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    REACTIVE DYES, THEIR PREPARATION AND THEIR USE
    71.
    发明申请
    REACTIVE DYES, THEIR PREPARATION AND THEIR USE 失效
    反应性染料及其制备及其使用

    公开(公告)号：US20100154145A1

    公开(公告)日：2010-06-24

    申请号：US12063277

    申请日：2006-08-02

    申请人： Hubert Jean Luc Christnacher ,  Athanassios Tzikas ,  Georg Roentgen

    发明人： Hubert Jean Luc Christnacher ,  Athanassios Tzikas ,  Georg Roentgen

    IPC分类号： D06P1/38 ,  C09B44/00 ,  B05D5/00

    CPC分类号： C09B62/043 ,  C09B62/4416 ,  Y10S8/918

    摘要： Reactive dyes of formula wherein B is an aliphatic bridging member, R1 is C1-C4alkyl, halogen or an —SO2—Z radical, R2 and R3 are each independently of the other C1-C4alkoxy, R4, R5 and R6 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, p is the number 0, 1 or 2, X1 and X2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R7)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group and Hal is halogen, or T is a radical of formula wherein R1, R2, R3, R4, k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.

    摘要翻译： R 1为C 1 -C 4烷基，卤素或-SO 2 - Z基团，R 2和R 3各自独立地为C 1 -C 4烷氧基，R 4，R 5和R 6各自独立地为 其他氢或未取代或取代的C 1 -C 4烷基，k和q各自独立地为数字0或1，p为数0,1或2，X 1和X 2各自独立地为其它卤素，T为卤素 ，非光纤反应性取代基或下式的纤维反应性基团其中（R7）0-2表示0至2个相同或不同的取代基，如卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基 或-CH 2 -CH 2 -U基团，U是在碱性条件下可除去的基团，Q是-CH（Hal）-CH 2 - Hal或-C（Hal）= CH 2基团，Hal是卤素，或T是 其中R1，R2，R3，R4，k，p和q各自具有上述定义的基团，其特别适用于染色棉花和具有良好全部成分的产量染色剂， 圆形坚牢性。

    Mixtures of reactive dyes and their use in a method for trichromatic dyeing or printing
    72.
    发明授权
    Mixtures of reactive dyes and their use in a method for trichromatic dyeing or printing 有权
    活性染料的混合物及其在三色染色或印刷方法中的应用

    公开(公告)号：US07604669B2

    公开(公告)日：2009-10-20

    申请号：US12094429

    申请日：2006-11-06

    申请人： Jean-Marie Sire ,  Athanassios Tzikas ,  Georg Roentgen

    发明人： Jean-Marie Sire ,  Athanassios Tzikas ,  Georg Roentgen

    IPC分类号： C09B62/00

    CPC分类号： C09B62/4416 ,  C09B31/057 ,  C09B62/043 ,  C09B62/095 ,  C09B62/4413 ,  C09B62/4415 ,  C09B67/0047 ,  Y10S8/918

    摘要： Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fiber-reactive substituent or a fiber-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fiber materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.

    摘要翻译： 染料混合物，包含至少一种式的染料和至少一种下式基团的染料，其中B1，B2和B3各自独立地为有机桥连构件，Q1为C1-C4烷基，卤素或-SO2- Z，Q2和Q3各自独立地为C 1 -C 4烷氧基，Q 4为C 1 -C 4烷氧基，C 1 -C 4烷基，卤素或磺基Q 5为C 1 -C 4烷氧基，C 1 -C 4烷基，C 1 -C 4烷酰基氨基，脲基，卤素或磺基， R 2，R 3，R 4，R 5，R 6，R 7，R 8和R 9各自独立地为氢或未取代或取代的C 1 -C 4烷基，k和q各自独立地为数个0或1，n和p分别为 独立于数字0,1或2，m是数字0,1,2或3，t是数字1,2或3，X1，X2，X3，X4，X5和X6各自独立于 其他卤素，T1，T2和T3各自独立地为非纤维反应性取代基或下式的纤维反应性基团其中（R 10）0-2表示0至2个相同或不同的取代基 卤素，C1-C4烷基，C1-C4烷氧基和磺基，Z是乙烯基或基团-CH2-CH2-U，U是在碱性条件下可除去的基团，Q是基团-CH（Hal）-CH 2 - Hal或-C（Hal）= CH2，Hal是卤素，特别适用于纤维素纤维材料的双色或三色染色或印花，并且具有良好的再现性和良好的全面牢固性能的产量染色或印花。

    Reactive polysaccharide derivatives, their preparation and their use
    73.
    发明申请
    Reactive polysaccharide derivatives, their preparation and their use 审中-公开
    活性多糖衍生物，其制备及其应用

    公开(公告)号：US20070113356A1

    公开(公告)日：2007-05-24

    申请号：US10583012

    申请日：2004-12-08

    申请人： Veronique Hall-Goulle ,  Athanassios Tzikas

    发明人： Veronique Hall-Goulle ,  Athanassios Tzikas

    IPC分类号： D06M13/322 ,  C07H17/02

    CPC分类号： D06M15/03

    摘要： A reactive polysaccharide derivative of formula (1a) or (1b), in which A is —O—, —S— or (1c), Q1 is hydrogen, the radical —B—A—Z, C1-C10aryl which is unsubstituted or substituted, C1-C12alkyl which may be interrupted by oxygen and is unsubstituted or substituted, Q2 and Q3 are each independently of the other hydrogen, C1-C12aryl which is unsubstituted or substituted, C1-C12alkyl which may be interrupted by oxygen and is unsubstituted or substituted, B is an aliphatic or aromatic bridge member, Z1 and Z2 are each independently of the other a reactive radical of the vinylsulfonyl series, the haloacryloyl series or the heterocyclic series, PS is a polysaccharide radical, m is 0, 1 or an integer greater than 1, n is 1 or an integer greater than 1, and the sum of n+m corresponds to the original number of hydroxy groups in the polysaccharide molecule, is useful as a finishing agent for textile fibers and for other applications.

    摘要翻译： 式（1a）或（1b）的反应性多糖衍生物，其中A是-O-，-S-或（1c），Q 1是氢，基团-BAZ，C 未被取代或取代的C 1 -C 12烷基，其可以被氧中断，未被取代或被取代，B是脂族或芳族桥连构件Z Z 1和Z 2各自独立地为乙烯基磺酰基系列的反应性基团，卤代丙烯酰基系列或杂环系列，PS为多糖基团，m为0， 1或大于1的整数，n为1或大于1的整数，n + m的和对应于多糖分子中原始的羟基数， 可用作纺织纤维和其他应用的整理剂。

    Mixtures of reactive dyes and their use
    74.
    发明申请
    Mixtures of reactive dyes and their use 审中-公开
    活性染料的混合物及其用途

    公开(公告)号：US20070032641A1

    公开(公告)日：2007-02-08

    申请号：US10576056

    申请日：2004-10-11

    申请人： Athanassios Tzikas ,  Georg Roentgen ,  Laszlo Fekete

    发明人： Athanassios Tzikas ,  Georg Roentgen ,  Laszlo Fekete

    IPC分类号： C09D11/00 ,  C09B46/00

    CPC分类号： D06P1/38 ,  C09B67/0072 ,  C09D11/32 ,  D06P3/10 ,  D06P3/66 ,  D06P5/30

    摘要： Dye mixtures comprising at least one dye of formula (1) together with at least one dye from the group of formulae (2a) and (2b), wherein the radicals are as defined in the claim, are suitable for dyeing or printing cellulosic fibre materials while having a good build-up behaviour and yield dyeings of a deep shade having good fastness properties.

    摘要翻译： 包含至少一种式（1）染料与至少一种式（2a）和（2b）基团的染料的染料混合物，其中所述基团如权利要求中所定义，适用于染色或印刷纤维素纤维材料 同时具有良好的积聚行为和产生具有良好牢度性质的深色调的染色。

    Asymmetrical reactive dyes containing two triazinyl radicals which are bridged via an aliphatic bridge member
    77.
    发明授权
    Asymmetrical reactive dyes containing two triazinyl radicals which are bridged via an aliphatic bridge member 失效
    不对称活性染料含有通过脂族桥连桥连接的两个三嗪基

    公开(公告)号：US5684138A

    公开(公告)日：1997-11-04

    申请号：US657455

    申请日：1996-05-29

    申请人： Herbert Klier ,  Bernhard Muller ,  Edmond Ruhlmann ,  Athanassios Tzikas

    发明人： Herbert Klier ,  Bernhard Muller ,  Edmond Ruhlmann ,  Athanassios Tzikas

    IPC分类号： C09B62/04 ,  C09B62/085 ,  C09B62/09 ,  C09B62/44 ,  C09B62/51 ,  C09B62/503 ,  D06P1/38 ,  D06P3/66

    CPC分类号： C09B62/4403 ,  C09B62/043

    摘要： Reactive dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, B is an aliphatic bridge member, Y.sub.1 and Y.sub.2 independently of one another are halogen or carboxypyridinium, A.sub.1 is the radical of an anthraquinone, phthalocyanine, dioxazine, formazan or disazo dye or a radical of the formulae (2a) to (2h) defined in claim 1 and A.sub.2 is as defined above for A.sub.1 or is a radical of the formulae (2i) to (2m), where A.sub.1 and A.sub.2 have different meanings to one another, are particularly suitable for dyeing or printing fibre materials containing hydroxyl groups or containing nitrogen. Dyeings having good fastness properties coupled with a high tinctorial yield are obtained.

    摘要翻译： 式（1）中的R 1，R 2，R 3和R 4彼此独立地是氢或取代或未取代的C 1 -C 4烷基，B是脂族桥连构件的反应性染料，Y1和Y2彼此独立地是卤素 或羧基吡啶鎓，A1是蒽醌，酞菁，二恶嗪，甲an或二偶氮染料或权利要求1和A2中定义的式（2a）至（2h）基团的基团如上对于A1所定义，或者为 式（2i）至（2m），其中A1和A2彼此具有不同的含义，特别适用于染色或印刷含有羟基或含氮的纤维材料。 得到具有良好牢度性能和高着色性能的染色剂。

    Reactive dyes, process for their preparation and the use thereof
    78.
    发明授权
    Reactive dyes, process for their preparation and the use thereof 失效
    活性染料，其制备方法及其用途

    公开(公告)号：US5597904A

    公开(公告)日：1997-01-28

    申请号：US614119

    申请日：1996-03-12

    申请人： Athanassios Tzikas ,  Claudia Carisch

    发明人： Athanassios Tzikas ,  Claudia Carisch

    IPC分类号： C09B62/51 ,  C09B62/45 ,  D06P3/24 ,  D06P3/66 ,  C09B62/473 ,  D06P1/384

    CPC分类号： C09B62/45

    摘要： Reactive dyes of formula ##STR1## wherein Z is a group of formula --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y, and Y is a leaving group, and K is a radical of formula ##STR2## wherein X is a radical of formula --(CH.sub.2).sub.n --Cl, ##STR3## or --CH.dbd.CH.sub.2 ; Hal is halogen; and n is 1, 2, 3 or 4; R is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl; R.sub.1 is amino or hydroxyl; R.sub.2 is methyl or carboxyl; and R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or carboxyl, are particularly suitable for dyeing or printing cellulosic fibre materials or natural or synthetic polyamide fibre materials in high tinctorial yield, and give dyeings and printings with good fastness properties.

    摘要翻译： 式（1）的活性染料其中Z为式-CH = CH 2或-CH 2 -CH 2 -Y基团，Y为离去基团，K为式（2）或 （3）其中X是式 - （CH2）n-Cl，或-CH = CH2的基团; 卤素是卤素; n为1,2,3或4; R是氢或未取代的或取代的C 1 -C 4烷基; R1是氨基或羟基; R2是甲基或羧基; 和R 3为氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，卤素或羧基，特别适用于染色或印刷高亮度产率的纤维素纤维材料或天然或合成聚酰胺纤维材料，并具有良好的染色和印花 坚牢性。