公开(公告)号：US20080256726A1

公开(公告)日：2008-10-23

申请号：US12094429

申请日：2006-11-06

申请人： Jean-Marie Sire ,  Athanassios Tzikas ,  Georg Roentgen

发明人： Jean-Marie Sire ,  Athanassios Tzikas ,  Georg Roentgen

IPC分类号： C09B62/01 ,  C09B44/18

CPC分类号： C09B62/4416 ,  C09B31/057 ,  C09B62/043 ,  C09B62/095 ,  C09B62/4413 ,  C09B62/4415 ,  C09B67/0047 ,  Y10S8/918

摘要： Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.

公开(公告)号：US20040107517A1

公开(公告)日：2004-06-10

申请号：US10611438

申请日：2003-07-01

发明人： Warren James Ebenezer ,  Werner Russ

IPC分类号： D06P005/00

CPC分类号： C09B62/09 ,  C09B62/043 ,  C09B62/082

摘要： The present invention refers to dyestuffs of the formula I 1 wherein each of R1, R2, R3, R4 and R5, independently, is H or an optionally substituted alkyl group; each of X1 and X2, independently, is a labile atom or group; each of x and y, independently, is 0 or 1 and at least one of x and y is 1; each of a and b is 2 to 5 and when each of x and y is 1, a>b; and z is 0, 1, 2, 3 or 4; and wherein the variables D1 and D2 are defined as given in claim 1, processes for their preparation and their use for dyeing and printing hydroxy- and/or carboxamido-containing fiber materials.

摘要翻译： 本发明涉及式I的染料，其中R 1，R 2，R 3，R 4和R 5各自独立地为H或任选取代的烷基; X1和X2各自独立地是不稳定的原子或基团; x和y各自独立地为0或1，x和y中的至少一个为1; a和b中的每一个为2至5，并且当x和y各自为1时，a> b; 且z为0,1,2,3或4; 并且其中变量D1和D2如权利要求1中所定义，其制备方法及其用于染色和印刷含羟基和/或羧酰氨基的纤维材料的用途。

公开(公告)号：US06592634B1

公开(公告)日：2003-07-15

申请号：US09521711

申请日：2000-03-09

申请人： Hans Reichert ,  Thomas Verdugo

发明人： Hans Reichert ,  Thomas Verdugo

IPC分类号： D06P1382

CPC分类号： C09B62/4403 ,  C09B62/021 ,  C09B62/043 ,  C09B62/205 ,  Y10S8/918

摘要： Reactive dyes of the formula (1) in which R1, R2, R3 and R4 independently of one another are hydrogen or substituted or unsubstituted C1-C4alkyl, (R5)0-2 and (R6)0-2 independently of one another are 0 to 2 identical or different substituents from the group consisting of C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, halogen, carboxyl, sulfo, carbamoyl, N-C1-C4alkylcarbamoyl, N,N-di-C1-C4alkylcarbamoyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylsulfamoyl and N,N-di-C1-C4alkylsulfamoyl, A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl or naphthyl which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C1-C4alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl, ureido or halogen, or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl, B1 is an aliphatic or aromatic bridge member, and the remaining substituents are described in the specification.

摘要翻译： 其中R 1，R 2，R 3和R 4彼此独立地是式（1）的反应性染料是氢或取代或未取代的C 1 -C 4烷基，（R 5）0-2和（R 6） 2个与C1-C4烷基，C1-C4烷氧基，C2-C4烷酰基氨基，卤素，羧基，磺基，氨基甲酰基，N-C1-C4烷基氨基甲酰基，N，N-二C1-C4烷基氨基甲酰基，C1-C4烷基磺酰基， 氨磺酰基，N-C 1 -C 4烷基氨磺酰基和N，N-二-C 1 -C 4烷基氨磺酰基，A是未取代或被羟基，磺基，羧基或硫酸酯取代的C 1 -C 4烷基，未被取代或被C1- C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，羟基，羧基，氨基甲酰基，磺基或卤素，苯基-C 1 -C 4亚烷基，其未被取代或在苯环中被C1-C4烷基，C1-C4烷氧基，C2-C4烷酰基氨基，羟基， ，磺基，氨基甲酰基，脲基或卤素，或未被取代或被C 1 -C 4烷基取代的C 5 -C 7环烷基 ，B1是脂族或芳族桥连构件，其余的取代基在说明书中描述。

公开(公告)号：US20030079648A1

公开(公告)日：2003-05-01

申请号：US10088352

申请日：2002-03-15

发明人： Yoriaki Matsuzaki ,  Kenichi Fujii ,  Osamu Kohgo ,  Hiroshi Naruse ,  Tsutami Misawa

IPC分类号： C09D011/00 ,  C09B029/09

CPC分类号： C09D11/328 ,  C09B43/16 ,  C09B62/043 ,  C09B62/08

摘要： Aqueous ink for ink jet recording comprising a coloring matter and an aqueous medium as main components, in which at least one of dyes represented by the formula (A) or their salts is contained as the coloring matter. 1 nullwherein R1 and R3, independently from each other, represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkoxy group, an amino group, a hydroxyl group or a halogen atom, R2 and R4, independently from each other, represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted aryl group or an aralkyl group, A represents an optionally substituted phenyl group or naphthyl group, X represents divalent bonding group free from a saturated carbon ring, and m and n, independently from each other, represent an integer of 1 to 4null. As the dye represented by the formula (A), a dye produced by adjusting pH of an aqueous solution of the dye to 9 or more to remove insoluble matters formed is preferably used. The aqueous ink can be provided in which clogging of a printer head is eliminated, formation of a high-quality image without blotting is enabled and a recorded image has also excellent properties in light fastness, moisture resistance and storage stability.

摘要翻译： 用于喷墨记录的水性油墨包括着色剂和水性介质作为主要成分，其中至少一种由式（A）表示的染料或其盐作为着色剂。 [其中R1和R3彼此独立地表示氢原子，任选取代的烷基，任选取代的烷氧基，氨基，羟基或卤素原子，R 2和R 4彼此独立地表示 氢原子，任选取代的烷基，任选取代的芳基或芳烷基，A表示任选取代的苯基或萘基，X表示不含饱和碳环的二价键合基​​团，m和n独立地为 彼此表示1〜4的整数]。 作为由式（A）表示的染料，优选使用通过将染料的水溶液的pH调节至9以上以除去形成的不溶性物质而生成的染料。 可以提供消除打印头堵塞的水性墨水，能够形成无印迹的高质量图像，并且记录图像在耐光性，耐湿性和储存稳定性方面也具有优异的性能。

公开(公告)号：US6022384A

公开(公告)日：2000-02-08

申请号：US256777

申请日：1999-02-24

申请人： John Anthony Taylor

发明人： John Anthony Taylor

IPC分类号： C09B62/085 ,  C09B62/04 ,  D06P1/382 ,  D06P3/66

CPC分类号： C09B62/043 ,  D06P1/382 ,  D06P3/663

摘要： The present invention relates to a water-soluble reactive dye of the formula N(Z).sub.3, wherein each Z independently has the formula (III): ##STR1## wherein m, Q, Y and D are defined in the claims. The present invention also relates to a process for coloring a substrate that includes applying to the substrate the water-soluble reactive dye of the above formula at a pH above 7.

摘要翻译： 本发明涉及式N（Z）3的水溶性活性染料，其中每个Z独立地具有式（III）：其中m，Q，Y和D如权利要求中所定义。 本发明还涉及对基材着色的方法，其包括在pH高于7的情况下将上式的水溶性活性染料施用于基材。

公开(公告)号：US5698681A

公开(公告)日：1997-12-16

申请号：US671785

申请日：1996-06-19

申请人： Paul Doswald

发明人： Paul Doswald

IPC分类号： C07D401/14 ,  C09B43/16 ,  C09B62/04 ,  C09B62/09 ,  D06P1/382 ,  D06P3/26 ,  D06P3/66

CPC分类号： C09B62/043 ,  C09B62/09

摘要： Fiber-reactive disazo dyes correspond to formula I, ##STR1## and they are present as free acids or in salt form. They are used as reactive dyes for dyeing or printing hydroxy-group-containing or nitrogen-containing organic substrates, especially leather or fibrous material, which consists of or contains natural or synthetic polyamides or natural or regenerated cellulose. The dyeings obtained have high fixation values and good light fastness.

摘要翻译： 纤维反应性双偶氮染料对应于式I，它们以游离酸或盐形式存在。 它们用作染料或印刷含羟基或含氮有机基材，特别是由天然或合成聚酰胺或天然或再生纤维素组成或含有天然或合成聚酰胺或天然或再生纤维素的皮革或纤维材料的活性染料。 获得的染色具有较高的固色值和良好的耐光性。

公开(公告)号：US5410041A

公开(公告)日：1995-04-25

申请号：US107475

申请日：1993-08-13

申请人： Bernhard Muller

发明人： Bernhard Muller

IPC分类号： C09B62/04 ,  C09B62/06 ,  C09B62/08 ,  C09B62/10 ,  C09B67/26 ,  D06P3/66 ,  D06P1/382

CPC分类号： D06P3/663 ,  C09B62/043

摘要： The invention relates to fibre-reactive dyes of formula ##STR1## wherein the variables are as defined in the claims. These dyes are especially suitable for dyeing cellulosic fibre materials and produce dyeings of good tinctorial strength and good fastness properties.

摘要翻译： 本发明涉及式（1）的纤维反应性染料，其中变量如权利要求中所定义。 这些染料特别适用于染色纤维素纤维材料，并产生良好着色强度和良好牢度性能的染色。

公开(公告)号：US5245020A

公开(公告)日：1993-09-14

申请号：US853518

申请日：1992-03-18

申请人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

发明人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

IPC分类号： C09B62/04

CPC分类号： C09B62/043

摘要： Reactive dyes of the formula ##STR1## where l is 0 or 1,n is 0 or 1,E is nitrogen or C--ClA is the radical of an azo dye attached to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimido group,B--if E is nitrogen--is the radical of an azo dye or of a formazan dye which in either case is bonded to the triazine ring via an imino of C.sub.1 -C.sub.4 -alkylimino group or else--if n is 0--is fluorine, chlorine or unsubstituted or substituted amino, or--if E is C--Cl--is fluorine, chlorine or methyl,X.sup.1 and X.sup.2 are independently of the other fluorine or chlorine,X.sup.3 is fluorine or chlorine or else--if E is C--Cl--methylsulfonyl andZ.sup.1 and Z.sup.2 are independently of the the other a radical of the formula ##STR2## where L.sup.3 and L.sup.4 are independently of the other hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl,with the proviso that l and n are not simultaneously 0 and that, if E is C--Cl or if n is 0 and Z.sup.1 is the radical of the formula ##STR3## where L.sup.3 and L.sup.4 are each as defined above, A may also be the radical of a formazan dye which is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group, are useful for dyeing or printing hydroxyl- or nitrogen-containing substrates.

摘要翻译： 其中l为0或1的反应性染料，其中l为0或1，n为0或1，E为氮或C-Cl为经由亚氨基或C 1 -C 4烷基亚氨基连接到三嗪环上的偶氮染料的基团 基团，B-如果E是氮，则是偶氮染料或甲an染料的基团，在任一情况下，通过C 1 -C 4 - 烷基亚氨基的亚氨基键合到三嗪环，或者 - 如果n是0- 氟，氯或未取代或取代的氨基，或 - 如果E是C-Cl-是氟，氯或甲基，则X1和X2独立于其它氟或氯，X3是氟或氯，或者 - 如果E是C- Cl-甲基磺酰基，Z 1和Z 2独立地为下式的基团：其中L 3和L 4独立于另一个氢或未取代或取代的C 1 -C 4 - 烷基，条件是 l和n不同时为0，并且如果E是C-Cl，或者如果n是0，并且Z1是式“IMAGE”的基团，其中L3和L4各自如上定义，则A也可以是 通过亚氨基或C 1 -C 4烷基亚胺基与三嗪环结合的甲an染料的基团可用于染色或印刷含羟基或含氮基底。

公开(公告)号：US5216137A

公开(公告)日：1993-06-01

申请号：US726242

申请日：1991-07-05

申请人： Hermann Loeffler ,  Manfred Patsch ,  Reinhold Krallmann

发明人： Hermann Loeffler ,  Manfred Patsch ,  Reinhold Krallmann

IPC分类号： C09B62/04

CPC分类号： C09B62/043

摘要： Azo reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where m is 0, 1 or 2,n is 0 or 1,p is 0 or 1,R.sup.1 and R.sup.2 are each independently of the other hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,R.sup.3 is hydrogen, methyl or ethyl,T is carboxyl or hydroxysulfonyl,Hal is fluorine or chlorine, andthe ring A may be benzofused or substituted.

摘要翻译： 可用于染色或印刷含羟基或含氮底物的偶氮活性染料具有式（1）其中m为0,1或2，n为0或1，p为0或1， R 1和R 2各自独立地为另一个氢或取代或未取代的C 1 -C 4 - 烷基，R 3是氢，甲基或乙基，T是羧基或羟基磺酰基，Hal是氟或氯，并且环A可以是苯并稠合或取代的。

公开(公告)号：US5197992A

公开(公告)日：1993-03-30

申请号：US648517

申请日：1991-01-30

申请人： John A. Taylor ,  Duncan A. S. Phillips ,  Chu K. Yung ,  Gerard Ellis

发明人： John A. Taylor ,  Duncan A. S. Phillips ,  Chu K. Yung ,  Gerard Ellis

IPC分类号： C09B62/04

CPC分类号： C09B62/043

摘要： A water-soluble reactive dye of the formula:D.sup.1 --Z.sup.1 --NR.sup.1 --T--NR.sup.2 --Z.sup.2 --D.sup.2 (1)whereineach of D.sup.1 and D.sup.2, independently, represents the radical of a water-soluble chromophoric compound,each of Z.sup.1 and Z.sup.2, independently, represents a triazine or pyrimidine residue carrying an atom or group imparting fibre-reactivity to the dye,R.sup.1 represents an optionally substituted alkyl radical,R.sup.2 represents hydrogen or an optionally substituted alkyl radical, andT represents a 1,3- or 1,4-phenylene radical which may carry one or more substituents selected from halogen, alkyl, alkoxy, acylamino, nitro and carboxy.

摘要翻译： 具有下式的水溶性活性染料D1-Z1-NR1-T-NR2-Z2-D2（1）其中D1和D2各自独立地表示水溶性发色化合物的基团，Z 1和 Z2独立地表示携带赋予染料纤维反应性的原子或基团的三嗪或嘧啶残基，R 1表示任选取代的烷基，R 2表示氢或任选取代的烷基，T表示1,3-或 可以携带一个或多个选自卤素，烷基，烷氧基，酰氨基，硝基和羧基的取代基的1,4-亚苯基。