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    Liquid crystal polymers
    1.
    发明授权
    Liquid crystal polymers 失效
    液晶聚合物

    公开(公告)号：US6099752A

    公开(公告)日：2000-08-08

    申请号：US66326

    申请日：1998-04-29

    申请人： Alan William Hall ,  David Lacey ,  Ian Charles Sage ,  Keith Moray Blackwood ,  Michelle Jones

    发明人： Alan William Hall ,  David Lacey ,  Ian Charles Sage ,  Keith Moray Blackwood ,  Michelle Jones

    IPC分类号： C08G61/00 ,  C09K19/38 ,  C09K19/42 ,  C09K19/30 ,  G02F1/13

    CPC分类号： C09K19/3833 ,  C08G61/00 ,  C09K19/3895

    摘要： Compounds of formula ##STR1## are provided which may be used in a variety of devices including liquid crystal devices, piezoelectric devices, pyroelectric devices and in optical recording media, wherein X.sub.1 and X.sub.2 are independently selected from H, CN, COCH.sub.3, CO.sub.2 CH.sub.3, m=at least 5; X.sub.3 and X.sub.4 are independently selected from formula (IA), ##STR2## wherein Y is selected from COO, OCO, O, S, CHOH, CHF, CH.sub.2 ; Q=(CH.sub.2).sub.n wherein one or more non-adjacent methylenes may be replaced by O and n=1-20; Z is selected from O, S, single covalent bond, COO, OCO; when Y is CH2 then n may also be O; formula (A) ##STR3## represents any mesogenic group; X3 and X.sub.4 are also independently selected from H, OH, OCOR.sup.1, COOH, CO.sub.2 R.sup.1 (CH.sub.2).sub.p OH, (CH.sub.2).sub.p CO.sub.2 H, --(CH.sub.2).sub.p OR.sup.1 or --(CH.sub.2).sub.p CO.sub.2 R.sup.1 and p=1-20, R.sup.1 =H or C.sub.1=16 alkyl, when R.sup.1 =C.sub.2-16 alkyl the terminal Ch.sub.3 group may be replaced by Br or Cl; provided that at least one of X3 and X4 is selected from formula (IA).

    摘要翻译： PCT No.PCT / GB96 / 02650 Sec。 371日期：1998年4月29日 102（e）1998年4月29日PCT PCT 1996年10月31日PCT公布。 出版物WO97 / 16441 日期：1997年5月9日提供了可用于液晶装置，压电装置，热电装置和光学记录介质的各种装置的化合物，其中X1和X2独立地选自H，CN，COCH 3，CO 2 CH 3， m =至少5; X 3和X 4独立地选自式（IA），其中Y选自COO，OCO，O，S，CHOH，CHF，CH 2; Q =（CH 2）n，其中一个或多个不相邻亚甲基可被O代替，n = 1-20; Z选自O，S，单共价键，COO，OCO; 当Y是CH2时，n也可以是O; 式（A）表示任何介晶组; X3和X4也独立地选自H，OH，OCOR1，COOH，CO2R（CH2）pOH，（CH2）pCO2H， - （CH2）pOR1或 - （CH2）pCO2R1和p = 1-20，R1 = H或C1 = 16个烷基，当R1 = C2-16烷基时，末端Ch3基团可被Br或Cl取代; 条件是X3和X4中的至少一个选自式（IA）。

    Polymers
    3.
    发明授权
    Polymers 有权
    聚合物

    公开(公告)号：US07112639B2

    公开(公告)日：2006-09-26

    申请号：US10240316

    申请日：2001-03-30

    申请人： Alan William Hall

    发明人： Alan William Hall

    IPC分类号： C08F120/42

    CPC分类号： C08F220/04 ,  B33Y70/00 ,  C08F222/02 ,  C08F222/1006 ,  C08F226/02

    摘要： A copolymer containing repeat units formed from the monomers (I) and (II), wherein each R1, if present, is independently hydrogen or hydrocarbyl; r is 0, 1 or 2; s is either 2 or 3; R2–R4 are each independently hydrogen or hydrocarbyl; R5 and R6 are each independently hydrogen, halo or hydrocarbyl; Pd− is the anion formed by loss of a proton from a proton donating group Pd—H; Z is either a bond or hydrocarbyl; R7 and R8 are each independently hydrogen, halo or hydrocarbyl; and either (a) A is an electron accepting group and W is either hydrogen or hydrocarbyl, (b) W is an electron accepting group and A is either a bond or hydrocarbyl or (c) both A and W are electron accepting groups. The invention also provides a method for preparing the copolymer by polymerising a mixture of (I) and (II) or their non-ionised precursors, preferably by exposure to ultraviolet radiation. The invention also relates to the uses of the copolymer in adhesive, coating, sealant and stereolithographic compositions

    摘要翻译： 含有由单体（I）和（II）形成的重复单元的共聚物，其中每个R 1如果存在，独立地是氢或烃基; r为0,1或2; s是2或3; R 2 -R 4各自独立地为氢或烃基; R 5和R 6各自独立地为氢，卤素或烃基; 由质子供体基团P by by by by anion anion;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; Z是键或烃基; R 7和R 8各自独立地为氢，卤素或烃基; 和（a）A是电子接受基团，W是氢或烃基，（b）W是电子接受基团，A是键或烃基，或（c）A和W都是电子接受基团。 本发明还提供了通过优选通过暴露于紫外线辐射聚合（I）和（II）或其非电离前体的混合物来制备共聚物的方法。 本发明还涉及共聚物在粘合剂，涂料，密封剂和立体光刻组合物中的用途