公开(公告)号：US5965680A

公开(公告)日：1999-10-12

申请号：US758610

申请日：1996-11-27

申请人： Robert D. Herold ,  Charles R. Wiedrich ,  Ajay D. Parkhe ,  Christopher D. Selvig ,  Robert A. Smith

发明人： Robert D. Herold ,  Charles R. Wiedrich ,  Ajay D. Parkhe ,  Christopher D. Selvig ,  Robert A. Smith

IPC分类号： C08F220/28 ,  C08F222/10 ,  G02B1/04 ,  C08F218/00

CPC分类号： G02B1/041 ,  C08F220/28 ,  C08F222/1006

摘要： Describes polymerizable organic compositions of from about 30 to 95 weight percent of a first monomer component which is a polyol[(meth)acryloyl terminated carbonate], e.g., diethylene glycol bis[(methacryloyloxy)ethylene carbonate)]; and from about 5 to 70 weight percent of at least one monomer component selected from: (i) an alkoxylated diol, e.g., alkoxylated bisphenol, having acrylate or methacrylate groups, e.g., dimethacrylate of bisphenol A having 25 to 35 ethoxy units, (ii) a bis[(meth)acryloyl-terminated]polyethylene glycol, and (iii) a monomer having at least three ethylenically-unsaturated terminal groups. Substantially completely cured polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.

摘要翻译： 描述了约30至95重量％的作为多元醇[（甲基）丙烯酰基封端的碳酸酯]的第一单体组分的可聚合有机组合物，例如二甘醇双[（甲基丙烯酰氧基）碳酸亚乙酯）]。 和约5至70重量％的选自以下的至少一种单体组分：（i）具有丙烯酸酯或甲基丙烯酸酯基团的烷氧基化二醇，例如烷氧基化双酚，例如具有25至35个乙氧基单元的双酚A的二甲基丙烯酸酯，（ii ）双（（甲基）丙烯酰基封端的]聚乙二醇，和（iii）具有至少三个烯键式不饱和端基的单体。 通过将这种组合物制备的基本上完全固化的聚合物可以用于通过将光致变色物质例如通过热转移引入到聚合物中来制备光致变色制品，例如镜片。