Variable stoichiometry silicon nitride barrier films for tunable etch selectivity and enhanced hyrogen permeability
    61.
    发明授权
    Variable stoichiometry silicon nitride barrier films for tunable etch selectivity and enhanced hyrogen permeability 有权
    用于可调蚀刻选择性和增强的透氢性的可变化学计量氮化硅阻挡膜

    公开(公告)号:US06268299B1

    公开(公告)日:2001-07-31

    申请号:US09668988

    申请日:2000-09-25

    IPC分类号: H01L21318

    CPC分类号: C23C14/0652 H01L21/3185

    摘要: A low-temperature process for forming a highly conformal barrier film during integrated circuit manufacture by low pressure chemical vapor deposition (LPCVD). The process includes the following steps. First, the process provides ammonia and a silicon-containing gas selected from the group consisting of silane, dichlorosilane, bistertiarybutylaminosilanc, hexachlorodisilane, and mixtures of those compositions. The ratio of the volume of ammonia to the volume of the silicon-containing gas is adjusted to yield silicon concentrations greater than 43 atomic percent in the resultant film. The process applies a deposition temperature of 550° C. to 720° C. The ammonia and the silicon-containing gas are reacted at the deposition temperature to form a silicon-rich nitride film less than 200 Å thick. Finally, the silicon nitride film is deposited by low pressure chemical vapor deposition.

    摘要翻译: 在低压化学气相沉积(LPCVD)的集成电路制造过程中形成高保形阻挡膜的低温工艺。 该过程包括以下步骤。 首先,该方法提供氨和含硅气体,其选自硅烷,二氯硅烷,二丁基氨基硅烷,六氯二硅烷,以及这些组合物的混合物。 调节氨体积与含硅气体体积的比例,得到所得膜中硅浓度大于43原子百分比。 该方法将沉积温度为550℃至720℃。氨和含硅气体在沉积温度下反应,形成厚度小于200埃的富硅氮化物膜。 最后,通过低压化学气相沉积沉积氮化硅膜。