公开(公告)号：US4036875A

公开(公告)日：1977-07-19

申请号：US583319

申请日：1975-06-02

申请人： Anders Brostrom

发明人： Anders Brostrom

IPC分类号： B01J19/18 ,  C07B45/02 ,  C07C303/00 ,  C07C309/08 ,  C07C309/28 ,  C07C143/24

CPC分类号： C07C303/00 ,  B01J19/18 ,  C07B45/02 ,  C07C303/06 ,  C07C303/24 ,  B01J2219/00085 ,  B01J2219/00189 ,  B01J2219/185

摘要： An improved process is provided for the continuous sulphonation and/or sulphation of organic substances with sulphur trioxide gas mixed with an inert gaseous diluent, at an increased production rate without impairment of product quality, while minimizing discoloration of the product, and the amounts of unsulphonated product in the product, and of unreacted sulphur trioxide in the residual gaseous mixture, by limiting the amount of sulphur trioxide introduced ab initio into the organic liquid to be sulphonated and/or sulphated to not exceeding 7%, and preferably within the range from about 0.25 to about 5%, of the stoichiometric amount required for the desired sulphonated or sulphated product, introducing the remaining sulphur trioxide over from about 20 to about 80%, preferably from about 25 to about 50%, of the remainder of the length of the reaction zone.

摘要翻译： 提供了一种改进的方法，用于连续磺化和/或硫酸化有机物质与三氧化硫气体混合惰性气体稀释剂，以增加的生产率，而不损害产品质量，同时最小化产品的变色，以及未磺​​化的量 产物和残余气体混合物中未反应的三氧化硫，通过将从头进入磺化和/或硫酸化的有机液体中的三氧化硫的量限制在不超过7％，优选在约 将所需磺化或硫酸化产物所需的化学计量量为0.25至约5％，将剩余的三氧化硫引入剩余长度的约20至约80％，优选约25至约50％ 反应区。