AMINE-FUNCTIONAL AEROGELS FOR ACID GAS REMOVAL

    公开(公告)号:US20250121354A1

    公开(公告)日:2025-04-17

    申请号:US18915673

    申请日:2024-10-15

    Abstract: Compositions corresponding to amine-functionalized organosilica materials are provided, along with methods of making such materials and methods of using such materials. The amine-functionalized organosilica materials are formed in part by using a single step synthesis process based on condensation of an alkoxy-substituted cyclic organosilane precursor in the presence of an aminosilane precursor so that an amine-functionalized polymer is formed. An acyclic alkoxy silane compound can also be used during the condensation to provide a secondary monomer that facilitates formation of the gel. The amine-functionalized organosilica materials are also formed in part by using at least one of a supercritical drying process and a freeze drying process. By using a supercritical drying process and/or a freeze drying process, an amine-functionalized organosilica material can be formed that has improved properties for sorption of CO2.

    BIPOLAR PARAMETHOXYPHENYL CONTAINING REDOX MOLECULES

    公开(公告)号:US20250118779A1

    公开(公告)日:2025-04-10

    申请号:US18897833

    申请日:2024-09-26

    Abstract: Disclosed herein are a variety of systems, compositions, and methods for reversibly storing electrical energy in a redox flow battery with a unit cell potential equal to or greater than 3.5 volts. The systems include a positive section, a negative section, and an electroactive bipolar redox molecule comprising an anolyte moiety and a catholyte moiety separated by a non-conjugating insulating linker. The catholyte moiety comprises para-dimethoxybenzene and the non-conjugating insulating linker comprises at least two -CX2 linkers, wherein X comprises at least one atom selected from the group consisting of hydrogen and heteroatoms. The positive section comprises a first metal electrode in contact with the electroactive bipolar redox molecule and a supporting electrolyte dissolved in a solvent. The negative section comprises a second metal electrode in contact with the electroactive bipolar redox molecule and additional electrolyte dissolved in additional solvent.

    EMM-58 zeolite compositions, syntheses, and uses

    公开(公告)号:US12269750B2

    公开(公告)日:2025-04-08

    申请号:US18040403

    申请日:2020-08-07

    Abstract: An aluminosilicate zeolite may have a molar ratio of Si to Al of about 3 to about 10, a monoclinic space group C2/m with unit cell dimensions of a of 13.6 Å+/−5%, b of 21.7 Å+/−5%, c of 6.7 Å+/−5%, and β of 93°+/−3°, 12-ring pores along a c-axis having dimensions of 7 Å+/−5% by 6 Å+/−5%, and 8-ring pores along an a-axis having dimensions of 3 Å+/−5% by 3 Å+/−5%. Said aluminosilicate zeolites may be useful in hydrocarbon conversion processes, selective catalytic reduction of NOx, CO2 and/or N2 adsorption, carbonylation reactions, and the monoalkylamine and dialkylamine syntheses.

    POLYOLEFIN COMPOSITIONS FEATURING IN SITU BLENDING OF AN OIL EXTENSION

    公开(公告)号:US20250101156A1

    公开(公告)日:2025-03-27

    申请号:US18975725

    申请日:2024-12-10

    Inventor: Peijun Jiang

    Abstract: High molecular weight elastomers, such as ethylene-propylene-diene monomer (EPDM) polymers, are conventionally formulated with a post-polymerization oil extension to mitigate their high Mooney viscosity. Post-polymerization oil extension adds to processing costs and precludes use of polymerization facilities lacking oil extension capabilities. A low molecular weight polymer may be co-produced with a high molecular weight elastomer containing the same monomers, where the low molecular weight polymer may function in place of conventional oil extension. Polymerization methods may form a polyolefin blend comprising first and second polyolefins having a bimodal molecular weight distribution.

    Processes for Making Propylene-Based Copolymers Having Broad CDs and MWDs

    公开(公告)号:US20250101149A1

    公开(公告)日:2025-03-27

    申请号:US18717135

    申请日:2022-12-14

    Abstract: Processes for making propylene-based copolymers having broad molecular weight distributions and broad comonomer distributions using a single tubular reactor. Processes for making a propylene-based copolymer can include introducing propylene and at least one other olefin comonomer to a tubular reactor to produce a propylene-based copolymer having a broad comonomer distribution, a Mw of about 10 kg/mol to about 2.000 kg/mol, and a MWD of about 2.0 to about 10.0. The tubular reactor can include one or more heat exchanger elements, preferably a spiral heat exchanger. Propylene-based copolymer compositions can include propylene derived units and at least one other comonomer derived units, wherein the copolymer compositions have a broad comonomer distribution, a Mw of about 10 kg/mol to about 2.000 kg/mol, and a MWD of about 2.0 to about 10.0. Such compositions can have broad orthogonal comonomer distributions.

    FCC CO-PROCESSING OF BIOMASS OIL WITH HYDROGEN RICH CO-FEED

    公开(公告)号:US20250092317A1

    公开(公告)日:2025-03-20

    申请号:US18965321

    申请日:2024-12-02

    Abstract: Systems and methods are provided for increasing the yield of products generated during co-processing of biomass oil in a fluid catalytic cracking (FCC) system. The systems and methods can allow for increased yield by reducing or minimizing formation of carbon oxides, gas phase products, and/or coke yields during the co-processing. This can be achieved by adding a hydrogen-rich co-feed to the co-processing environment. Examples of hydrogen-rich co-feeds include high hydrogen content vacuum gas oil co-feed, high hydrogen content distillate co-feed, and/or high hydrogen content naphtha co-feed. Additionally or alternately, various types of fractions that contain a sufficient amount of hydrogen donor compounds can be used to reduce or minimize carbon oxide formation.

    Ethanol Conversion Using FCC System

    公开(公告)号:US20250059449A1

    公开(公告)日:2025-02-20

    申请号:US18744973

    申请日:2024-06-17

    Abstract: The present disclosure provides methods and systems for converting ethanol and cracking hydrocarbons into ethylene and at least cracked products. A method to convert ethanol and cracking hydrocarbons includes: introducing a hydrocarbon feed into a riser of a fluid catalytic cracking reactor such that hydrocarbons in the hydrocarbon feed reacts in the presence of one or more fluid catalytic cracking catalysts to produce at least cracked products; and introducing an ethanol feed into an upper one third of a stripper of the fluid catalytic cracking reactor such that the ethanol reacts in the presence of spent catalyst flowing downwardly from a separator section of the fluid catalytic cracking reactor to produce at least ethylene.

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