公开(公告)号：US5554697A

公开(公告)日：1996-09-10

申请号：US583241

申请日：1996-01-05

申请人： Menno A. Van Dijk ,  Jacqueline M. Veurink ,  Birgitte M. L. C. Van De Vliet ,  Jeroen Van Westrenen

发明人： Menno A. Van Dijk ,  Jacqueline M. Veurink ,  Birgitte M. L. C. Van De Vliet ,  Jeroen Van Westrenen

IPC分类号： C08F297/04 ,  C09J153/00 ,  C09J153/02

CPC分类号： C08F297/04 ,  C09J153/02

摘要： Block copolymers of the structure A-B-C-D of improved processability derived from a vinyl aromatic monomer and a conjugated diene, having a total bound vinyl aromatic content in the range of from 10 to 40 wt %, wherein the conjugated diene has been polymerized in a 1,2 or 3,4 addition in an amount of from 1 to 20% of the total bound conjugated diene, and wherein A represents a predominantly poly(vinylaromatic)block, B represents a predominantly poly(conjugated diene), D represents a predominantly poly(vinylaromatic)block, and C represents a tapered block of the conjugated diene occurring in the block B and a the vinyl aromatic occuring in the block D, wherein the tapering in block C shows an increasing content of vinyl aromatic monomer in the direction to block D, wherein the weight ratio of the conjugated diene occurring in block B and the conjugated diene occurring in block C is in the range of from 5:5 to 9:1, and wherein the total apparent molecular weight of which is in the range of from 130,000 to 300,000.

摘要翻译： 乙烯基芳族单体和共轭二烯衍生的改进加工性的结构ABCD的嵌段共聚物，总结合的乙烯基芳族化合物含量为10〜40重量％，其中共轭二烯已经在1,2 或3,4加入量为总结合共轭二烯的1至20％，并且其中A表示主要为聚（乙烯基芳族化合物）嵌段，B表示主要为聚（共轭二烯），D表示主要为聚（乙烯基芳族化合物） ）嵌段，C表示嵌段B中发生的共轭二烯的渐缩嵌段和在块D中发生的乙烯基芳族化合物，其中嵌段C中的渐缩显示乙烯基芳族单体在阻断D的方向上的含量增加， 其中嵌段B中发生的共轭二烯和嵌段C中发生的共轭二烯的重量比在5:5至9:1的范围内，其中总表观分子量在 从13万到30万。

公开(公告)号：US5510423A

公开(公告)日：1996-04-23

申请号：US414842

申请日：1995-03-31

申请人： Menno A. Van Dijk ,  Jacqueline M. Veurink ,  Birgitte M. L. C. Van de Vliet ,  Jeroen Van Westrenen

发明人： Menno A. Van Dijk ,  Jacqueline M. Veurink ,  Birgitte M. L. C. Van de Vliet ,  Jeroen Van Westrenen

IPC分类号： C08F297/04 ,  C09J153/00 ,  C09J153/02

CPC分类号： C08F297/04 ,  C09J153/02

摘要： Block copolymers of the structure A-B-C-D of improved processability derived from a vinyl aromatic monomer and a conjugated diene, having a total bound vinyl aromatic content in the range of from 10 to 40 wt. %, wherein the conjugated diene has been polymerized in a 1,2 or 3,4 addition in an amount of from 1 to 20% of the total bound conjugated diene, and wherein A represents a predominantly poly(vinylaromatic)block, B represents a predominantly poly(conjugated diene), D represents a predominantly poly(vinylaromatic)block, and C represents a tapered block of the conjugated diene occurring in the block B and a the vinyl aromatic occuring in the block D, wherein the tapering in block C shows an increasing content of vinyl aromatic monomer in the direction to block D, wherein the weight ratio of the conjugated diene occurring in block B and the conjugated diene occurring in block C is in the range of from 5:5 to 9:1, and wherein the total apparent molecular weight of which is in the range of from 130,000 to 300,000.

摘要翻译： 由乙烯基芳族单体和共轭二烯衍生的改进加工性的结构A-B-C-D的嵌段共聚物，其总结构乙烯基芳族化合物的含量范围为10〜40wt。 ％，其中共轭二烯在1,2或3,4加成中以占总结合的共轭二烯的1至20％的量聚合，并且其中A表示主要是聚（乙烯基芳族化合物）嵌段，B表示 主要是聚（共轭二烯），D代表主要是聚（乙烯基芳族化合物）嵌段，C代表嵌段B中发生的共轭二烯的渐缩嵌段和在块D中发生的乙烯基芳族化合物，其中嵌段C中的渐缩显示 乙烯基芳族单体在阻挡D的方向上的含量增加，其中在嵌段B中发生的共轭二烯和在嵌段C中发生的共轭二烯的重量比在5:5至9:1的范围内，其中 其总表观分子量在13万至30万的范围内。