ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20240343970A1

    公开(公告)日:2024-10-17

    申请号:US18062668

    申请日:2022-12-07

    IPC分类号: C09K11/06 H10K50/11 H10K85/30

    摘要: Compounds of Formula I,




    are provided. In Formula I, M is Pd or Pt; each of X1 to X14 is C or N; one of Z1 and Z2 is C and the other is N; Y is selected from O, S, Se, N*R, CRR′, SiRR′, or GeRR′; K1 is a direct bond, O, or S; each R, R′, RA, RB, RC, and RD is independently hydrogen or a substituent; at least one of R, R′, RA, RB, RC, or RD is a substituent R*; and (i) R* comprises a 5-membered or 6-membered heterocyclic ring, or (ii) R* comprises Formula Ia:




    Formula Ia;



    wherein each of RY and RZ independently represents mono to the maximum allowable substitution, or no substitution;
    R1, R2, R3, R4, RY and RZ is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, germyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, selenyl, and combinations thereof;
    wherein at least one of R1, R2, R3, and R4 is not hydrogen. Formulations, OLEDs, and consumer products including the compound are also provided.

    ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20240317786A1

    公开(公告)日:2024-09-26

    申请号:US18436593

    申请日:2024-02-08

    摘要: A compound of Formula I,




    is provided. In Formula I, M is Pt or Pd; moieties B, C, and D are independently a monocyclic ring or a polycyclic fused ring system; moiety E is a monocyclic ring or a bicyclic fused ring system; n is 0, 1, or 2; K and K1 to K3 are independently a direct bond or a linker; Z is C or a heteroatom; each of Z1 to Z3 is independently C or N; X is CR, CRR′, NR, or PRR′; each of XC, XD, X1 to X3 and X8 to X12 is independently C or N; L1 is a direct bond or a linker; L2 is absent a bond, a direct bond, or a linker; each of Q1 and Q2 is a direct bond or a linker; each R substituent is independently hydrogen or a General Substituent. Formulations, OLEDs, and consumer products containing the same are also provided.