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1.发明申请ALKALINE SINGLE ION CONDUCTORS WITH HIGH CONDUCTIVITY AND TRANSFERENCE NUMBER AND METHODS FOR PREPARING THE SAME 有权具有高电导率和转移数的碱性单离子导体及其制备方法公开(公告)号：US20130216936A1
公开(公告)日：2013-08-22
申请号：US13882535
申请日：2011-11-02
IPC分类号： H01G9/035 , H01M8/10 , H01M10/0565
CPC分类号： H01G9/035 , H01B1/122 , H01M8/1018 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2300/0082
摘要： A method of producing an alkaline single ion conductor with high conductivity includes: a) providing a hydrocarbon oligomer or polymer having immobilized acidic substituent groups selected from the group consisting of a sulfonic acid group, sulfamide group, a phosphonic acid group, or a carboxy group, in its alkaline ion form wherein at least a part of the acidic protons of the substituent groups have been exchanged against alkali cations, and b) solvating the hydro-carbon oligomer or polymer of step a) in an aprotic polar solvent for a sufficient time to effect a solvent uptake of at least 5% by weight and to obtain a solvated product, wherein the molar ratio of solvent/alkaline cation is 1:1 to 10,000:1, and which solvated product has a conductivity of at least 10−5 S/cm at room temperature (24° C.).
摘要翻译： 制备具有高导电性的碱性单离子导体的方法包括：a）提供具有选自磺酸基，磺酰胺基，膦酸基或羧基的固定的酸性取代基的烃低聚物或聚合物 以其碱性离子形式，其中取代基的至少一部分酸性质子已经被碱金属阳离子交换，和b）将非氢化极性溶剂中的步骤a）的氢碳低聚物或聚合物溶剂足够的时间 以使溶剂吸收至少为5重量％，并获得溶剂化产物，其中溶剂/碱性阳离子的摩尔比为1:1至10,000:1，并且该溶剂化产物的导电率至少为10-5 在室温（24℃）下S / cm。
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2.发明授权Alkaline single ion conductors with high conductivity and transference number and methods for preparing the same 有权具有高导电性和转移次数的碱性单离子导体及其制备方法公开(公告)号：US09299501B2
公开(公告)日：2016-03-29
申请号：US13882535
申请日：2011-11-02
IPC分类号： H01M8/10 , H01G9/035 , H01B1/12 , H01M10/0565 , H01M10/0568 , H01M10/0569
CPC分类号： H01G9/035 , H01B1/122 , H01M8/1018 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2300/0082
摘要： A method of producing an alkaline single ion conductor with high conductivity includes: a) providing a hydrocarbon oligomer or polymer having immobilized acidic substituent groups selected from the group consisting of a sulfonic acid group, sulfamide group, a phosphonic acid group, or a carboxy group, in its alkaline ion form wherein at least a part of the acidic protons of the substituent groups have been exchanged against alkali cations, and b) solvating the hydrocarbon oligomer or polymer of step a) in an aprotic polar solvent for a sufficient time to effect a solvent uptake of at least 5% by weight and to obtain a solvated product, wherein the molar ratio of solvent/alkaline cation is 1:1 to 10,000:1, and which solvated product has a conductivity of at least 10−5 S/cm at room temperature (24° C.).
摘要翻译： 制备具有高导电性的碱性单离子导体的方法包括：a）提供具有选自磺酸基，磺酰胺基，膦酸基或羧基的固定的酸性取代基的烃低聚物或聚合物 以其碱性离子形式，其中取代基的至少一部分酸性质子已经被碱金属阳离子交换，和b）将非极性极性溶剂中的步骤a）的烃低聚物或聚合物溶剂足够的时间来实现 溶剂吸收量为至少5重量％，并获得溶剂化产物，其中溶剂/碱性阳离子的摩尔比为1:1至10,000:1，并且该溶剂化产物具有至少10 -5 S / 室温（24℃）。
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3.发明授权Proton conductors which are thermally stable over a wide range and have good proton conductivities 失效在宽范围内热稳定且具有良好质子电导率的质子导体公开(公告)号：US06264857B1
公开(公告)日：2001-07-24
申请号：US09242036
申请日：1999-07-02
申请人： Klaus-Dieter Kreuer , Annette Fuchs , Joachim Maier , Georg Frank , Thomas Soczka-Guth , Joachim Clauss
发明人： Klaus-Dieter Kreuer , Annette Fuchs , Joachim Maier , Georg Frank , Thomas Soczka-Guth , Joachim Clauss
IPC分类号： H01B100
CPC分类号： C25B13/04 , H01M2/1653 , H01M8/0289 , H01M8/08 , H01M10/02
摘要： Proton conductors comprising from 1 to 99% by weight of an acid and from 99 to 1% by weight of a nonaqueous amphoteric material which are thermally stable from −50° C. to 400° C. and have a proton conductivity of ≧10−5 S/cm. The invention further relates to membranes comprising the proton conductors of the invention, processes for preparing the membranes and their use in electrochromic cells, secondary batteries and electrochromic displays.
摘要翻译： 包含1至99重量％的酸和99至1重量％的非水性两性材料的质子导体，其在-50℃至400℃下热稳定且质子传导率≥10 -5 S / cm。 本发明还涉及包含本发明的质子导体的膜，制备膜的方法及其在电致变色电池，二次电池和电致变色显示器中的应用。
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