公开(公告)号：US5220009A

公开(公告)日：1993-06-15

申请号：US691313

申请日：1991-04-25

申请人： Yehuda Mazur ,  Aureliu Acher ,  Lea Shragina ,  Moshe Avramoff

发明人： Yehuda Mazur ,  Aureliu Acher ,  Lea Shragina ,  Moshe Avramoff

IPC分类号： A61L2/18 ,  C07D279/18 ,  C07H15/26

CPC分类号： C07H15/26 ,  C07D279/18

摘要： Novel 3,7-disubstituted phenothiazinium salts are active in the photochemical disinfection of aqueous effluents. The novel salts are of the general formula ##STR1## wherein: either R.sub.1 is a saccharide residue;R.sub.2 is alkyl, cycloalkyl, aryl, aralkyl or heterocyclyl, any alkyl or alkylene chain being optionally interrupted by one or more heteroatoms, and Y is alkylene optionally substituted by alkyl, cycloalkyl, aryl or aralkyl; orR.sub.1 and R.sub.2 are each methyl and Y is a bond; and when R.sub.1 is a saccharide residue X is an anion selected from halogen, R.sub.3 CO.sub.2.sup.-, R.sub.3 SO.sub.3.sup.- and R.sub.3 OSO.sub.3.sup.-, wherein R.sub.3 is alkyl, cycloalkyl, aryl, aralkyl or heterocyclyl, andwhen R.sub.1 and R.sub.2 are each methyl, X is an anion selected from R.sub.3 SO.sub.3.sup.-, R.sub.3 OSO.sub.3.sup.- wherein R.sub.3 is as defined above and R.sub.4 CO.sub.2.sup.-, wherein R.sub.4 is an aldose or ketose residue, an N-protected .alpha.-amino acid residue or a .omega.-carboxy-.alpha.-amino acid residue.

摘要翻译： 新型3,7-二取代吩噻嗪鎓盐在含水废水的光化学消毒中具有活性。 所述新型盐具有通式为：其中：R1是糖残基; R 2是烷基，环烷基，芳基，芳烷基或杂环基，任选的烷基或亚烷基链任选被一个或多个杂原子中断，Y是任选被烷基，环烷基，芳基或芳烷基取代的亚烷基; 或R 1和R 2各自为甲基，Y为键; 当R1是糖残基时，X是选自卤素，R3CO2-，R3SO3-和R3OOSO3-的阴离子，其中R3是烷基，环烷基，芳基，芳烷基或杂环基，当R1和R2各自是甲基时，X是阴离子 选自R3SO3-，R3OSO3-，其中R3如上定义，R4CO2-，其中R4是醛糖或酮糖残基，N-保护的α-氨基酸残基或ω-羧基-α-氨基酸残基。