Abstract:
A monolith catalyst carrier for insertion in a tube of a tubular reactor has a container for holding a monolith catalyst in use. The container has a bottom surface closing the container and a skirt extending upwardly from the bottom surface of the container to a position below the location of a seal and spaced therefrom. The skirt is positioned such that there is a space between an outer surface of the monolith catalyst and the skirt. A seal is located at or near a top surface of the monolith catalyst and extends from the monolith catalyst by a distance which extends beyond an outer surface of the skirt.
Abstract:
In a process for removing aromatic carboxylic acid from a slurry thereof in solvent, the slurry is split into sub streams and each of said sub streams is supplied to a respective rotary pressure filter such that the sub stream pass through the filters in parallel. Gas is passed through the rotary pressure filters in series in an open-loop arrangement.
Abstract:
A catalyst carrier for insertion in a radial tube reactor, said catalyst carrier comprising: an annular container for holding catalyst in use, said container having a perforated inner wall defining a tube, a perforated outer wall, a top surface closing the annular container and a bottom surface closing the annular container; a surface closing the bottom of said tube formed by the inner wall of the annular container; a skirt extending upwardly from the perforated outer wall of the annular container from a position at or near the bottom surface of said container to a position below the location of a seal; and a seal located at or near the top surface and extending from the container by a distance which extends beyond an outer surface of the skirt.
Abstract:
A process for the co-production of a stream of a fatty alcohol having first carbon chain lengths and a stream of a fatty alcohol having second carbon chain lengths, said second carbon chain lengths being longer than said first carbon chain lengths.
Abstract:
In a process for distillation, in a distillation column, of a crude stream of methanol produced from synthesis gas, fusel oil is removed from the distillation column as a vapour side draw from a point in the distillation column below the feed, and the vapour side draw is substantially free of alkali. A process for the production of methanol utilising this distillation process is also described.
Abstract:
A process for the co-production of a stream of a fatty alcohol having first carbon chain lengths and a stream of a fatty alcohol having a second carbon chain lengths, said second carbon chain lengths being longer than said first carbon chain lengths, said process comprising the steps of: (a) supplying a stream comprising lower alkyl esters of fatty acids having chain lengths comprising the first and second chain lengths to a first vaporisation zone and contacting said stream with an amount of hydrogen which is sufficient to vaporise the lower alkyl esters of the fatty acids having the first carbon chain lengths into the hydrogen; (b) supplying the hydrogen and the vaporised lower alkyl esters of fatty acids having the first carbon chain lengths to a first reaction zone comprising catalyst and operating under reaction conditions to allow hydrogenation to the desired alcohol having first carbon chain lengths; (c) recovering from the first reaction zone an alcohol product stream having first carbon chain lengths and hydrogen; (d) separating the stream of fatty alcohol having the first carbon chain lengths from hydrogen; (e) supplying the unvaporised lower alkyl esters of the fatty acids having second carbon chain lengths remaining from step (a) to a second vaporisation zone; (f) contacting the unvaporised lower alkyl esters having second carbon chain lengths in the second vaporisation zone with hydrogen recovered in step (d) and an additional amount of hydrogen such that the total amount of hydrogen is sufficient to vaporise the lower alkyl esters having fatty acids of the second carbon chain lengths into the hydrogen; (g) supplying the hydrogen and the vaporised lower alkyl esters of fatty acids having second carbon chain lengths to a second reaction zone comprising catalyst and operating under reaction conditions to allow hydrogenation to the desired alcohol having second carbon chain lengths; and (h) recovering from the second reaction zone an alcohol product stream having second carbon chain lengths and hydrogen.
Abstract:
A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.
Abstract:
A process for hydrogenation of glycerol in which a feed comprising glycerol is contacted with a stream of a hydrogen-containing gas and subjected to hydrogenation in the vapour phase in the presence of a catalyst at a temperature of from about 160° C. to about 260° C., a pressure of from about 10 to about 30 bar, a hydrogen to glycerol ratio of from 400:1 to about 600:1 and a residence time of from about 0.01 to about 2.5 secs.
Abstract:
A process for use in equilibrium exothermic gas phase reactions comprising the steps of (a) providing a recycle stream with the addition of make-up gas, to form a feed gas stream; (b) heating the feed gas stream; (c) passing the heated feed gas stream to a first reactor containing a catalyst for the exothermic gas phase reactions at conditions suitable for the reaction; (d) removing a product stream comprising product and unreacted gases from the first reactor; (e) cooling and partially condensing the product stream to form a gas phase and a liquid phase; (f) separating the liquid phase containing the desired product from the product stream and removing said liquid phase; (g) separating the gas phase from the product stream to form a gas stream; (h) optionally mixing the gas stream from the product stream with additional make-up gas; (i) heating the gas stream; (j) passing the heated gas stream to a final reactor containing a catalyst for the exothermic gas phase reactions at conditions suitable for the reaction; (k) removing a final product stream comprising product and unreacted gases from the final reactor; (l) cooling and partially condensing the final product stream to form a final gas phase and a mal liquid phase; (m) separating the final liquid phase containing the desired product from the final product stream and removing said final liquid phase; and (n) separating the gas phase from the final product stream and recycling the gas to step (a); and in which the gas stream from step (g) is compressed prior to heating in step (i).
Abstract:
A homogeneous process for the hydrogenation of dicarboxylic acids and/or anhydrides in the presence of a catalyst comprising: (a) ruthenium, rhodium, iron, osmium or palladium; and (b) an organic phosphine; wherein the hydrogenation is carried out in the presence of at least about 1% by weight water and wherein the reaction is carried out at a pressure of from about 500 psig to about 2000 psig and a temperature of from about 200° C. to about 300° C. such that from about 1 mol to about 10 mol of hydrogen are used to strip 1 mole of product from the reactor.