公开(公告)号：US20130216936A1

公开(公告)日：2013-08-22

申请号：US13882535

申请日：2011-11-02

申请人： Annette Fuchs ,  Klaus-Dieter Kreuer ,  Joachim Maier ,  Andreas Wohlfarth

发明人： Annette Fuchs ,  Klaus-Dieter Kreuer ,  Joachim Maier ,  Andreas Wohlfarth

IPC分类号： H01G9/035 ,  H01M8/10 ,  H01M10/0565

CPC分类号： H01G9/035 ,  H01B1/122 ,  H01M8/1018 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0082

摘要： A method of producing an alkaline single ion conductor with high conductivity includes: a) providing a hydrocarbon oligomer or polymer having immobilized acidic substituent groups selected from the group consisting of a sulfonic acid group, sulfamide group, a phosphonic acid group, or a carboxy group, in its alkaline ion form wherein at least a part of the acidic protons of the substituent groups have been exchanged against alkali cations, and b) solvating the hydro-carbon oligomer or polymer of step a) in an aprotic polar solvent for a sufficient time to effect a solvent uptake of at least 5% by weight and to obtain a solvated product, wherein the molar ratio of solvent/alkaline cation is 1:1 to 10,000:1, and which solvated product has a conductivity of at least 10−5 S/cm at room temperature (24° C.).

摘要翻译： 制备具有高导电性的碱性单离子导体的方法包括：a）提供具有选自磺酸基，磺酰胺基，膦酸基或羧基的固定的酸性取代基的烃低聚物或聚合物 以其碱性离子形式，其中取代基的至少一部分酸性质子已经被碱金属阳离子交换，和b）将非氢化极性溶剂中的步骤a）的氢碳低聚物或聚合物溶剂足够的时间 以使溶剂吸收至少为5重量％，并获得溶剂化产物，其中溶剂/碱性阳离子的摩尔比为1:1至10,000:1，并且该溶剂化产物的导电率至少为10-5 在室温（24℃）下S / cm。

公开(公告)号：US09299501B2

公开(公告)日：2016-03-29

申请号：US13882535

申请日：2011-11-02

申请人： Annette Fuchs ,  Klaus-Dieter Kreuer ,  Joachim Maier ,  Andreas Wohlfarth

发明人： Annette Fuchs ,  Klaus-Dieter Kreuer ,  Joachim Maier ,  Andreas Wohlfarth

IPC分类号： H01M8/10 ,  H01G9/035 ,  H01B1/12 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/0569

CPC分类号： H01G9/035 ,  H01B1/122 ,  H01M8/1018 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0082

摘要： A method of producing an alkaline single ion conductor with high conductivity includes: a) providing a hydrocarbon oligomer or polymer having immobilized acidic substituent groups selected from the group consisting of a sulfonic acid group, sulfamide group, a phosphonic acid group, or a carboxy group, in its alkaline ion form wherein at least a part of the acidic protons of the substituent groups have been exchanged against alkali cations, and b) solvating the hydrocarbon oligomer or polymer of step a) in an aprotic polar solvent for a sufficient time to effect a solvent uptake of at least 5% by weight and to obtain a solvated product, wherein the molar ratio of solvent/alkaline cation is 1:1 to 10,000:1, and which solvated product has a conductivity of at least 10−5 S/cm at room temperature (24° C.).

摘要翻译： 制备具有高导电性的碱性单离子导体的方法包括：a）提供具有选自磺酸基，磺酰胺基，膦酸基或羧基的固定的酸性取代基的烃低聚物或聚合物 以其碱性离子形式，其中取代基的至少一部分酸性质子已经被碱金属阳离子交换，和b）将非极性极性溶剂中的步骤a）的烃低聚物或聚合物溶剂足够的时间来实现 溶剂吸收量为至少5重量％，并获得溶剂化产物，其中溶剂/碱性阳离子的摩尔比为1:1至10,000:1，并且该溶剂化产物具有至少10 -5 S / 室温（24℃）。