Photoresponsive device containing arylmethanes
    82.
    发明授权
    Photoresponsive device containing arylmethanes 失效
    含芳基甲烷的光响应装置

    公开(公告)号:US4457994A

    公开(公告)日:1984-07-03

    申请号:US440782

    申请日:1982-11-10

    IPC分类号: G03G5/06 G03G5/10

    CPC分类号: G03G5/0614

    摘要: An improved layered photoresponsive device comprised of a substrate, a photogenerating layer, comprised of inorganic photoconductive composition, or an organic photoconductive composition, a charge carrier transport layer in contact with the photogenerating layer, which transport layer is comprised of electrically active molecules of the formula: ##STR1## dispersed in a highly insulating and transparent organic resinous material, wherein X is selected from the group consisting of (ortho) CH.sub.3, (meta) CH.sub.3, (para) CH.sub.3, (ortho) Cl, (meta) Cl, (para) Cl; and as a top coating in contact with the charge carrier transport layer, an arylmethane of the formula: ##STR2## wherein R.sub.1 and R.sub.2 are independently selected from the group consisting of alkyl groups, aryl groups, alkylaryl groups and arylalkyl groups, R.sub.3 is independently selected from the group consisting of hydrogen, and methyl, R.sub.4 is independently selected from the group consisting of alkyl groups, alkylaryl groups, arylalkyl groups, and a disubstituted aminophenyl group, wherein the substituents are independently selected from the group consisting of alkyl, aryl, alkylaryl, and arylalkyl, as well as the use of such devices in electrostatic latent imaging systems.

    摘要翻译: 一种改进的层状光响应装置,包括由无机光电导组合物或有机光电导组合物构成的基板,光生成层,与光生代层接触的载流子传输层,该传输层由式 分散在高度绝缘和透明的有机树脂材料中,其中X选自(邻)CH3,(间)CH3,(对)CH 3,(邻)Cl,(间)Cl,( para)Cl; 并且作为与电荷载流子传输层接触的顶部涂层,具有下式的芳基甲烷:其中R 1和R 2独立地选自烷基,芳基,烷基芳基和芳基烷基,R 3独立地为 选自氢和甲基,R 4独立地选自烷基,烷基芳基,芳烷基和二取代的氨基苯基,其中取代基独立地选自烷基,芳基, 烷基芳基和芳基烷基,以及在静电潜像系统中使用这种装置。

    Imaging system using novel charge transport layer
    83.
    发明授权
    Imaging system using novel charge transport layer 失效
    使用新型电荷传输层的成像系统

    公开(公告)号:US4233384A

    公开(公告)日:1980-11-11

    申请号:US34817

    申请日:1979-04-30

    摘要: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises a polycarbonate resin containing from about 25 to about 75 percent by weight of one or more of a compound having the general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are selected from the group consisting of hydrogen, an ortho, meta or para alkyl group having from 1 to about 4 carbon atoms, an ortho, meta or para halogen atom, a para phenyl group and combinations thereof.

    摘要翻译: 公开了具有至少两个电操作层的感光构件。 第一层包括光电导层,其能够对空穴进行光生并将光生空穴注入连续的电荷传输层。 电荷输送层包含含有约25至约75重量%的一种或多种具有以下通式的化合物的聚碳酸酯树脂:其中R1,R2,R3和R4选自氢, 具有1至约4个碳原子的邻位,间位或对位烷基,邻位,间位或对位卤原子,对苯基及其组合。

    Functional hybrid compounds and thin films by sol-gel process
    85.
    发明授权
    Functional hybrid compounds and thin films by sol-gel process 失效
    功能杂化化合物和薄膜通过溶胶 - 凝胶法制备

    公开(公告)号:US5116703A

    公开(公告)日:1992-05-26

    申请号:US451050

    申请日:1989-12-15

    摘要: Materials and a process for producing the materials are useful in electrophotographic imaging members. The materials are produced through a sol-gel process wherein a hybrid material, which may be obtained through hydrolysis and condensation, includes an inorganic glassy network, a flexible organic subunit and a functional subunit. The latter two subunits may be unitary. The materials can be easily coated for fabricating electrophotographic imaging members and the like.

    摘要翻译: 材料和制造该材料的方法可用于电子照相成像部件。 通过溶胶 - 凝胶法制备材料,其中可以通过水解和缩合获得的杂化材料包括无机玻璃质网络,柔性有机亚单元和功能性亚单位。 后两个亚单位可能是一体的。 这些材料可以容易地涂覆以制造电子照相成像构件等。

    Process for preparation of 2-anthryl and substituted 2-anthryl
functional monomers and polymers
    86.
    发明授权
    Process for preparation of 2-anthryl and substituted 2-anthryl functional monomers and polymers 失效
    制备2-苯乙烯和取代的2-苯乙烯官能单体和聚合物的方法

    公开(公告)号:US4117239A

    公开(公告)日:1978-09-26

    申请号:US556257

    申请日:1975-03-07

    摘要: Process for preparation of 2-anthryl and substituted 2-anthryl functional monomers and polymers. In the process for preparation of these monomers, an anthracenic reactant of the formula: ##STR1## wherein X and Y are independently selected from hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms or phenylIs acylated in nitrobenzene under conditions which favor reaction at the two position. The resulting acylated product can then be (a) reacted with an alkylidenephosphorane (Wittig synthesis) or (b) reduced to the corresponding alcohol. Subsequent to such reduction, this alcohol can undergo further modification at the hydroxyl function to form a polymerizable addition monomer. Through the proper selection of the relative concentration of reactants and control over processing conditions, it is possible not only to prepare such monomers in high yields but also upon polymerization of such monomers, to obtain high molecular weight 2-anthryl and substituted 2-anthryl functional polymers (molecular weight of at least 10.sup.4). Polymers of such high molecular weight can readily be formed without the use of binders into self-supporting films. Such films are intrinsically photoconductive in the ultraviolet region of the electromagnetic spectrum and have good transport capabilities for charge carriers of both polarities.

    Electrostatographic imaging member and process using anthracene
functional polymers
    87.
    发明授权
    Electrostatographic imaging member and process using anthracene functional polymers 失效
    静电成像和使用蒽功能聚合物的方法

    公开(公告)号:US4043812A

    公开(公告)日:1977-08-23

    申请号:US556256

    申请日:1975-03-07

    摘要: Process for preparation of 2-anthryl and substituted 2-anthryl functional monomers and polymers. In the process for preparation of these monomers, an anthracenic reactant of the formula: ##STR1## wherein X and Y are independently selected from hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms or phenylIs acylated in nitrobenzene under conditions which favor reaction at the two position. The resulting acylated product can then be (a) reacted with an alkylidenephosphorane (Wittig synthesis) or (b) reduced to the corresponding alcohol. Subsequent to such reduction, this alcohol can undergo further modification at the hydroxyl function to form a polymerizable addition monomer. Through the proper selection of the relative concentration of reactants and control over processing conditions, it is possible not only to prepare such monomers in high yields but also upon polymerization of such monomers, to obtain high molecular weight 2-anthryl and substituted 2-anthryl functional polymers (molecular weight of at least 10.sup.4). Polymers of such high molecular weight can readily be formed without the use of binders into self-supporting films. Such films are intrinsically photoconductive in the ultraviolet region of the electromagnetic spectrum and have good transport capabilities for charge carriers of both polarities.

    摘要翻译: 制备2-蒽基和取代的2-蒽基官能单体和聚合物的方法。 在制备这些单体的方法中,下式的蒽反应物:其中X和Y独立地选自氢,氯,溴,1至4个碳原子的烷基或苯基。在氮气条件下,在氮气下进行酰化。 在两个位置的反应。 所得到的酰化产物可以(a)与亚烷基次磷酰(Wittig合成)或(b)还原成相应的醇反应。 在这种还原之后,该醇可以在羟基官能团进一步改性以形成可聚合的加成单体。 通过适当选择反应物的相对浓度并控制加工条件,不仅可以以高产率制备这些单体,而且可以在这些单体聚合时获得高分子量2-蒽基和取代的2-蒽基官能团 聚合物(分子量至少为104)。 可以容易地形成这样高分子量的聚合物,而不需要使用粘合剂作为自支撑膜。 这样的膜在电磁光谱的紫外区域是本征光电导,并且对于两极性的电荷载体具有良好的传输能力。

    IMAGING MEMBER
    89.
    发明申请
    IMAGING MEMBER 有权
    成像会员

    公开(公告)号:US20090325094A1

    公开(公告)日:2009-12-31

    申请号:US12560575

    申请日:2009-09-16

    IPC分类号: G03G13/16 G03G5/06 G03G5/07

    摘要: Provided is an imaging member such as photoreceptor comprising a substrate, a charge generation layer, a first charge transport layer, a second charge transport layer, and an optional overcoat layer. The first charge transport layer is formed from a first CTL formulation comprising an aromatic monoamine and a first polymeric film forming binder material. The second charge transport layer is formed from a second CTL formulation comprising aromatic diamine and a second polymeric film forming binder material. The imaging member has gained improved properties such as removal of anti-curl layer, desirable structural flatness, electrical properties, mechanical robustness, flexibility, longevity, and copy image qualities over extended use, among others.

    摘要翻译: 提供了诸如感光体的成像构件,其包括基底,电荷产生层,第一电荷输送层,第二电荷输送层和任选的外涂层。 第一电荷输送层由包含芳族单胺和第一聚合物膜形成粘合剂材料的第一CTL制剂形成。 第二电荷输送层由包含芳族二胺和第二聚合物膜形成粘合剂材料的第二CTL制剂形成。 成像构件已经获得了改进的性能,例如去除抗卷曲层,期望的结构平整度,电性能,机械坚固性,柔韧性,寿命和复制图像质量等等。