionic acid of the general formula (3) ClPr—A1—X (3) with elimination of HCl, where acrylate is an acrylate radical, ClPr is a 3-chloropropionate radical, A1 are identical or different alkyl chain spacers having 2-20 carbon atoms, in which the carbon chain may be interrupted by non-adjacent ether, thioether, or imino groups, A2 are radicals A1 or single chemical bonds, M is a mesogenic group, X is a leaving group, Z are alkyl radicals or crosslinkable groups, Y1 and Y2, independently of one another, are a single chemical bond, —O—, —S—, —O—CO—, —CO—O—, —O—CO—O, —CO—NR1—, —NR1—CO—, —O—CO—NR1—, —NR1—CO—O— or —NR1—CO—NR1—, R1 is hydrogen or a C1-C4-alkyl radical, n is 1, 2, 3 or 4, and m is 0, 1, 2 or 3.
摘要翻译： 本发明涉及一种制备通式（1）的含丙烯酰基的液晶单体的一步法，其中通式（2）的介晶醇与3-氯丙酸的酯反应 消除HCl的通式（3），其中丙烯酸酯是丙烯酸酯基，ClPr是3-氯丙酸酯基，A1是相同或不同的具有2-20个碳原子的烷基链间隔基，其中碳链可被非 - 相邻的醚，硫醚或亚氨基，A2是基团A1或单个化学键，M是介晶基团，X是离去基团，Z是烷基或可交联基团，Y1和Y2彼此独立地是单 化学键，-O - ， - S-，-O-CO-，-CO-O-，-O-CO-O，-CO-NR1-，-NR1-CO-，-O-CO-NR1-， -NR1-CO-O-或-NR1-CO-NR1-，R1是氢或C1-C4-烷基，n是1,2,3或4，并且m是0,1,2或3。
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