Method for improving adhesion of water-based inks to halogen-containing resin articles
    63.
    发明授权
    Method for improving adhesion of water-based inks to halogen-containing resin articles 失效
    提高水性油墨对含卤素树脂制品的附着力的方法

    公开(公告)号:US07025904B2

    公开(公告)日:2006-04-11

    申请号:US10655459

    申请日:2003-09-04

    摘要: Flexible and semi-rigid vinyl chloride resin compositions comprising a combination of a latent mercaptan and a zinc salt of oxidized polyethylene (a zinc ionomer) as a heat stabilizer are substantially free from the offensive odor typically associated with mercaptans and are protected during processing by the degradation products of the latent mercaptan and the zinc ionomer. The oxidized polyethylene is split out from the ionomer to act as an adhesion promoter for aqueous inks and paints, and the residual zinc carboxylate functions as a co-stabilizer with the latent mercaptan in the composition. The latent mercaptan is exemplified by a 2-S-(tetrahydropyranyl)thioalkanol, a carboxylic acid ester thereof, a 2-S-(tetrahydropyranyl)-thiocarboxylic acid, an ester thereof, and the furanyl homologs of each.

    摘要翻译: 包含作为热稳定剂的氧化聚乙烯(锌离子交联聚合物)的潜在硫醇和锌盐的组合的柔性和半刚性氯乙烯树脂组合物基本上没有通常与硫醇相关的令人反感的气味,并且在加工过程中受到保护 潜硫醇和锌离聚物的降解产物。 氧化的聚乙烯从离聚物中分离出来,用作水性油墨和油漆的粘合促进剂,残留的羧酸锌起着与组合物中潜在的硫醇的共稳定剂的作用。 潜硫族的例子有2-S-(四氢吡喃基)硫代烷醇,其羧酸酯,2-S-(四氢吡喃基) - 硫代羧酸及其酯,和各自的呋喃基同系物。

    Color filter black matrix resist composition
    64.
    发明申请
    Color filter black matrix resist composition 审中-公开
    滤色片黑矩阵抗蚀剂组成

    公开(公告)号:US20060036023A1

    公开(公告)日:2006-02-16

    申请号:US10539037

    申请日:2003-12-15

    IPC分类号: C08L31/00

    摘要: The present invention relates to (1) a photosensitive composition for color filter black matrix resists, containing (A) a binder resin having a carboxyl group, (B) a compound having an ethylenically unsaturated bond, (C) a photopolymerizing initiator, (D) a thiol compound having two or more mercapto-group-containing groups in which carbon atoms at the a-position and/or n-position with respect to the mercapto group have a substituent, and (E) an organic solvent, and having high sensitivity and excellent storage stability; and (2) color filterblack blackmatrix resist containing (1) the photosensitive composition for color filter black matrix resists and a black pigment (F).

    摘要翻译: 本发明涉及(1)一种用于滤色器黑底抗蚀剂的感光组合物,其包含(A)具有羧基的粘合剂树脂,(B)具有烯属不饱和键的化合物,(C)光聚合引发剂,(D )具有两个或多个含巯基的基团的硫醇化合物,其中在α-位和/或n位相对于巯基的碳原子具有取代基,和(E)有机溶剂,并且具有高的 灵敏度和优良的储存稳定性; 和(2)含有(1)用于滤色器黑底抗蚀剂的光敏组合物和黑色颜料(F)的彩色黑色黑矩阵抗蚀剂。

    High CoR golf ball using zinc dimethacrylate
    66.
    发明申请
    High CoR golf ball using zinc dimethacrylate 失效
    高CoR高尔夫球使用二甲基丙烯酸锌

    公开(公告)号:US20050137344A1

    公开(公告)日:2005-06-23

    申请号:US10740530

    申请日:2003-12-22

    申请人: Peter Voorheis

    发明人: Peter Voorheis

    摘要: The present invention is directed to resilient golf balls and portions thereof including compositions containing zinc dimethacrylate and zinc pentachlorothiophenol, and methods for making same. In particular, the present invention is directed to a golf ball having at least one of a center, cover, or intermediate layer that includes a reaction product that includes a resilient polymer component, a free radical source, zinc dimethacrylate and at least one halogenated organosulfur compound having the following general formula I: where R1-R5 can be substituted or unsubstituted C1-C8 alkyl groups; halogen groups; thiol groups (—SH), carboxylated groups; sulfonated groups; and hydrogen; in any order.

    摘要翻译: 本发明涉及弹性高尔夫球及其部分,包括含有二甲基丙烯酸锌和五氯硫酚锌的组合物及其制备方法。 特别地,本发明涉及一种高尔夫球,其具有包括弹性聚合物组分,自由基源,二甲基丙烯酸锌和至少一种卤化有机硫的反应产物的中心层,覆盖层或中间层中的至少一个 具有以下通式I的化合物:其中R 1 -R 5可以是取代或未取代的C 1 -C 8 - 烷基; 卤素基团; 硫醇基(-SH),羧基; 磺化基团; 和氢; 以任何顺序。

    Latent mercaptans as multi-functional additives for halogen-containing polymer compositions

    公开(公告)号:US06790892B1

    公开(公告)日:2004-09-14

    申请号:US09368150

    申请日:1999-08-04

    IPC分类号: C08K536

    CPC分类号: C08K5/37 C08L57/08

    摘要: Halogen-containing polymer compositions comprising a latent mercaptan-containing heat stabilizer composition substantially free from the offensive odor typically associated with mercaptans are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan may be the sole heat stabilizer additive but the free mercaptan released during processing may also synergize the activity of metal-based heat stabilizers such as metal salts and organometallic stabilizers such as organotin carboxylates and mercaptides in the polymer composition. The odor of primary mercaptan-containing heat stabilizers in halogenated polymer compositions is masked by a small amount of a latent mercaptan. The latent mercaptans also serve as intermediates in the preparation of anti-oxidants, anti-microbial agents, photostabilizers, and primary heat stabilizers. Highly effective heat stabilizers are prepared by the condensation of formaldehyde and a para-phenol and further condensation of the crude product with a mercapto-containing compound.

    Method for improving adhesion of water-based inks to halogen-containing resin articles
    70.
    发明授权
    Method for improving adhesion of water-based inks to halogen-containing resin articles 有权
    提高水性油墨对含卤素树脂制品的附着力的方法

    公开(公告)号:US06706792B2

    公开(公告)日:2004-03-16

    申请号:US09320304

    申请日:1999-05-26

    IPC分类号: C08K536

    摘要: Flexible and semi-rigid vinyl chloride resin compositions comprising a combination of a latent mercaptan and a zinc salt of oxidized polyethylene (a zinc ionomer) as a heat stabilizer are substantially free from the offensive odor typically associated with mercaptans and are protected during processing by the degradation products of the latent mercaptan and the zinc ionomer. The oxidized polyethylene is split out from the ionomer to act as an adhesion promoter for aqueous inks and paints, and the residual zinc carboxylate functions as a co-stabilizer with the latent mercaptan in the composition. The latent mercaptan is exemplified by a 2-S-(tetrahydropyranyl)thioalkanol, a carboxylic acid ester thereof, a 2-S-(tetrahydropyranyl)thiocarboxylic acid, an ester thereof, and the furanyl homologs of each.

    摘要翻译: 包含作为热稳定剂的氧化聚乙烯(锌离子交联聚合物)的潜在硫醇和锌盐的组合的柔性和半刚性氯乙烯树脂组合物基本上没有通常与硫醇相关的令人反感的气味,并且在加工过程中受到保护 潜硫醇和锌离聚物的降解产物。 氧化的聚乙烯从离聚物中分离出来,用作水性油墨和油漆的粘合促进剂,残留的羧酸锌起着与组合物中潜在的硫醇的共稳定剂的作用。 潜在的硫醇的例子有2-S-(四氢吡喃基)硫代烷醇,其羧酸酯,2-S-(四氢吡喃基)硫代羧酸,其酯和各自的呋喃基同系物。