公开(公告)号：US20110198988A1

公开(公告)日：2011-08-18

申请号：US13024570

申请日：2011-02-10

Applicant: Hideko INOUE ,  Tomoka NAKAGAWA ,  Satoshi SEO

Inventor： Hideko INOUE ,  Tomoka NAKAGAWA ,  Satoshi SEO

IPC: H01J1/62 ,  C07F15/00

CPC classification number: C09K11/06 ,  C07F15/0033 ,  C09K2211/1007 ,  C09K2211/1059 ,  C09K2211/185 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5016 ,  H01L2251/308

Abstract: A first object is to provide an organometallic complex capable of exhibiting phosphorescence. In General Formula (G1), at least one substituent of R11 to R14 represents any of a halogen group, a haloalkyl group having 1 to 4 carbon atoms, and a cyano group. At least one substituent of R15 to R19 represents any of a halogen group, a haloalkyl group having 1 to 4 carbon atoms, and a cyano group. R20 represents any of an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms, and a heteroaryl group having 4 to 10 carbon atoms. M is either a Group 9 element or a Group 10 element. When M is a Group 9 element, n is 3, and when M is a Group 10 element, n is 2.

Abstract translation: 第一个目的是提供能够显示出磷光的有机金属络合物。 在通式（G1）中，R11至R14的至少一个取代基表示卤素基团，具有1至4个碳原子的卤代烷基和氰基中的任一个。 R 15〜R 19中的至少一个取代基表示卤素基，碳原子数1〜4的卤代烷基和氰基中的任一个。 R 20表示碳原子数1〜6的烷基，碳原子数5〜8的环烷基，碳原子数6〜12的芳基，碳原子数4〜10的杂芳基中的任一种。 M为9族元素或10族元素。 当M为9族元素时，n为3，M为10族时，n为2。

公开(公告)号：US20110186825A1

公开(公告)日：2011-08-04

申请号：US13041568

申请日：2011-03-07

Applicant: Masakazu Egawa ,  Sachiko Kawakami ,  Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo ,  Ryoji Nomura

Inventor： Masakazu Egawa ,  Sachiko Kawakami ,  Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo ,  Ryoji Nomura

IPC: H01L51/54

CPC classification number: C07D241/42 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L27/3244 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5016 ,  H01L2251/5323 ,  H05B33/14 ,  Y10S428/917

Abstract: A quinoxaline derivative expressed by the general formula (1) is provided. (Each of R1 to R12 represents one of a hydrogen atom, a halogen atom, an alkyl group, an alkoxyl group, an acyl group, a dialkyl amino group, a diarylamino group, a substituted or unsubstituted vinyl group, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heterocycle group. Ar1 represents one of a substituted or unsubstituted biphenyl group and a substituted or unsubstituted terphenyl group, and Ar2 represents one of a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, and a substituted or unsubstituted monocyclic heterocycle group.)

Abstract translation: 提供由通式（1）表示的喹喔啉衍生物。 （R 1〜R 12分别表示氢原子，卤素原子，烷基，烷氧基，酰基，二烷基氨基，二芳基氨基，取代或未取代的乙烯基，取代或未取代的芳基 基团和取代或未取代的杂环基，Ar 1表示取代或未取代的联苯基和取代或未取代的三联苯基中的一个，Ar 2表示取代或未取代的苯基，取代或未取代的联苯基，取代或未取代的联苯基， 未取代的三联苯基和取代或未取代的单环杂环基）。

公开(公告)号：US20110024732A1

公开(公告)日：2011-02-03

申请号：US12899975

申请日：2010-10-07

Applicant: Nobuharu OHSAWA ,  Hiroko ABE ,  Hideko INOUE ,  Satoko SHITAGAKI ,  Satoshi SEO

Inventor： Nobuharu OHSAWA ,  Hiroko ABE ,  Hideko INOUE ,  Satoko SHITAGAKI ,  Satoshi SEO

IPC: H01L51/30

CPC classification number: C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L27/3244 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5278 ,  H05B33/14 ,  Y10S428/917

Abstract: It is an object of the present invention to obtain an organometallic complex that is capable of converting an excited triplet state into luminescence, a light-emitting element that can be driven for a long time, is high in luminous efficiency, and has a favorable long lifetime, and a light-emitting device using the light-emitting element. The present invention provides a light-emitting element that has a pair of electrodes (an anode and a cathode) and a light-emitting layer between a pair of electrodes, where the light-emitting layer includes an organometallic complex represented by the following general formula (5) and one of a compound that has a larger energy gap than the organometallic complex and a compound that has a larger ionization potential and a smaller electron affinity than the organometallic complex, and provides a light-emitting device using the light-emitting device.

Abstract translation: 本发明的目的是获得能够将激发的三线态转化为发光的有机金属络合物，长时间驱动的发光元件的发光效率高，并且具有良好的长 寿命和使用发光元件的发光器件。 本发明提供一种在一对电极之间具有一对电极（阳极和阴极）和发光层的发光元件，其中发光层包括由以下通式表示的有机金属络合物 （5）和具有比有机金属络合物更大的能隙的化合物和具有比有机金属络合物更大的电离电位和更小的电子亲和性的化合物之一，并且提供使用该发光器件的发光器件 。

公开(公告)号：US07795429B2

公开(公告)日：2010-09-14

申请号：US11791832

申请日：2005-12-01

Applicant: Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

Inventor： Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC: C07D241/42

CPC classification number: C09K11/06 ,  C07F15/0033 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

Abstract: A material which can emit phosphorescence is disclosed. Further, a light-emitting element having good chromaticity is disclosed. An embodiment of the present invention is an organometallic complex including a structure as represented by the general formula (1): wherein R1 represents an alkyl group having 1 to 4 carbon atoms; each of R2 to R5 represents any one of hydrogen, a halogen element, an acyl group, an alkyl group, an alkoxyl group, an aryl group, a cyano group, and a heterocyclic group; Ar represents an aryl group or a heterocyclic group, preferably, an aryl group having an electron withdrawing group or a heterocyclic group having an electron withdrawing group; and M represents a Group 9 element or a Group 10 element. By virtue that the Ar has an electron withdrawing group, an organometallic complex which emits phosphorescence with higher emission intensity can be obtained.

Abstract translation: 公开了可以发射磷光的材料。 此外，公开了具有良好色度的发光元件。 本发明的一个实施方案是包括由通式（1）表示的结构的有机金属络合物：其中R 1表示具有1至4个碳原子的烷基; R 2至R 5中的任一个表示氢，卤素元素，酰基，烷基，烷氧基，芳基，氰基和杂环基中的任一个; Ar表示芳基或杂环基，优选具有吸电子基的芳基或具有吸电子基的杂环基; M表示第9族元素或第10族元素。 由于Ar具有吸电子基团，可以获得发射强度较高的发出磷光的有机金属络合物。

公开(公告)号：US20100145044A1

公开(公告)日：2010-06-10

申请号：US12701077

申请日：2010-02-05

Applicant: Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

Inventor： Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC: C07F15/00

CPC classification number: C09K11/06 ,  C07F15/0033 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/185 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

Abstract: An organometallic complex having a structure represented by the general formula (G1) is synthesized and applied to a light-emitting element. In the formula, R3 represents either an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or an alkoxycarbonyl group having 1 to 5 carbon atoms; R2 and R3 each show either hydrogen or an alkyl group 1 to 4 carbon atoms; Ar represents an arylene group having 6 to 25 carbon atoms; M is a center metal selected from Group 9 element and Group 10 element.

Abstract translation: 合成具有由通式（G1）表示的结构的有机金属配合物并将其施加到发光元件上。 式中，R3表示碳原子数1〜4的烷基，碳原子数1〜4的烷氧基或碳原子数1〜5的烷氧基羰基。 R2和R3各自表示氢或1-4个碳原子的烷基; Ar表示碳原子数6〜25的亚芳基。 M是选自第9族元素和第10族元素的中心金属。

公开(公告)号：US20100059741A1

公开(公告)日：2010-03-11

申请号：US12552817

申请日：2009-09-02

Applicant: Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo

Inventor： Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo

IPC: H01L51/54 ,  H01L51/52

CPC classification number: H01L51/5012 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5036 ,  H01L2251/552

Abstract: To provide a light-emitting element with high light emission efficiency, a long lifetime, and reduced driving voltage. To provide a light-emitting element including an anode, a cathode, and a plurality of light-emitting layers which are in contact with each other so that a stacked structure is formed, between the anode and the cathode, in which the plurality of light-emitting layers are formed with a first light-emitting layer which is close to the anode and a second light-emitting layer which is close to the cathode, the first light-emitting layer and the second light-emitting layer each include a host material, a hole-transporting material, and a light-emitting material, and the concentration of the hole-transporting material in the first light-emitting layer is higher than the concentration of the hole-transporting material in the second light-emitting layer.

Abstract translation: 提供具有高发光效率，长寿命和降低的驱动电压的发光元件。 为了提供一种发光元件，其包括在阳极和阴极之间的阳极，阴极和彼此接触以形成层叠结构的多个发光层，其中多个光 形成有靠近阳极的第一发光层和接近阴极的第二发光层，第一发光层和第二发光层各自包括主体材料 空穴传输材料和发光材料，并且第一发光层中的空穴传输材料的浓度高于第二发光层中的空穴传输材料的浓度。

公开(公告)号：US20090140643A1

公开(公告)日：2009-06-04

申请号：US12323492

申请日：2008-11-26

Applicant: Nobuharu OHSAWA ,  Hideko INOUE ,  Satoshi SEO

Inventor： Nobuharu OHSAWA ,  Hideko INOUE ,  Satoshi SEO

IPC: H01J1/62

CPC classification number: H01L51/0085 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/185 ,  H01L51/5016

Abstract: A light-emitting element having high emission efficiency and long lifetime is provided. By manufacturing a light-emitting device using the light-emitting element, the light-emitting device having low power consumption and long lifetime is provided. The light-emitting element is manufactured in which a light-emitting layer is included between a first electrode serving as an anode and a second electrode serving as a cathode. The light-emitting layer includes a first organic compound having a hole-transporting property, a second organic compound having an electron-transporting property, and an organometallic complex including a dibenzo[f,h]quinoxaline skeleton as a ligand. Further, a light-emitting device is manufactured using the light-emitting element.

Abstract translation: 提供了发光效率高，寿命长的发光元件。 通过制造使用发光元件的发光装置，提供了具有低功耗和长寿命的发光装置。 制造发光元件，其中在用作阳极的第一电极和用作阴极的第二电极之间包括发光层。 发光层包括具有空穴传输性的第一有机化合物，具有电子传输性的第二有机化合物和包含二苯并[f，h]喹喔啉骨架作为配体的有机金属络合物。 此外，使用发光元件制造发光器件。

公开(公告)号：US20090033209A1

公开(公告)日：2009-02-05

申请号：US11909130

申请日：2006-03-22

Applicant: Satoshi Seo ,  Hideko Inoue ,  Nobuharu Ohsawa

Inventor： Satoshi Seo ,  Hideko Inoue ,  Nobuharu Ohsawa

IPC: H01J1/62 ,  C07F15/00

CPC classification number: H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0071 ,  H01L51/008 ,  H01L51/0087 ,  H01L51/5016 ,  H05B33/14

Abstract: In a general formula (1), each of R1 and R2 represents any one of hydrogen, an alkyl group, a halogen group, —CF3, an alkoxy group, and an aryl group. M represents an element that belongs to Group 9 or Group 10. Here, an alkyl group having 1 to 4 carbon atoms is preferable in the alkyl group. A fluoro group is particularly preferable in the halogen group. An alkoxy group having 1 to 4 carbon atoms is preferable in the alkoxy group. A phenyl group is particularly preferable in the aryl group. Iridium is particularly preferable among the elements that belong to Group 9, and platinum is particularly preferable among the elements that belong to Group 10. The general formula (1) is inserted.

Abstract translation: 在通式（1）中，R 1和R 2各自表示氢，烷基，卤素基，-CF 3，烷氧基和芳基中的任一个。 M表示属于第9族或第10族的元素。这里，烷基中优选碳原子数1〜4的烷基。 在卤素基团中，氟基是特别优选的。 在烷氧基中优选碳原子数1〜4的烷氧基。 在芳基中特别优选苯基。 铱是属于第9族的元素中特别优选的，铂是特别优选属于第10族的元素。插入通式（1）。

公开(公告)号：US20080305361A1

公开(公告)日：2008-12-11

申请号：US12132174

申请日：2008-06-03

Applicant: Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

Inventor： Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC: H05B33/00 ,  B32B9/00 ,  C07F19/00

CPC classification number: C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/185 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016

Abstract: The present invention provides a novel organometallic complex which emits green phosphorescence so as to enrich variations of phosphorescent materials for green color which is one of three primary colors. An organometallic complex comprising a structure represented by a general formula (G1) is provided. In the formula, R1 represents an alkyl group having 1 to 4 carbon atoms, and R2 and R3 individually represent hydrogen or an alkyl group having 1 to 4 carbon atoms. In addition, R4 to R7 individually represent an electron-withdrawing group, hydrogen or an alkyl group having 1 to 4 carbon atoms. Note that at least one of R4 to R7 represents an electron-withdrawing group. In addition, M is a central metal and represents either an element belonging to Group 9 in the periodic table or an element belonging to Group 10 in the periodic table.

Abstract translation: 本发明提供一种发射绿色磷光的新型有机金属配合物，以富集三原色之一的绿色磷光材料的变化。 提供了包含由通式（G1）表示的结构的有机金属络合物。 式中，R1表示碳原子数1〜4的烷基，R2和R3分别表示氢或碳原子数1〜4的烷基。 另外，R4〜R7分别表示吸电子基团，氢原子或碳原子数为1〜4的烷基。 注意，R4至R7中的至少一个表示吸电子基团。 此外，M是中心金属，并且表示属于周期表中的第9族的元素或元素周期表中属于第10族的元素。

公开(公告)号：US20080113216A1

公开(公告)日：2008-05-15

申请号：US11792424

申请日：2005-12-01

Applicant: Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

Inventor： Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

IPC: H01L51/50 ,  C07F15/00

CPC classification number: H01L51/0087 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/009 ,  H01L51/5016 ,  H05B33/14 ,  Y10S428/917

Abstract: It is an object of the present invention to provide a substance capable of emitting phosphorescence. In addition, it is an object of the present invention to provide a light-emitting element that is excellent in chromaticity. One aspect of the present invention is an organometallic complex having a structure represented by a general formula (1). In the general formula (1), R1 to R4 are each any one of hydrogen, a halogen element, an acyl group, an alkyl group, an alkoxyl group, an aryl group, a cyano group, and a heterocyclic group. In addition, R5 to R13 are each any one of hydrogen, an acyl group, an alkyl group, an alkoxyl group, an aryl group, a heterocyclic group, and an electron-withdrawing group. An organometallic complex having such a structure can emit phosphorescence with higher emission intensity.

Abstract translation: 本发明的目的是提供能够发射磷光的物质。 此外，本发明的目的是提供一种色度优异的发光元件。 本发明的一个方面是具有由通式（1）表示的结构的有机金属配合物。 在通式（1）中，R 1至R 4各自为氢，卤素元素，酰基，烷基，烷氧基， 芳基，氰基和杂环基。 此外，R 5至R 13各自为氢，酰基，烷基，烷氧基，芳基，杂环基和 吸电子基团。 具有这种结构的有机金属络合物可以发射具有更高发射强度的磷光。