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1.发明授权Process for the production of alkylbenzene hydroperoxides under mild conditions and in the presence of new catalytic systems 失效在温和条件下和存在新的催化体系下生产烷基苯氢过氧化物的方法公开(公告)号：US08445729B2
公开(公告)日：2013-05-21
申请号：US12933204
申请日：2009-03-13
申请人： Francesco Minisci , Carlo Punta , Francesco Recupero , Cristian Gambarotti , Raffaele Spaccini , Angelo Clerici , Alberto Clerici
发明人： Francesco Minisci , Ombretta Porta , Carlo Punta , Francesco Recupero , Cristian Gambarotti , Raffaele Spaccini
IPC分类号： C07C409/00
CPC分类号： C07C409/08 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , C07C2601/18 , C07C2601/20
摘要： Process for the preparation of hydroperoxides of alkylbenzenes characterized by the fact that the alkylbenzene reacts with oxygen in the presence of a catalytic system which includes an N-hydroxyimide or an N-hydroxysulfamide and a polar solvent.
摘要翻译： 制备烷基苯氢过氧化物的方法，其特征在于烷基苯在包括N-羟基酰亚胺或N-羟基磺酰胺和极性溶剂的催化体系存在下与氧反应。
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2.发明申请CATALYTIC PROCESS FOR THE PREPARATION OF HYDROPEROXIDES OF ALKYLBENZENES BY AEROBIC OXIDATION UNDER MILD CONDITIONS 失效用于通过粉碎条件下的氧化氧化制备烷基苯酚的氢过氧化物的催化方法公开(公告)号：US20110082320A1
公开(公告)日：2011-04-07
申请号：US12933190
申请日：2009-03-13
申请人： Francesco Minisci , Ombretta Porta , Carlo Punta , Francesco Recupero , Cristian Gambarotti , Raffaele Spaccini , Angelo Clerici , Alberto Clerici
发明人： Francesco Minisci , Ombretta Porta , Carlo Punta , Francesco Recupero , Cristian Gambarotti , Raffaele Spaccini , Angelo Clerici , Alberto Clerici
IPC分类号： C07C409/02
CPC分类号： C07C409/08 , C07C407/00 , C07C409/14 , C07C2601/14
摘要： Process for the preparation of hydroperoxides of alkylbenzenes characterized by the fact that the alkylbenzene reacts with oxygen in the presence of a catalytic system consisting of an N-hydroxyimide associated with a peroxide activator having a peracid or dioxyrane structure, possibly generated in situ.
摘要翻译： 用于制备烷基苯的氢过氧化物的方法，其特征在于烷基苯在与可能在原位产生的具有过酸或双氧结构的过氧化物活化剂相关联的N-羟基酰亚胺的催化体系存在下与氧反应。
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3.发明授权Catalytic process for the preparation of hydroperoxides of alkylbenzenes by aerobic oxidation under mild conditions 失效在温和条件下通过需氧氧化制备烷基苯氢过氧化物的催化方法公开(公告)号：US08420867B2
公开(公告)日：2013-04-16
申请号：US12933190
申请日：2009-03-13
申请人： Francesco Minisci , Carlo Punta , Francesco Recupero , Cristian Gambarotti , Raffaele Spaccini , Angelo Clerici , Alberto Clerici
发明人： Francesco Minisci , Ombretta Porta , Carlo Punta , Francesco Recupero , Cristian Gambarotti , Raffaele Spaccini
IPC分类号： C07C409/02
CPC分类号： C07C409/08 , C07C407/00 , C07C409/14 , C07C2601/14
摘要： Process for the preparation of hydroperoxides of alkylbenzenes characterized by the fact that the alkylbenzene reacts with oxygen in the presence of a catalytic system consisting of an N-hydroxyimide associated with a peroxide activator having a peracid or dioxyrane structure, possibly generated in situ.
摘要翻译： 用于制备烷基苯的氢过氧化物的方法，其特征在于烷基苯在与可能在原位产生的具有过酸或双氧结构的过氧化物活化剂相关联的N-羟基酰亚胺的催化体系存在下与氧反应。
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4.发明申请公开(公告)号：US20110251436A1
公开(公告)日：2011-10-13
申请号：US12933204
申请日：2009-03-13
申请人： Francesco Minisci , Carlo Punta , Francesco Recupero , Christian Gambarotti , Raffaele Spaccini , Ombretta Porta , Angelo Clerici , Alberto Clerici
发明人： Francesco Minisci , Carlo Punta , Francesco Recupero , Christian Gambarotti , Raffaele Spaccini , Ombretta Porta , Angelo Clerici , Alberto Clerici
IPC分类号： C07C407/00
CPC分类号： C07C409/08 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , C07C2601/18 , C07C2601/20
摘要： Process for the preparation of hydroperoxides of alkylbenzenes characterized by the fact that the alkylbenzene reacts with oxygen in the presence of a catalytic system which includes an N-hydroxyimide or an N-hydroxysulfamide and a polar solvent.
摘要翻译： 制备烷基苯氢过氧化物的方法，其特征在于烷基苯在包括N-羟基酰亚胺或N-羟基磺酰胺和极性溶剂的催化体系存在下与氧反应。
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5.发明申请公开(公告)号：US20110098509A1
公开(公告)日：2011-04-28
申请号：US12443271
申请日：2007-09-20
申请人： Francesco Minisci , Ombretta Porta , Angelo Clerici , Alberto Clerici , Francesco Recupero , Carlo Punta , Cristian Gambarotti , Monica Pierini
发明人： Francesco Minisci , Ombretta Porta , Angelo Clerici , Alberto Clerici , Francesco Recupero , Carlo Punta , Cristian Gambarotti , Monica Pierini
IPC分类号： C07C407/00 , C07C37/08
CPC分类号： C07C409/10 , C07C37/08 , C07C407/00 , Y02P20/52 , C07C39/04
摘要： The invention relates to a process for the preparation of phenol which comprises the aerobic oxidation of cumene to hydroperoxide with high conversions and selectivities, in the presence of new catalytic systems, extremely mild conditions and the subsequent acid decomposition of the hydroperoxide to phenol and acetone.
摘要翻译： 本发明涉及一种苯酚的制备方法，该方法包括在新的催化体系存在下，非常温和的条件和随后的氢过氧化物酸分解成苯酚和丙酮，将枯烯好氧氧化为氢过氧化物，具有高转化率和选择性。
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