ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20240224781A1

    公开(公告)日:2024-07-04

    申请号:US18403291

    申请日:2024-01-03

    CPC classification number: H10K85/342 C07F15/0033 C09K11/06 H10K50/12

    Abstract: A compound having a formula M(LA)x(LB)y(LC)z, where each of LA, LB, and LC is a different bidentate ligand is provided. In formula M(LA)x(LB)y(LC)z, x+y+z is equal to the valence of the metal M, the first ligand LA has a structure of Formula I,




    each of moiety A and moiety B is a monocyclic ring or a polycyclic fused ring system; each of X1 to X4 and Z1 and Z2 is C or N; each of K1, K2, and L1 is a direct bond of a linker; L1 is a direct bond or an organic linker; each R substituent is hydrogen or a General Substituent defined herein; and at least one RA or RB comprises a ring D that is an electron-deficient heterocyclic ring comprising one or two ring carbon atoms. Formulations, OLEDs, and consumer products containing such compounds are also provided.

    ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20240016049A1

    公开(公告)日:2024-01-11

    申请号:US18330385

    申请日:2023-06-07

    CPC classification number: H10K85/342 H10K50/12 C09K11/06 C07F15/0033

    Abstract: A compound comprising a first ligand LA of Formula I,




    and a structure of Formula II,




    is provided. Formula II is fused to ring A by two adjacent ones of X1 to X4, which are both C. In Formula I and II, X1 to X4 are C or N; K is a direct bond, O, S, N(Rα), P(Rα), B(Rα), C(Rα)(Rβ), and Si(Rα)(Rβ); moiety E is H or D; C1 is C; each of moiety B and moiety C is independently a ring or a fused ring system; each Rα, Rβ, RA, RB, and RC is hydrogen or a General Substituent; and LA is coordinated to a metal M with an atomic mass of at least 40. If moiety C is a 6-membered ring, then moiety B is a fused ring system and then all the RC substituents comprise two or more of combined carbon atoms. Formulations, OLEDs, and consumer product including the compound are also provided.

    ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20230337517A1

    公开(公告)日:2023-10-19

    申请号:US18297693

    申请日:2023-04-10

    CPC classification number: H10K85/342 C07F15/0033 C09K11/06 H10K50/11

    Abstract: A heteroleptic compound of formula Ir(LA)m(LB)n(LC)p is provided wherein LA has a structure of Formula IA,




    or Formula IB,




    LB has a structure of Formula II,




    and LC is a bidentate ligand; and wherein m is 1 or 2; n is 1 or 2; and p is 0 or 1; and m+n+p=3In Formulae I and II, moieties A and D are heterocyclic ring or a polycyclic ring system; each of X1 to X12 is C or N; Ring B is connected to moiety A by a C; at least one of X9 to X12 is N; Y is a linking group that forms a 5-membered ring; each R, R′, R″, RA, RB, RC, RD, and RE is hydrogen or a General Substituent as defined herein; LA forms a 5-membered chelate ring with Ir. Formulations, OLEDs, and consumer products containing the compound are also provided.

    ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20230320188A1

    公开(公告)日:2023-10-05

    申请号:US17960455

    申请日:2022-10-05

    CPC classification number: H01L51/0085 C07F15/0033 C09K11/06 H01L51/5016

    Abstract: A compound having a first ligand LA of Formula I,





    is provided. In Formula I, each of XB, X1 to X4 is C or N; two adjacent RA are joined together to form a structure of Formula II,





    each one of moiety B and moiety C is a monocyclic ring or polycyclic ring system; Y is selected from a group of divalent single-atom linkers; each R, R′, R″, RA, RB, and RC is hydrogen or a General Substituent; the first ligand LA is coordinated to metal M through the dashed lines; metal M may be coordinated to other ligands; and any two substituents may be joined or fused to form a ring. Formulations, OLEDs, and consumer products including the compound are also provided.

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