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1.发明授权Optical resin composition from polyol((meth)acryloyl carbonate) monomer 失效多元醇（（甲基）丙烯酰基碳酸酯）单体的光学树脂组合物
公开(公告)号：US5965680A
公开(公告)日：1999-10-12
申请号：US758610
申请日：1996-11-27
申请人： Robert D. Herold , Charles R. Wiedrich , Ajay D. Parkhe , Christopher D. Selvig , Robert A. Smith
发明人： Robert D. Herold , Charles R. Wiedrich , Ajay D. Parkhe , Christopher D. Selvig , Robert A. Smith
IPC分类号： C08F220/28 , C08F222/10 , G02B1/04 , C08F218/00
CPC分类号： G02B1/041 , C08F220/28 , C08F222/1006
摘要： Describes polymerizable organic compositions of from about 30 to 95 weight percent of a first monomer component which is a polyol[(meth)acryloyl terminated carbonate], e.g., diethylene glycol bis[(methacryloyloxy)ethylene carbonate)]; and from about 5 to 70 weight percent of at least one monomer component selected from: (i) an alkoxylated diol, e.g., alkoxylated bisphenol, having acrylate or methacrylate groups, e.g., dimethacrylate of bisphenol A having 25 to 35 ethoxy units, (ii) a bis[(meth)acryloyl-terminated]polyethylene glycol, and (iii) a monomer having at least three ethylenically-unsaturated terminal groups. Substantially completely cured polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.
摘要翻译： 描述了约30至95重量％的作为多元醇[（甲基）丙烯酰基封端的碳酸酯]的第一单体组分的可聚合有机组合物，例如二甘醇双[（甲基丙烯酰氧基）碳酸亚乙酯）]。 和约5至70重量％的选自以下的至少一种单体组分：（i）具有丙烯酸酯或甲基丙烯酸酯基团的烷氧基化二醇，例如烷氧基化双酚，例如具有25至35个乙氧基单元的双酚A的二甲基丙烯酸酯，（ii ）双（（甲基）丙烯酰基封端的]聚乙二醇，和（iii）具有至少三个烯键式不饱和端基的单体。 通过将这种组合物制备的基本上完全固化的聚合物可以用于通过将光致变色物质例如通过热转移引入到聚合物中来制备光致变色制品，例如镜片。
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公开(公告)号：US5708064A
公开(公告)日：1998-01-13
申请号：US322834
申请日：1994-10-13
CPC分类号： G02B1/041
摘要： Organic ophthalmic articles are photochromic and have high indices of refraction.
摘要翻译： 有机眼用物品是光致变色的并且具有高的折射率。
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公开(公告)号：US5077421A
公开(公告)日：1991-12-31
申请号：US630418
申请日：1990-12-19
摘要： Disclosed is a process for preparing aminofunctional silicone fluids substantially free of alkoxy groups by equilibrating a partially hydrolyzed aminofunctional dialkoxy or trialkoxy silane with a trialkylsiloxy terminated poly(dialkylsiloxane) followed by equilibration with a silanol terminated poly(dialkylsiloxane).
摘要翻译： 公开了一种通过使部分水解的氨基官能二烷氧基或三烷氧基硅烷与三烷基甲硅烷氧基封端的聚（二烷基硅氧烷）平衡，然后用硅烷醇封端的聚（二烷基硅氧烷）平衡来制备基本上不含烷氧基的氨基官能硅氧烷流体的方法。
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公开(公告)号：US5246630A
公开(公告)日：1993-09-21
申请号：US7218
申请日：1993-01-22
摘要： The resistance to yellowing caused by post formation heating of a solid organic polymer produced by polymerizing a polymerizable composition comprising:(a) from about 55 to about 89 percent by weight poly(allyl carbonate)-functional material selected from the group consisting of poly(allyl carbonate)-functional monomer, prepolymer of said monomer, and a mixture thereof;(b) from about 10 to about 30 percent by weight vicinally aliphatic polyurethane having two ethylenically unsaturated terminal groups of which at least about 40 mole percent are allyl terminal groups; and(c) from about 0.05 to about 0.5 percent by weight organic pyrocarbonate selected from the group consisting of dialkyl pyrocarbonate, dicycloalkyl pyrocarbonate, bis(cycloalkylalkyl) pyrocarbonate, and a mixture thereof;is enhanced by also including in the polymerizable composition from about 0.05 to about 0.5 percent by weight triphenyl phosphite.
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公开(公告)号：US5221721A
公开(公告)日：1993-06-22
申请号：US911422
申请日：1992-07-10
摘要： The resistance to yellowing caused by post formation heating of a solid organic polymer produced by polymerizing a polymerizable composition comprising:(a) from about 55 to about 89 percent by weight poly(allyl carbonate)-functional material selected from the group consisting of poly(allyl carbonate)-functional monomer, prepolymer of said monomer, and a mixture thereof;(b) from about 10 to about 30 percent by weight vicinally aliphatic polyurethane having two ethylenically unsaturated terminal groups of which at least about 40 mole percent are allyl terminal groups; and(c) from about 0.05 to about 0.5 percent by weight organic pyrocarbonate selected from the group consisting of dialkyl pyrocarbonate, dicycloalkyl pyrocarbonate, bis(cycloalkylalkyl) pyrocarbonate, and a mixture thereof;is enhanced by also including in the polymerizable composition from about 0.05 to about 0.5 percent by weight triphenyl phosphite.
摘要翻译： 由通过聚合可聚合组合物制备的固体有机聚合物的后形成加热引起的对黄化的抵抗性包括：（a）约55至约89重量％的聚（烯丙基碳酸酯）官能材料，其选自聚 烯丙基碳酸酯）官能单体，所述单体的预聚物及其混合物; （b）约10至约30重量％的具有两个烯键式不饱和端基的邻近的脂族聚氨酯，其具有至少约40摩尔％的烯丙基端基; 和（c）约0.05至约0.5％重量的选自焦碳酸二烷基酯，焦碳酸二环烷基酯，双（环烷基烷基）焦碳酸酯的有机焦碳酸酯及其混合物; 通过在聚合性组合物中还含有约0.05〜约0.5重量％的亚磷酸三苯酯来增强。
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公开(公告)号：US06106744A
公开(公告)日：2000-08-22
申请号：US984387
申请日：1997-12-03
IPC分类号： G02C7/10 , C07D493/04 , C08K5/1545 , C08L101/00 , G02B5/23 , G02S5/23 , C07D311/78
CPC分类号： C07D493/04 , C08K5/1545 , G02B5/23
摘要： Described are novel photochromic pyrano-fused naphthopyran compounds, examples of which are naphthopyran compounds having a substituted or unsubstituted "S" pyran ring, the 3,4 positions of which are fused to the f side of the naphtho portion of the naphthopyran, and certain substituents at the 2-position of the "T" pyran ring. Certain substituents may also be present at the number 5, 7, 8, 9, 10, 11 or 12 carbon atoms of the compounds. These compounds may be represented by the following graphic formula: ##STR1## Also described are polymeric organic host materials that contain or that are coated with such compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds.
摘要翻译： 描述了新的光致变色吡喃并稠合萘并吡喃化合物，其实例是具有取代或未取代的“S”吡喃环的萘并吡喃化合物，其3,4位与萘并吡喃的萘酚部分的f侧稠合， “T”吡喃环2位的取代基。 某些取代基也可以存在于化合物的5,7,8,9,10,11或12个碳原子上。 这些化合物可以由以下图解表示：还描述了含有或被这些化合物或其组合与互补光致变色化合物（例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚））化合物 。
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7.发明授权Resin composition of polyol (allyl carbonate) and allyl terminated aliphatic urethane 失效多元醇（碳酸烯丙酯）和烯丙基封端的脂肪族氨基甲酸酯的树脂组合物
公开(公告)号：US5236978A
公开(公告)日：1993-08-17
申请号：US767164
申请日：1991-09-27
IPC分类号： C08F290/06
CPC分类号： C08F290/062 , C08F290/061
摘要： Describes polymerizable organic resin compositions of from about 70 to 90 weight percent of a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), and from about 30 to 70 weight percent of aliphatic polyurethane having terminal allylic unsaturation. The polymerizable compositions have initiated pot life times of at least about 24 hours at 25.degree. C. and castings that have low yellowness (b*) values. Polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.
摘要翻译： 描述了约70至90重量％的多元醇（碳酸烯丙酯），例如二甘醇双（碳酸烯丙酯）和约30至70重量％的具有末端烯丙基不饱和基团的脂族聚氨酯的可聚合有机树脂组合物。 可聚合组合物在25℃下具有至少约24小时的适用期限和具有低黄度（b *）值的铸件。 由这样的组合物制备的聚合物可以用于通过将光致变色物质例如通过热转移引入聚合物来制备光致变色制品，例如镜片。
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公开(公告)号：US5981634A
公开(公告)日：1999-11-09
申请号：US120654
申请日：1998-07-22
摘要： A method of preparing photochromic materials useful for optical applications, and photochromic materials prepared by such method, are described. Such method comprises polymerizing a blend of a polyol[(meth)acryloyl terminated carbonate] monomer and a photochromic amount of an organic photochromic substance, thereby forming a photochromic material. A preferred polyol[(meth)acryloyl terminated carbonate] monomer is diethylene glycol bis[(methacryloyloxy)ethylene carbonate]. Polymerization may be performed by free radical initiation using thermal initiators, photoinitiators or a combination of such initiators. Photochromic materials prepared by such method may be used in optical applications, e.g., photochromic lenses.
摘要翻译： 描述了制备用于光学应用的光致变色材料的方法，以及通过这种方法制备的光致变色材料。 这种方法包括聚合多元醇[（甲基）丙烯酰基封端的碳酸酯]单体和光致变色量的有机光致变色物质的共混物，从而形成光致变色材料。 优选的多元醇[（甲基）丙烯酰基封端的碳酸酯]单体是二乙二醇双[（甲基丙烯酰氧基）碳酸亚乙酯]。 可以使用热引发剂，光引发剂或这些引发剂的组合，通过自由基引发进行聚合。 通过这种方法制备的光致变色材料可以用于光学应用中，例如光致变色透镜。
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9.发明授权
公开(公告)号：US5200483A
公开(公告)日：1993-04-06
申请号：US788978
申请日：1991-11-07
IPC分类号： C08F18/24 , C08F18/00 , C08F218/00 , C08F283/02 , C08F290/00 , C08F290/06 , C08F299/06 , C08G18/67 , C08K5/109 , C08K5/357 , C08L31/00 , C08L55/00 , G02B1/04 , G02B5/23 , G02C7/10 , G02F1/17
CPC分类号： C08F218/00 , G02B1/041
摘要： Describes organic resin compositions of from about 30 to 90 weight percent of a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), and from about 10 to 70, e.g., 10 to 30, weight percent of a mixture of aliphatic urethanes, the terminal portions of which contain allyl or acrylyl functional groups. Polymerizable compositions prepared from such compositions produce castings which have low yellowness (b*) values and which do not pre-release from the molds in which they are formed. Polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.
摘要翻译： 描述了约30至90重量％的多元醇（碳酸烯丙酯）的有机树脂组合物，例如二甘醇双（碳酸烯丙酯）和约10至70，例如10至30重量％的脂族 氨基甲酸酯，其末端部分含有烯丙基或丙烯酰基官能团。 由这种组合物制备的可聚合组合物产生具有低黄度（b *）值的铸件，并且不会从形成它们的模具预释放。 由这样的组合物制备的聚合物可以用于通过将光致变色物质例如通过热转移引入聚合物来制备光致变色制品，例如镜片。
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