公开(公告)号：US20200325093A1

公开(公告)日：2020-10-15

申请号：US16087051

申请日：2017-03-21

申请人： Novomer, Inc.

发明人： Sadesh H. SOOKRAJ ,  Alexander TSEITLIN

IPC分类号： C07C51/09 ,  C07C51/50 ,  C07C51/44 ,  C07D305/12 ,  C08F20/06 ,  B01J8/02 ,  B01J4/00 ,  B01J29/08 ,  B01J29/40 ,  B01J20/26 ,  B01J20/30

摘要： Provided herein are methods of producing acrylic acid from beta-propiolactone. Such methods may involve the use of a heterogeneous catalyst, such as a zeolite.

公开(公告)号：US20240166615A1

公开(公告)日：2024-05-23

申请号：US18282915

申请日：2022-04-04

申请人： Novomer, Inc.

发明人： Branden Cole ,  Jeff Uhrig

IPC分类号： C07D305/12 ,  B01J31/16 ,  B01J31/18

CPC分类号： C07D305/12 ,  B01J31/1616 ,  B01J31/183

摘要： A continuous method of carbonylating an epoxide and/or lactone with carbon monoxide with improved catalyst efficiency and reactor productivity is comprised of reacting the epoxy and/or lactone in a solvent with carbon monoxide in the presence of a catalyst at a temperature of at least 80° C. and an amount of water that is at most about 150 ppm of the effluent from the reactor. The amount of water in any of the ingredients used in a method of the invention is desirably substantially below the aforementioned water concentration in the effluent from the reactor. Likewise, in a method of the invention, the amount of polyether byproduct is substantially absent. The methods may be performed without recycling of the catalyst.

公开(公告)号：US20230340199A1

公开(公告)日：2023-10-26

申请号：US18209884

申请日：2023-06-14

申请人： Novomer, Inc.

发明人： Han Lee ,  Sadesh H. Sookraj ,  Alexander Tseitlin

IPC分类号： C08G69/22 ,  C08G69/16

CPC分类号： C08G69/22 ,  C08G69/16

摘要： Provided are methods of producing polyamides from beta-lactones. The polyamides include bio-based polyamides that may be obtained, either in part or completely, from renewable sources.

公开(公告)号：US20230227605A1

公开(公告)日：2023-07-20

申请号：US18020722

申请日：2021-08-13

申请人： Novomer, Inc.

发明人： Geoffrey W. Coates ,  Jeffrey K. Uhrig ,  Eric Stoutenburg

IPC分类号： C08G63/08 ,  C09D167/04 ,  B32B27/08 ,  B32B27/36

CPC分类号： C08G63/08 ,  C09D167/04 ,  B32B27/08 ,  B32B27/36 ,  B32B2250/24 ,  B32B2250/02 ,  B32B2307/7163

摘要： Disclosed herein are polymers, copolymers and polymer systems based on polypropiolactones which can be biodegradable and can enhance the recyclability of polymer systems, which can be functionalized to introduce desired functionality into the polymers and/or which may optionally be prepared from renewable raw materials. Disclosed are novel functionalized beta propiolactones. Some of the novel functionalized beta propiolactones have functional groups bound to the ring structure of the lactone that provide improved polymer systems. Disclosed are novel homopolymers of the functionalized beta propiolactones. Disclosed are novel copolymers based on the functionalized beta propiolactones with beta propiolactone or other monomers which copolymerize with the functionalized beta propiolactones.

公开(公告)号：US11685809B2

公开(公告)日：2023-06-27

申请号：US16981437

申请日：2019-03-20

申请人： Novomer, Inc.

发明人： Han Lee ,  Alexander Tseitlin ,  Sadesh H. Sookraj

IPC分类号： C08G63/692 ,  C08G63/08 ,  C08K3/30 ,  C08K5/5399

CPC分类号： C08G63/08 ,  C08G63/692 ,  C08G63/6922 ,  C08K3/30 ,  C08K5/5399 ,  C08K2003/309 ,  C08K2003/3009

摘要： Provided are methods of producing sulfur- and phosphorus-containing polymers from beta-lactones. The sulfur- and phosphorus-containing polymers include bio-based sulfur- and phosphorus-containing polymers that may be obtained from renewable sources.

公开(公告)号：US11492443B2

公开(公告)日：2022-11-08

申请号：US16851517

申请日：2020-04-17

申请人： Novomer, Inc.

发明人： Jay J. Farmer ,  Peter Galebach ,  Kyle Sherry ,  Sadesh H. Sookraj

IPC分类号： C08G63/08 ,  C08G63/82 ,  B01D3/14

摘要： Provided are integrated processes for the conversion of ethylene oxide to polypropiolactone. System for the production of polypropiolactone are also provided.

公开(公告)号：US20210291153A1

公开(公告)日：2021-09-23

申请号：US17192452

申请日：2021-03-04

申请人： Novomer, Inc.

发明人： Han Lee

IPC分类号： B01J31/18 ,  B01J31/22 ,  C07D487/22 ,  C07F5/06

摘要： The present disclosure provides novel methods of making aluminum complexes with utility for promoting epoxide carbonylation reactions. Methods include reacting neutral metal carbonyl compounds with alkylaluminum complexes.

公开(公告)号：US11078172B2

公开(公告)日：2021-08-03

申请号：US16453775

申请日：2019-06-26

申请人： Novomer, Inc.

发明人： Sadesh H. Sookraj ,  Michael A. Slowik

IPC分类号： C07D307/60 ,  C07D305/12 ,  C01B3/50 ,  C10G2/00

摘要： The integrated processes herein provide improved carbon efficiency for processes based on coal or biomass gasification or steam methane reforming. Provided are also ethylene oxide carbonylation products such as beta-propiolactone and succinic anhydride having a bio-based content between 0% and 100%, and methods for producing and analyzing the same.

公开(公告)号：US20210221950A1

公开(公告)日：2021-07-22

申请号：US17054808

申请日：2019-06-13

申请人： Novomer, Inc.

发明人： John Osaheni ,  Robert E. Lapointe

IPC分类号： C08G63/91 ,  C08G63/685 ,  C08G63/78

摘要： Provided herein are methods and systems for producing a thermally stable polylactone polymer comprising chain terminating the polymer with an end-capping agent to prevent scission of the polymer. Also provided is a thermally stable polylactone polymer wherein the polymer has a first end and a second end, wherein at least one of said first and second ends terminate in an end-capping agent.

公开(公告)号：US10927091B2

公开(公告)日：2021-02-23

申请号：US16919644

申请日：2020-07-02

申请人： Novomer, Inc.

发明人： Jay J. Farmer ,  Peter Galebach ,  Kyle Sherry ,  Sadesh H. Sookraj

IPC分类号： C07D307/60 ,  C07D305/12 ,  B01J31/00 ,  C07C67/37

摘要： Provided are processes for monitoring and maintaining continuous carbonylation of epoxides or lactones. Processes include measuring parameters affecting the rate of the carbonylation reaction and adding supplemental replacement catalyst replacement components to maintain a constant rate of carbonylation.