公开(公告)号：US4373054A

公开(公告)日：1983-02-08

申请号：US280314

申请日：1981-07-06

申请人： David V. Gibson ,  Garry M. McKay ,  John E. Swalwell

发明人： David V. Gibson ,  Garry M. McKay ,  John E. Swalwell

IPC分类号： C08F283/00 ,  C08F2/18 ,  C08F2/20 ,  C08F2/22 ,  C08F2/28 ,  C08F283/02 ,  C08F283/10 ,  C08F291/00 ,  C08J3/24 ,  C09D5/44 ,  C09D151/00 ,  C25D13/06 ,  C08L61/20

CPC分类号： C08F2/22 ,  C08F283/02 ,  C08F283/10 ,  C09D5/4488 ,  Y10S524/901

摘要： A process of preparing aqueous dispersions of multi-component film-forming polymer particles, suitable for use in a cathodic electrodeposition process. The disperse particles, which may be thermoplastic or thermosetting, are derived from mixtures of pre-formed polymer and addition polymer formed in situ. The process is carried out at a pH below 10 and in the presence of a selected cationic surface active agent which stabilizes the dispersion below pH 10 but renders it unstable at a pH of 10-11.

摘要翻译： 制备适用于阴极电沉积工艺的多组分成膜聚合物颗粒的水性分散体的方法。 可以是热塑性或热固性的分散颗粒来源于预先形成的聚合物和原位形成的加成聚合物的混合物。 该方法在低于10℃的pH下进行，并且在选择的阳离子表面活性剂的存在下进行，所述阳离子表面活性剂将分散体稳定在pH 10以下，但使其在10-11的pH下不稳定。

公开(公告)号：US4341676A

公开(公告)日：1982-07-27

申请号：US175163

申请日：1980-08-04

申请人： Steven E. Patricca ,  Stephen L. Buchwalter

发明人： Steven E. Patricca ,  Stephen L. Buchwalter

IPC分类号： C08G59/00 ,  C08F283/10 ,  C08G59/14 ,  C08G59/56 ,  C08G73/02 ,  C08G85/00 ,  C08L63/10 ,  C09D5/44 ,  C09D163/00 ,  C09D201/06 ,  C08L63/02

CPC分类号： C08G85/004 ,  C08G59/56 ,  C08G73/028 ,  C09D201/06 ,  C09D5/4407 ,  C09D5/4488 ,  Y10S524/901

摘要： The present invention relates to N-methylol amide-containing resinous compositions and the methods of preparing them. Aqueous dispersions of the instant resinous composition containing N-methylol amides in amounts sufficient to impart self-curing at comparatively low temperatures are disclosed. The aqueous dispersions of the instant resinous compositions are useful as coating compositions; they are particularly suited to electrodeposition.

摘要翻译： 本发明涉及含有N-羟甲基酰胺的树脂组合物及其制备方法。 本发明公开了含有N-羟甲基酰胺的本发明树脂组合物的水分散体，其量足以在较低温度下进行自固化。 本发明树脂组合物的水分散体可用作涂料组合物; 它们特别适用于电沉积。

公开(公告)号：US4314930A

公开(公告)日：1982-02-09

申请号：US167884

申请日：1980-07-22

申请人： Hugh C. Gardner

发明人： Hugh C. Gardner

IPC分类号： C08F222/10 ,  C08F283/10 ,  C08L63/10

CPC分类号： C08F222/10 ,  C08F283/10

摘要： Described herein is a molding composition comprising: ##STR1## wherein n is a number having an average value of about 1.5 to less than about 4, m is equal to the free valence of R less the average value of n, R is the hydroxyl-free residue of an organic polyol which contained from 2 to 4, inclusive, hydroxyl groups, OH, in formula (I), (b) maleic anhydride, (c) an epoxide containing two or more 1,2-epoxide radicals, (d) an ethylenically unsaturated monomer which forms a liquid homogeneous mixture with the half ester, maleic anhydride and epoxide, and (e) one or more reinforcing fibers having a melting point or a glass transition temperature above about 130.degree. C.

摘要翻译： 本文描述的是一种模塑组合物，其包含：其中n是平均值为约1.5至小于约4的数，m等于R的平均值小于R的自由价，R为 在式（I），（b）马来酸酐中含有2至4个（包括羟基）OH的有机多元醇的无羟基残基，（c）含有两个或更多个1,2-环氧基的环氧化物 ，（d）与半酯，马来酸酐和环氧化物形成液体均匀混合物的烯属不饱和单体，和（e）一种或多种熔点或玻璃化转变温度高于约130℃的增强纤维。

公开(公告)号：US4167539A

公开(公告)日：1979-09-11

申请号：US775432

申请日：1977-03-08

申请人： William J. Heilman ,  Frank C. Peterson ,  Mical C. Renz ,  Leslie P. Theard

发明人： William J. Heilman ,  Frank C. Peterson ,  Mical C. Renz ,  Leslie P. Theard

IPC分类号： C08F283/10 ,  C08G59/42 ,  C08L63/00

CPC分类号： C08F283/10 ,  C08G59/4261

摘要： A polyanhydride copolymer is made having styrene grafted onto the linear backbone chain of a styrene-maleic anhydride copolymer or a 1-alkene-maleic anhydride copolymer. This graft copolymer is also prepared in the presence of an epoxy compound such as monoepoxide or an epoxy resin for subsequent curing.

摘要翻译： 制备具有苯乙烯接枝到苯乙烯 - 马来酸酐共聚物或1-烯 - 马来酸酐共聚物的直链主链上的聚酐共聚物。 该接枝共聚物也是在环氧化合物如单环氧化物或环氧树脂存在下制备的，用于随后的固化。

公开(公告)号：US4092443A

公开(公告)日：1978-05-30

申请号：US767268

申请日：1977-02-10

申请人： George Edward Green

发明人： George Edward Green

IPC分类号： C08G59/00 ,  C08F283/10 ,  C08J3/28 ,  C08J5/10 ,  C08J5/24 ,  B05D3/06

CPC分类号： C08J5/24 ,  C08F283/10 ,  C08J2363/00

摘要： A method for the preparation of prepregs comprisesI. impregnating a fibrous reinforcing material with a liquid composition containing an epoxide resin, a photopolymerizable compound, and with a heat-activated curing agent for epoxide resins, andIi. in the absence of a substance which gives rise to a substantial degree of photoinduced polymerization through consumption of epoxide groups, exposing the impregnated material to actinic radiation such that the composition solidifies due to photopolymerization of the said photopolymerizable compound while the epoxide resin remains substantially in the thermosettable state.Preferably the liquid composition also contains a dual-functional substance which has in the same molecule both an epoxide group and a dissimilar group through which the substance can be photopolymerized. The prepreg, optionally after shaping and/or stacking, is heated to cure the epoxide resin and, if used, the photopolymerized dual-functional substance.

摘要翻译： 制备预浸料的方法包括I.用含有环氧化物树脂的液体组合物，可光热合成化合物和用于环氧树脂的热活化固化剂的纤维增强材料的制备方法。 在通过消耗环氧化物聚合物的情况下，通过消耗环氧化物聚合物的光聚合物的主要程度而导致的物质不存在，将曝光的材料暴露于等离子体辐射，这是因为当环氧化物树脂在本发明中主要依赖于固化的可光热化合物的光聚合固化时，组合物固化 热稳定状态

公开(公告)号：US4017453A

公开(公告)日：1977-04-12

申请号：US590460

申请日：1975-06-26

申请人： William J. Heilman ,  Frank C. Peterson ,  Mical C. Renz ,  Leslie P. Theard

发明人： William J. Heilman ,  Frank C. Peterson ,  Mical C. Renz ,  Leslie P. Theard

IPC分类号： C08G59/00 ,  C08F283/10 ,  C08G59/17 ,  C08G59/40 ,  C08G59/42 ,  C08K7/14 ,  C08L63/00 ,  C08L63/02

CPC分类号： C08G59/4261 ,  C08F283/10

摘要： A homogeneous mixture of a polyanhydride and a polyepoxide is prepared by the copolymerization of an olefinically unsaturated monomer capable of polymerization by free-radical means with an olefinically unsaturated monoanhydride and an olefinically saturated polyanhydride in the presence of a polyepoxide and an anhydride accelerator without substantial anhydride-epoxide cross-linking. As an example, reinforcing glass fibers are impregnated with a solution of styrene, maleic anhydride, stryene-maleic anhydride copolymer, a diglycidyl ether of bisphenol A and 1-methylimidazole and the resin is thickened in situ by copolymerization of the styrene, maleic anhydride and styrene-maleic anhydride copolymer to form a moldable, homogeneous mixture of styrene-maleic anhydride copolymer, diglycidyl ether of bisphenol A, 1-methylimidazole and reinforcing glass fibers.

摘要翻译： 聚酐和聚环氧化物的均匀混合物是通过在聚环氧化物和酸酐促进剂的存在下，通过自由基手段聚合的烯属不饱和单体与烯属不饱和单酸酐和烯属饱和聚酐共聚来制备的，而没有实质的酸酐 - 环氧交联。 作为示例，用苯乙烯，马来酸酐，苯乙烯 - 马来酸酐共聚物，双酚A的二缩水甘油醚和1-甲基咪唑的溶液浸渍增强玻璃纤维，并且树脂通过苯乙烯，马来酸酐和 苯乙烯 - 马来酸酐共聚物，以形成苯乙烯 - 马来酸酐共聚物，双酚A的二缩水甘油醚，1-甲基咪唑和增强玻璃纤维的可成型的均匀混合物。

公开(公告)号：US3912608A

公开(公告)日：1975-10-14

申请号：US48064874

申请日：1974-06-19

申请人： GRACE W R & CO

发明人： MARANS NELSON S ,  GLUECKSMANN ALFRED

IPC分类号： B01J19/12 ,  C08F283/10 ,  B01J1/10 ,  B01J1/12 ,  C08F33/08

CPC分类号： C08F283/10 ,  B01J19/123 ,  C08F220/34

摘要： A radiation curable epoxy composition prepared by admixing an epoxy compound having the formula

in which A is

and n has an average value of 0-13 and a compound having the formula

in which R1, R3, and R4 are lower alkyl groups, and R2 is an alkylene group having 2-8 carbon atoms.

摘要翻译： 通过混合具有式O ANGLE CH2-CH-CH2-An-O-CH3O | ANGLE -C-CH2-CH-CH2 | CH3的环氧化合物制备的可辐射固化环氧组合物，其中A为CH 3 OH | O-C-O-CH 2 -CH-CH 2 - | CH 3，n具有0-13的平均值，并且具有式R 3 CH 2 = C COO-R 2 -N ANGLE | R 1 R 4的化合物，其中R 1，R 3和 R4是低级烷基，R2是具有2-8个碳原子的亚烷基。

公开(公告)号：US3819567A

公开(公告)日：1974-06-25

申请号：US31139772

申请日：1972-12-01

申请人： DU PONT

发明人： SWANSON R ,  WALUS A

IPC分类号： C08F283/10 ,  C08L55/00 ,  C08L63/00 ,  C09D5/44 ,  C08G45/04

CPC分类号： C09D5/4426 ,  C08F283/10 ,  C08L55/00 ,  C08L63/00 ,  C08L2666/14 ,  C08L2666/02

摘要： The sealer composition contains a polymeric binder dissolved in an organic solvent in which the polymeric binder comprises the following components: A. an acrylic-epoxy ester graft copolymer that has a backbone of methyl methacrylate, styrene, ethyl acrylate, acrylonitrile or mixtures thereof, contains 1-7% of methacrylic acid or acrylic acid which has been reacted with an alkylene imine and the polymeric side-chain segments of the graft copolymer are epoxy esters of an epoxy resin and an aliphatic dicarboxylic acid; and B. an epoxy hydroxy polyether resin; THE NOVEL COMPOSITION FORMS A HIGH QUALITY COATING AND IS PARTICULARLY USEFUL AS A SEALER COMPOSITION FOR AUTOMOBILES AND TRUCKS.

摘要翻译： 密封剂组合物包含溶解在有机溶剂中的聚合物粘合剂，其中聚合物粘合剂包含以下组分：

公开(公告)号：US3720592A

公开(公告)日：1973-03-13

申请号：US3720592D

申请日：1971-03-12

申请人： DOW CHEMICAL CO

发明人： MANI I

IPC分类号： C08F2/46 ,  C08F20/20 ,  C08F283/10 ,  C08F299/02 ,  C08G45/04

CPC分类号： C08F299/026 ,  C08F20/20 ,  C08F283/10

摘要： THE ADDITION OF AT LEAST ABOUT 0.1 WEIGHT PERCENT OF CARBON TETRABROMIDE TO A THERMPSETTABLE MIXTURE OF CERTAIN VINYL MONOMERS AND POLYMERIZABLE VINYL ESTER RESINS REDUCES THE DOSAGE LEVEL OF IONIZING RADIATION REQUIRED TO CURE THE MIXTURE.

公开(公告)号：US3686045A

公开(公告)日：1972-08-22

申请号：US3686045D

申请日：1970-08-28

申请人： WESTINGHOUSE ELECTRIC CORP

发明人： FOSTER NEWTON C

IPC分类号： C08F283/10 ,  C08G59/42 ,  H01B3/40 ,  H01B13/06

CPC分类号： H01B3/40 ,  C08F283/10 ,  C08G59/42 ,  C08G59/4284

摘要： COMPOSITIONS OF MONTHS-LONG CATALYZED POT LIFE AT ROOM TEMPERATURE AND HENCE ESPECIALLY SUITABLE FOR COATING LARGE OBJECTS SUCH AS HIGH VOLTAGE COILS, ARE MADE BY MIXING (A) THE PRODUCT OF THE UNCATALYZED HALF-ESTERIFICATION OF EPOXY RESIN WITH AN OLEFINICALLY UNSATURATED DICARBOXYLIC ACID ANHYDRIDE (E.G., MALEIC ANHYDRIED), (B) A COREACTIVE VINYL MONOMER (E.G., STYRENE), (C) A POLYCARBOXYLIC ANHYDRIDE

CONTAINING NO OLEFINIC UNSATURATION (E.G., NADIC METHYL ANHYDRIDE (NMA) VISCOUS LIQUID METHYL BICYCLO (2.2.1) HEPTENE-2,3-DICARBOXLIC ANHYDRIDE ISOMERS) AND (D) POLYMERIZATION CATALYSTS AND INHIBITORS. THE LARGE OBJECTS ARE IMPREGNATED WITH LIQUID LOW VISCOSITY COMPOSITIONS. UPON HEATING, THE COMPOSITION CURES TO A THERMOSET RESIN.