公开(公告)号：US06251575B1

公开(公告)日：2001-06-26

申请号：US09704293

申请日：2000-11-01

申请人： William J. Begley ,  Gary M. Russo ,  Denis T. Curt

发明人： William J. Begley ,  Gary M. Russo ,  Denis T. Curt

IPC分类号： G03C108

CPC分类号： G03C7/346 ,  C07C317/44 ,  C07C2603/74 ,  C07D263/56 ,  G03C7/30523

摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a “NB coupler” having the formula (I): wherein: the term “NB coupler” represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5 nm less than that of the same dye in solution form; Y is H or a coupling-off group; each Z* is an independently selected substituent group where p is 0 to 2; V is a substituent group containing a sulfone group; R4 is represented by the formula wherein each of R5, R6 and R7 is hydrogen or an independently selected substituent with no more than one being hydrogen; provided that two or more of R5, R6 and R7 may join to form a ring or rings and provided that the combined sum of the aliphatic carbon atoms in V, R4 and all Z* is at least 8, and provided further that R4 is not a fully fluorinated alkyl group. Such elements provide improved hue.

摘要翻译： 公开了一种照相元件，其包含感光卤化银乳剂层，其具有与其相关联的具有式（I）的“NB成色剂”：其中：术语“NB成色剂”表示式（I）的成色剂，其形成用于 其中使用旋涂的左带宽（LBW）比溶液形式的相同染料小至少5nm; Y为H或偶合离去基团;每个Z *为独立选择的取代基，其中p为0 至2; V是含有砜基的取代基; R 4由R 5，R 6和R 7各自独立地选自氢或独立选择的取代基，其中不超过一个为氢; 并且R 7可以连接形成环或环，并且假设V，R 4和全部Z *中的脂族碳原子的总和为至少8，并且进一步提供R4不是完全氟化的烷基。 这些元素提供了改善的色调。

公开(公告)号：US06197491B1

公开(公告)日：2001-03-06

申请号：US09473517

申请日：1999-12-28

申请人： William J. Begley ,  Gary M. Russo ,  Denis T. Curt

发明人： William J. Begley ,  Gary M. Russo ,  Denis T. Curt

IPC分类号： G03C108

CPC分类号： G03C7/346

摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a “NB coupler” having the formula (I): wherein: the term “NB coupler” represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5 nm less than that of the same dye in solution form; Y is H or a coupling-off group; each Z* is an independently selected substituent group where p is 0 to 2; V is a substituent group containing a sulfonamido group; R4 is hydrogen or a group bonded to the carbonamido group by an aliphatic carbon atom; provided that the combined sum of the aliphatic carbon atoms in V, R4 and all Z* is at least 8. The element provides a dye of improved hue.

摘要翻译： 公开了一种照相元件，其包含感光卤化银乳剂层，其具有与其相关联的具有式（I）的“NB成色剂”：其中：术语“NB成色剂”表示式（I）的成色剂，其形成用于 其中使用旋涂的左带宽（LBW）比溶液形式的相同染料小至少5nm; Y为H或偶合离去基团;每个Z *为独立选择的取代基，其中p为0 至2; V是含有亚磺酰氨基的取代基; R4是氢或通过脂族碳原子与碳酰胺基键合的基团;条件是V，R 4和全部Z *中的脂族碳原子的总和为 至少8.元素提供改善色调的染料。

公开(公告)号：US06197489B1

公开(公告)日：2001-03-06

申请号：US09473923

申请日：1999-12-28

申请人： James L. Edwards ,  William J. Begley

发明人： James L. Edwards ,  William J. Begley

IPC分类号： G03C173

CPC分类号： G03C7/3029 ,  G03C1/035 ,  G03C1/09 ,  G03C7/3041 ,  G03C7/346 ,  G03C7/3835 ,  G03C2001/03517 ,  G03C2001/0357 ,  G03C2001/03594 ,  G03C2001/091 ,  G03C2001/093 ,  G03C2001/096

摘要： Disclosed is a color photographic element comprising at least four imaging layers including: a first light sensitive silver halide imaging layer having associated therewith a cyan image dye-forming coupler; a second light sensitive silver halide imaging layer having associated therewith a magenta image dye-forming coupler; a third light sensitive silver halide imaging layer having associated therewith a yellow image dye-forming coupler; and a fourth light sensitive silver halide imaging layer having associated therewith a fourth image dye-forming coupler for which the normalized spectral transmission density distribution curve of the dye formed by the fourth image dye-forming coupler upon reaction with color developer has a CIELAB hue angle, hab, from 225 to 310°. The element provides improved color gamut.

摘要翻译： 公开了一种包括至少四个成像层的彩色照相元件，其包括：第一感光卤化银成像层，其具有与其相关联的青色影像染料形成成色剂;第二感光卤化银成像层，其具有与其相关的品红色图像染料形成 耦合器;第三感光卤化银成像层，其具有黄色图像染料形成耦合器; 和具有第四感光卤化银成像层的第四感光卤化银成像层，其具有与第四图像染料形成成色剂在与显色剂反应时形成的染料的标准化光谱透射密度分布曲线具有CIELAB色调角的第四图像染料形成成色剂， hab，从225到310°。 该元素提供了改进的色域。

公开(公告)号：US06194132B1

公开(公告)日：2001-02-27

申请号：US09473632

申请日：1999-12-28

申请人： William J. Begley ,  Frank D. Coms ,  Gary M. Russo

发明人： William J. Begley ,  Frank D. Coms ,  Gary M. Russo

IPC分类号： G03C108

CPC分类号： C07D213/82 ,  C07D209/42 ,  C07D231/14 ,  C07D231/56 ,  C07D233/90 ,  C07D235/24 ,  C07D249/06 ,  C07D263/58 ,  C07D307/68 ,  C07D401/12 ,  C07D403/12 ,  C07D471/04 ,  G03C7/3212 ,  G03C7/346

摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a cyan coupler having the formula: wherein: V is a sulfone or sulfoxide containing group; Y is H or a coupling-off group; W2 represents the atoms necessary to complete a carbocyclic or heterocyclic ring group; each Z″, Z* and Z# is an independently selected substituent group where n and r are independently 0 to 4 and p is 0 to 2; and X is a halogen atom, and s is 1 to 5; provided that the combined sum of the aliphatic carbon atoms in V, all Z″, all Z#, and all Z* is at least 8. The element exhibits improved cyan dye stability.

摘要翻译： 公开了一种含有感光卤化银乳剂层的照相元件，其具有下式的青色成色剂：其中：V是含有砜或亚砜的基团; Y是H或偶合离去基团; W2代表必要的原子 完成碳环或杂环基;每个Z“，Z *和Z＃是独立选择的取代基，其中n和r独立地为0至4，p为0至2; 且X为卤素原子，s为1至5;条件是V，所有Z“，所有Z＃和全部Z *中的脂族碳原子的总和至少为8.该元素表现出改进的青色染料 稳定性。

公开(公告)号：US6043012A

公开(公告)日：2000-03-28

申请号：US282259

申请日：1999-03-31

申请人： Allan F. Sowinski ,  William J. Begley ,  Stephen P. Singer

发明人： Allan F. Sowinski ,  William J. Begley ,  Stephen P. Singer

IPC分类号： G03C7/20 ,  G03C7/30 ,  G03C7/392 ,  G03C1/46

CPC分类号： G03C7/3029 ,  G03C2007/3034 ,  G03C2200/19 ,  G03C2200/26 ,  G03C5/266 ,  G03C7/3041

摘要： A color negative photographic element is disclosed containing higher levels of oxidized developer agent scavenging compound in the lowest and intermediate sensitivity layers of a triple-coated image recording unit than in the fast layer. Reduced fog and granularity are obtained, and increased speed and latitude are obtained.

摘要翻译： 公开了一种彩色负型照相材料，其在三层涂布图像记录单元的最低和中等敏感层中含有比在快速层中更高含量的氧化显影剂清除化合物。 获得降低雾度和粒度，并获得提高的速度和纬度。

公开(公告)号：US5411839A

公开(公告)日：1995-05-02

申请号：US4027

申请日：1993-01-15

申请人： John W. Harder ,  Paul A. Burns ,  J. Ramon Vargas ,  Arlyce T. Bowne ,  Philip D. Knight ,  William J. Begley ,  Hans G. Ling

发明人： John W. Harder ,  Paul A. Burns ,  J. Ramon Vargas ,  Arlyce T. Bowne ,  Philip D. Knight ,  William J. Begley ,  Hans G. Ling

IPC分类号： G03C5/50 ,  G03C7/00 ,  G03C7/305 ,  G03C7/407 ,  G03C7/46

CPC分类号： G03C7/30558 ,  Y10S430/158

摘要： An improved color reversal element comprising: a support having thereon at least two light-sensitive silver halide emulsion layers and a compound capable of releasing a development inhibitor, the element comprising a compound having the structural formulaCAR--(TIME).sub.n --INHwherein:CAR is a carrier moiety from which --(TIME).sub.n --INH is released during color development;TIME is a timing group; INH is comprised of a development inhibitor moiety selected from the group consisting of oxazole, thiazole, diazole, oxathiazole, triazole, thiatriazole, benzotriazole, tetrazole, benzimidazole, indazole, isoindazole, mercaptotriazole, mercaptothiadiazole, mercaptotetrazole, selenotetrazole, mercaptothiazole, selenobenzothiazole, mercaptobenzoxazole, selenobenzoxazole, mercaptobenzimidazole, mercaptobenzothiazole, selenobenzimidazole, benzodiazole, mercaptooxadiazole, or benzisodiazole, the INH havina an inhibitor strength greater than 1 (one), andn is 0, 1 or 2.

摘要翻译： 一种改进的颜色反转元件，包括：其上具有至少两个感光卤化银乳剂层的支持体和能够释放显影抑制剂的化合物，所述元件包含具有结构式CAR-（TIME）n-INH的化合物，其中： CAR是载体部分， - （TIME）n-INH在显色期间释放; TIME是一个时间组; INH由选自恶唑，噻唑，二唑，恶噻唑，三唑，噻三唑，苯并三唑，四唑，苯并咪唑，吲唑，异吲唑，巯基三唑，巯基噻二唑，巯基四唑，硒四唑，巯基噻唑，硒苯并噻唑，巯基苯并恶唑， 硒代苯并恶唑，巯基苯并咪唑，巯基苯并噻唑，硒代苯并咪唑，苯并二唑，巯基恶二唑或苯并二唑，其INH浓度大于1（1），n为0,1或2。

公开(公告)号：US5288593A

公开(公告)日：1994-02-22

申请号：US903784

申请日：1992-06-24

申请人： William J. Begley ,  Drake M. Michno ,  Hans G. Ling ,  Teh H. Chen

发明人： William J. Begley ,  Drake M. Michno ,  Hans G. Ling ,  Teh H. Chen

IPC分类号： C07D257/04 ,  G03C7/305 ,  G03C7/32 ,  G03C7/34

CPC分类号： C07D257/04 ,  G03C7/30576 ,  Y10S430/158

摘要： A photographic element comprises a support bearing at least one photographic silver halide emulsion layer and at least one coupler (A) having a water solubilizing group wherein coupler (A) forms a compound that is washed out of the photographic element during photographic processing and forms a coupling-off group represented by the formula:--X--Rel.sup.2 --T.sup.2 --INHwherein;X is selected from oxygen, nitrogen or sulfur;X--Rel.sup.2 contains a photographic ballast and is a releasing group for releasing T.sup.2 --INH from X--Rel.sup.2 by elimination electron transfer reaction during photographic processing without substantial delay of releasing;T.sup.2 is a timing group that releases INH by elimination electron transfer reaction with timing delay during photographic processing;INH is a development inhibitor group.The photographic coupler (A) enables formation of easily removable dyes in photographic elements and processes that provide images having improved acutance, stability and interimage effects.

摘要翻译： 照相元件包括支承至少一个照相卤化银乳剂层的支持体和至少一个具有水溶性基团的成色剂（A），其中成色剂（A）形成在照相处理过程中从照相元件洗出的化合物，并形成 由-X-Rel2-T2-INH表示的偶联离去基团，其中： X选自氧，氮或硫; X-Rel2含有照相镇流器，是通过在摄影过程中消除电子转移反应而从X-Rel2中释放T2-INH而释放的释放基，而没有明显的释放延迟; T2是通过在摄影处理期间具有定时延迟的消除电子转移反应释放INH的定时组; INH是一种开发抑制剂组。 摄影耦合器（A）能够在摄影元件中形成容易去除的染料，并提供具有改善的锐度，稳定性和图像效果的图像的工艺。

公开(公告)号：US5264583A

公开(公告)日：1993-11-23

申请号：US903796

申请日：1992-06-24

申请人： William J. Begley ,  Donald Singleton, Jr.

发明人： William J. Begley ,  Donald Singleton, Jr.

IPC分类号： C07D257/04 ,  G03C7/305 ,  C07D257/02 ,  G03C7/26

CPC分类号： C07D257/04 ,  G03C7/30576

摘要： A method of forming a washout photographic coupler comprising a coupler moiety (COUP) containing a substituted or unsubstituted ballasted releasing group (A) selected from aryloxy, thioaryloxy, heterocyclicoxy, and thioheterocyclicoxy releasing groups having attached thereto a phenoxy timing group containing a photographically useful group (PUG), the releasing group capable of intramolecular displacement to release the timing group, the method comprising:(a) providing a coupler moiety (COUP) having the releasing group (A) in a coupling off position, the releasing group (A) having a 2 position containing a carbamyl chloride;(b) reacting the carbamyl chloride with a phenoxy timing group having an amine blocked with a carbamate group, the reacting being carried out in the presence of a base to form a first product;(c) removing the carbamate group using an acid to provide a coupler moiety (COUP) having a releasing group (A) and phenoxy timing group having an amine group; and(d) reacting the amine group to form a carbamyl chloride on the phenoxy timing group before reacting with a photographically useful group to form the washout coupler.

摘要翻译： 一种形成含有取代或未取代的选自芳氧基，硫代芳氧基，杂环氧基和硫代杂环氧基脱模基团的取代或未取代的稳压释放基团（A）的成色剂部分（COUP）的洗涤照相成色剂的方法，其中附着有含有照相用组 （PUG），能够进行分子内置换的释放基团以释放定时基团，所述方法包括：（a）提供具有释放基团（A）的偶联位置的成色剂部分（COUP），释放基团（A） 具有含有氨基甲酰氯的2位; （b）使氨基甲酰氯与具有被氨基甲酸酯基团封端的胺的苯氧基正时基团反应，该反应在碱的存在下进行以形成第一产物; （c）使用酸去除氨基甲酸酯基团，得到具有释放基团（A）的偶联剂部分（COUP）和具有胺基的苯氧基正时基团; 和（d）使该基团在苯氧基时基上反应形成氨基甲酰氯，然后与摄影有用的基团反应形成洗涤偶合剂。

公开(公告)号：US08088500B2

公开(公告)日：2012-01-03

申请号：US12269066

申请日：2008-11-12

申请人： William J. Begley ,  Natasha Andrievsky ,  Liang-Sheng Liao

发明人： William J. Begley ,  Natasha Andrievsky ,  Liang-Sheng Liao

IPC分类号： H01J1/63

CPC分类号： C09K11/06 ,  C09K2211/1029 ,  C09K2211/107 ,  C09K2211/185 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0058 ,  H01L51/0072 ,  H01L51/5092 ,  H01L2251/5384 ,  H05B33/14 ,  H05B33/20

摘要： The invention provides an OLED device including a cathode, an anode, and having there between a light-emitting layer, further including, between the cathode and the light emitting layer, a first layer containing a fluoranthene compound including one and only one fluoranthene nucleus and having no aromatic rings annulated to the fluoranthene nucleus, the fluoranthene nucleus having independently selected aromatic groups in the 7,10-positions and an azine group in the 8- or 9-position, provided that the azine group is not a phenanthroline group. The OLED device desirably includes a second layer containing an alkali metal or alkali metal compound, located between the cathode and the first layer. The OLED device can also include a polycyclic aromatic hydrocarbon compound in the first layer or in a third layer located between the first layer and the light-emitting layer. Devices of the invention provide improvement in features such as efficiency and drive voltage.

摘要翻译： 本发明提供了一种OLED器件，其包括阴极，阳极，并且在发光层之间具有发光层，所述发光层还包括在所述阴极和所述发光层之间，包含含有一个且仅一个荧蒽核的荧蒽化合物的第一层和 没有与荧蒽核呈环状的芳香环，在7,10位具有独立选择的芳族基团的荧蒽核和8位或9位的吖嗪基团，条件是吖嗪基不是菲咯啉基团。 OLED器件理想地包括位于阴极和第一层之间的含有碱金属或碱金属化合物的第二层。 OLED器件还可以包括位于第一层和发光层之间的第一层或第三层中的多环芳族烃化合物。 本发明的装置提供诸如效率和驱动电压之类的特征的改进。

公开(公告)号：US08076009B2

公开(公告)日：2011-12-13

申请号：US11924631

申请日：2007-10-26

申请人： William J. Begley ,  Liang-Sheng Liao ,  Natasha Andrievsky

发明人： William J. Begley ,  Liang-Sheng Liao ,  Natasha Andrievsky

IPC分类号： H01L51/54

CPC分类号： H01L51/0054 ,  C07C13/62 ,  C07C13/66 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/008 ,  H01L51/0087 ,  H01L51/5092 ,  Y10S428/917

摘要： The invention provides an OLED device comprising a cathode, an anode, and having there between a light-emitting layer, further comprising, between the cathode and the light emitting layer, a non-luminescent electron transporting layer containing a compound with a 7,10-diaryl substituted fluoranthene nucleus having no aromatic rings annulated to the fluoranthene nucleus and desirably comprises still further an additional layer containing an organic alkali metal compound, located between the cathode and the electron transporting layer. Devices of the invention provide improvement in features such as efficiency, drive voltage, and operational stability.

摘要翻译： 本发明提供了一种OLED器件，其包括阴极，阳极，并且在发光层之间具有发光层，该发光层还包括在阴极和发光层之间的非发光电子传输层，其含有具有7,10 没有芳族环的二芳基取代的荧蒽核连接到荧蒽核上，并且期望还包含位于阴极和电子传输层之间的含有有机碱金属化合物的另外的层。 本发明的装置提供诸如效率，驱动电压和操作稳定性等特征的改进。