公开(公告)号：US08071812B1

公开(公告)日：2011-12-06

申请号：US12335997

申请日：2008-12-16

申请人： Joachim C. Ritter ,  Annalisa Hargis

发明人： Joachim C. Ritter ,  Annalisa Hargis

IPC分类号： C07C209/00

CPC分类号： C07C209/10 ,  C07C211/52

摘要： A process is provided for the preparation of 1,3-diamino-4,6-dinitrobenzene by amination of 1,3-dihalo-4,6-dinitrobenzene. The presence of water advantageously results in a highly pure product, free or essentially free of glycol ether impurities.

摘要翻译： 提供了通过1,3-二卤代-4,6-二硝基苯胺化制备1,3-二氨基-4,6-二硝基苯的方法。 水的存在有利地产生游离或基本上不含二醇醚杂质的高纯度产物。

公开(公告)号：US08580910B2

公开(公告)日：2013-11-12

申请号：US13517261

申请日：2010-12-21

申请人： Rajiv Dhawan ,  Annalisa Hargis ,  Joachim C Ritter

发明人： Rajiv Dhawan ,  Annalisa Hargis ,  Joachim C Ritter

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C07C213/02 ,  C07C213/00 ,  C07C213/10 ,  C07C215/80

摘要： New triaminophenol compositions and related compounds are disclosed, as are processes for their preparation and for the preparation of novel salts and diacid complexes from such compounds. Polymers prepared from these compositions can be made into high strength fiber, film, and tape and are useful in applications such as protective apparel, aircraft, automotive components, personal electronics, and sports equipment.

摘要翻译： 公开了新的三氨基苯酚组合物和相关化合物，以及它们的制备方法以及从这些化合物制备新的盐和二酸配合物。 由这些组合物制备的聚合物可以制成高强度纤维，薄膜和胶带，并且可用于诸如保护性服装，飞机，汽车部件，个人电子设备和运动器材的应用中。

公开(公告)号：US20130012741A1

公开(公告)日：2013-01-10

申请号：US13517261

申请日：2010-12-21

申请人： Rajjiv Dhawan ,  Annalisa Hargis ,  Joachim C. Ritter

发明人： Rajjiv Dhawan ,  Annalisa Hargis ,  Joachim C. Ritter

IPC分类号： C07C213/02

CPC分类号： C07C213/02 ,  C07C213/00 ,  C07C213/10 ,  C07C215/80

摘要： New triaminophenol compositions and related compounds are disclosed, as are processes for their preparation and for the preparation of novel salts and diacid complexes from such compounds. Polymers prepared from these compositions can be made into high strength fiber, film, and tape and are useful in applications such as protective apparel, aircraft, automotive components, personal electronics, and sports equipment.

公开(公告)号：US20130158296A1

公开(公告)日：2013-06-20

申请号：US13517052

申请日：2010-12-21

申请人： Annalisa Hargis ,  Joachim C. Ritter

发明人： Annalisa Hargis ,  Joachim C. Ritter

IPC分类号： C07C209/10

CPC分类号： C07C209/10 ,  C07C211/52

摘要： A process is provided for the preparation of 1-amino-3-halo-4,6-dinitrobenzene and related compounds by monoamination of dihalodinitrobenzenes by ammonia in the presence of solvent and water. Using glycol as a solvent for the dihalodinitrobenzene and feeding ammonia at a rate at which it is consumed allows for the synthesis of high purity product, such as 1-amino-3-chloro-4,6-dinitrobenzene, at high yields.

摘要翻译： 提供了一种通过在溶剂和水存在下用氨将二卤代硝基苯单胺化制备1-氨基-3-卤代-4,6-二硝基苯及相关化合物的方法。 使用乙二醇作为二卤代硝基苯的溶剂并以其消耗的速率供给氨，可高产率地合成高纯度产物如1-氨基-3-氯-4,6-二硝基苯。

公开(公告)号：US20130172621A1

公开(公告)日：2013-07-04

申请号：US13517272

申请日：2010-12-21

申请人： Rajiv Dhawan ,  Annalisa Hargis ,  Joachim C. Ritter

发明人： Rajiv Dhawan ,  Annalisa Hargis ,  Joachim C. Ritter

IPC分类号： C07C213/02

CPC分类号： C07C213/02 ,  C07C215/80 ,  Y02P20/125

摘要： An integrated process is provided for efficiently preparing 2,4,5-triaminophenol, starting with nitration of 2,6-dihalobenzene; high purity salts thereof; and complexes of 2,4,5-triaminophenol aromatic diacids, which are precursors for making polybenzimidazole polymer for high performance fibers. The process design eliminates several costly intermediate drying and recrystallization steps. The handling of solid materials with possible skin sensitizing properties and toxicity is avoided, thereby eliminating human and environmental exposure.

摘要翻译： 提供了一种综合方法，用于有效地制备2,4,5-三氨基苯酚，从2,6-二卤代苯的硝化开始; 其高纯度盐; 以及2,4,5-三氨基苯酚芳族二酸的络合物，其是用于制备用于高性能纤维的聚苯并咪唑聚合物的前体。 该工艺设计消除了几个昂贵的中间干燥和重结晶步骤。 避免了具有可能的皮肤敏感性和毒性的固体材料的处理，从而消除了人体和环境的暴露。