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公开(公告)号：US06435552B1
公开(公告)日：2002-08-20
申请号：US09466776
申请日：1999-12-20
IPC分类号： B60R2128
CPC分类号： A62D1/06 , C06B25/34 , C06D5/06 , C07C281/16
摘要： A pyrotechnic gas generant composition includes a high oxygen balance compound or fuel, preferably, azodiformamidine dinitrate, which is the resulting reaction product of an aminoguanidine salt and nitric acid. Specifically, the high oxygen balance compound or fuel of the present invention is the resulting reaction product of aminoguanidine salts, such as aminoguanidine nitrate, aminoguanidine bicarbonate, or aminoguanidine sulfate with nitric acid. Preferably, the aminoguanidine salt is aminoguanidine bicarbonate. The resulting reaction product is a yellow precipitate that can be used alone, with or without oxidizers or other additives, for very rapid self-deflagration or in combination with oxidizers and additives. In each instance, the gas generant composition provides both high gas output and low production of solid combustion products. Further, the precipitant is relatively non-hygroscopic and has a high burn rate. The gas generating composition is useful as a gas generator for an air bag of an occupant restraint system for an automobile, gun propellants, inflation and expulsion devices, flotation devices, pyrotechnics, fire suppression devices and smokeless, reduced smoke and smokey rocket propellants.
摘要翻译： 烟火气体发生剂组合物包括高氧余量化合物或燃料，优选硝酸吖啶甲脒，其是所得的氨基胍盐和硝酸的反应产物。 具体地说，本发明的高氧平衡化合物或燃料是所得到的氨基胍盐如氨基胍硝酸盐，氨基胍碳酸氢盐或氨基胍硫酸盐与硝酸的反应产物。 优选地，氨基胍盐是氨基胍碳酸氢盐。 所得反应产物是黄色沉淀物，可以单独使用，具有或不具有氧化剂或其它添加剂，用于非常快速的自燃或与氧化剂和添加剂的组合。 在每种情况下，气体发生剂组合物提供高的气体输出和低固体燃烧产物的生产。 此外，沉淀剂相对不吸湿并且具有高燃烧率。 气体发生剂组合物可用作用于汽车，枪推进剂，膨胀和排出装置，浮选装置，烟火，灭火装置和无烟，减少烟雾和烟雾火箭推进剂的乘员约束系统的气囊的气体发生器。
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公开(公告)号：US06328906B1
公开(公告)日：2001-12-11
申请号：US09466777
申请日：1999-12-20
IPC分类号： C06B2900
CPC分类号： A62D1/06 , C06B25/34 , C06D5/06 , C07C281/16
摘要： A pyrotechnic gas generant composition includes a high oxygen balance compound or fuel, preferably, azodiformamidine dinitrate, which is the resulting reaction product of an aminoguanidine salt and nitric acid. Specifically, the high oxygen balance compound or fuel of the present invention is the resulting reaction product of aminoguanidine salts, such as aminoguanidine nitrate, aminoguanidine bicarbonate, or aminoguanidine sulfate with nitric acid. Preferably, the aminoguanidine salt is aminoguanidine bicarbonate. The resulting reaction product is a yellow precipitate that can be used alone, with or without oxidizers or other additives, for very rapid self-deflagration or in combination with oxidizers and additives. In each instance, the gas generant composition provides both high gas output and low production of solid combustion products. Further, the precipitant is relatively non-hygroscopic and has a high burn rate. The gas generating composition is useful as a gas generator for an air bag of an occupant restraint system for an automobile, gun propellants, inflation and expulsion devices, flotation devices, pyrotechnics, fire suppression devices and smokeless, reduced smoke and smokey rocket propellants.
摘要翻译： 烟火气体发生剂组合物包括高氧余量化合物或燃料，优选硝酸吖啶甲脒，其是所得的氨基胍盐和硝酸的反应产物。 具体地说，本发明的高氧平衡化合物或燃料是所得到的氨基胍盐如氨基胍硝酸盐，氨基胍碳酸氢盐或氨基胍硫酸盐与硝酸的反应产物。 优选地，氨基胍盐是氨基胍碳酸氢盐。 所得反应产物是黄色沉淀物，可以单独使用，具有或不具有氧化剂或其它添加剂，用于非常快速的自燃或与氧化剂和添加剂的组合。 在每种情况下，气体发生剂组合物提供高的气体输出和低固体燃烧产物的生产。 此外，沉淀剂相对不吸湿并且具有高燃烧率。 气体发生剂组合物可用作用于汽车，喷枪，膨胀和排出装置，浮选装置，烟火，灭火装置和无烟，减少烟雾和烟雾火箭推进剂的乘员约束系统的气囊的气体发生器。
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3.发明授权Gas generant compositions exhibiting low autoignition temperatures and methods of generating gases therefrom 有权显示低自燃温度的气体发生剂组合物和从其中产生气体的方法公开(公告)号：US06673172B2
公开(公告)日：2004-01-06
申请号：US09849439
申请日：2001-05-07
IPC分类号： C06B4300
CPC分类号： C06C9/00 , C06B21/005 , C06B31/12 , C06D5/06
摘要： Gas generant compositions exhibit low autoignition temperatures. In preferred forms, the gas generant compositions include azobisformamidine dinitrate (AZODN) and a eutectic mixture (comelt) of silver nitrate and potassium nitrate. The comelt of silver nitrate and potassium nitrate is most preferably present in the formulations of the invention in an amount to achieve a low autoignition temperature of between about 140° C. (284° F.) to about 160° C. (320° F.). The compositions of the invention may include a variety of auxiliary components typically employed in conventional gas generant compositions for their intended purpose. For example, especially preferred formulations of the present invention will include a powdered metal or metal oxide as a combustion catalyst to speed the decomposition reaction and also as a combustion aid to facilitate the ignition of the primary propellant or gas generant.
摘要翻译： 气体发生剂组合物显示低自燃温度。 在优选形式中，气体发生剂组合物包括硝酸银和硝酸钾的偶氮二甲脒二硝酸盐（AZODN）和共晶混合物（熔点）。 硝酸银和硝酸钾的熔点最优选存在于本发明的制剂中，其用量达到约140℃（284°F）至约160℃的低自燃温度（320°F 。）。 本发明的组合物可以包括通常用于其预期目的的常规气体发生剂组合物中的各种辅助组分。 例如，本发明的特别优选的配方将包括作为燃烧催化剂的粉末金属或金属氧化物以加速分解反应，并且还可以作为燃烧助剂以促进初级推进剂或气体发生剂的点燃。
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公开(公告)号：US6093269A
公开(公告)日：2000-07-25
申请号：US993882
申请日：1997-12-18
IPC分类号： A62D1/00 , C06B25/34 , C06B43/00 , C06B45/10 , C06B49/00 , C06D5/04 , C06D5/06 , C07C281/16 , C06B29/00
CPC分类号： C06D5/06 , C06B25/34 , C07C281/16
摘要： A pyrotechnic gas generant composition including a high oxygen balance compound or fuel which is the resulting reaction product of aminoguanidine nitrate and nitric acid. Specifically, the resulting reaction product is a yellow precipitate that can be used alone, with or without oxidizers or other additives, for very rapid self-deflagration or in combination with oxidizers and additives. In each instance, the gas generant composition provides both high gas output and low production of solid combustion products. Further, the precipitant is relatively non-hygroscopic and has a high burn rate. Specifically, the gas generating composition is useful as a gas generator for an air bag of an occupant restraint system for an automobile, gun propellants, inflation and expulsion devices, flotation devices, pyrotechnics, fire suppression devices and smokeless, reduced smoke and smokey rocket propellants.
摘要翻译： 一种包含高氧平衡化合物或燃料的烟火气体发生剂组合物，其是硝酸氨基胍与硝酸的反应产物。 具体地说，所得到的反应产物是一种黄色沉淀物，可以单独使用，具有或不具有氧化剂或其它添加剂，用于非常快速的自燃或与氧化剂和添加剂的组合。 在每种情况下，气体发生剂组合物提供高的气体输出和低固体燃烧产物的生产。 此外，沉淀剂相对不吸湿并且具有高燃烧率。 具体地说，气体发生组合物可用作用于汽车乘客约束系统，枪推进剂，充气和排出装置，浮选装置，烟火，灭火装置和无烟，减少烟雾和烟雾火箭推进剂的气囊的气体发生器 。
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