公开(公告)号：US20130005975A1

公开(公告)日：2013-01-03

申请号：US13602672

申请日：2012-09-04

申请人： Yun CHI ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

发明人： Yun CHI ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

IPC分类号： C07F15/00

CPC分类号： C07F15/0033

摘要： The present invention provides a phosphorescent tris-chelated transition metal complex having one carbon-nitrogen (ĈN) or nitrogen-nitrogen (N̂N) chromophoric ligand forming a coordination sphere thereof with a transition metal, and two identical carbon-phosphorus (ĈP) chelates being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the chromophoric ligands possess a relatively lower energy gap in comparison with that of the non-chromophoric chelate, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that bright phosphorescence can be observed. The architecture and energy gap of the present molecular designs are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明提供了一种具有一个碳氮（ĈN）或氮 - 氮（NN）发色配体的磷光三螯合过渡金属配合物，其与过渡金属形成配位球，并且两个相同的碳 - 磷（ĈP）螯合物是 掺入到配位球中，其中金属是铱，铂，锇或钌，并且发色配体与非发色性螯合物相比具有相对较低的能隙，后者为抑制配体 - 到配体电荷转移过程，使得可以观察到明亮的磷光。 本分子设计的结构和能量差异适用于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US20120247561A1

公开(公告)日：2012-10-04

申请号：US13306609

申请日：2011-11-29

申请人： Yun CHI ,  Cheng-Xuan Li ,  Shen-Han Yang ,  Hsin-Pei Wu ,  Kuan-Lin Wu ,  Chien-Wei Hsu ,  Shih-Han Chang

发明人： Yun CHI ,  Cheng-Xuan Li ,  Shen-Han Yang ,  Hsin-Pei Wu ,  Kuan-Lin Wu ,  Chien-Wei Hsu ,  Shih-Han Chang

IPC分类号： H01L51/46 ,  C07F15/00 ,  C07D401/14 ,  C07D409/14 ,  C07D495/04

CPC分类号： C07D401/14 ,  C07D409/14 ,  C07D495/04 ,  C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0037 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

摘要： Disclosed is a 4,4′-dicarboxy-2,2′-bipyridine derived tridentate ligand represented by formula (I): wherein definitions of Y1, Y2, and R are the same as those defined in the specification. Also disclosed are a metal complex containing the aforesaid tridentate ligand and a dye-sensitized solar cell containing the metal complex.

摘要翻译： 公开了由式（I）表示的4,4'-二羧基-2,2'-联吡啶衍生的三齿配体：其中Y1，Y2和R的定义与说明书中定义的相同。 还公开了含有上述三齿配体的金属络合物和含有金属络合物的染料敏化太阳能电池。

公开(公告)号：US08580961B2

公开(公告)日：2013-11-12

申请号：US13618210

申请日：2012-09-14

申请人： Yun Chi ,  Chien-Wei Hsu ,  Shu-Te Ho

发明人： Yun Chi ,  Chien-Wei Hsu ,  Shu-Te Ho

IPC分类号： C07F15/00 ,  C07D401/04

CPC分类号： C07F15/0046 ,  C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0061 ,  H01L51/0068 ,  H01L51/0086 ,  Y02E10/542

摘要： A 2-phenyl-6-azolylpyridine-based ligand is represented by the following formula (I): wherein, X represents nitrogen or C—R10; R1, R2, R3, R4, R5, R6, R7, R8 and R10 independently represent hydrogen, halogen, a cyano group, an amino group, an optionally substituted aryl group, an optionally substituted heteroaryl group, sulfate, —COOH, an alkoxy group, a carbonyl group, a C1-C10 haloalkyl group, a C1-C12 alkyl group, a C2-C10 alkenyl group, a C2-C10 alkynyl group, a C3-C20 cycloalkyl group, a C3-C20 cycloalkenyl group, a C1-C20 heterocycloalkyl group, or a C1-C20 heterocycloalkenyl group; and R9 represents hydrogen or alkali metal.

摘要翻译： 2-苯基-6-吡唑基吡啶类配体由下式（I）表示：其中，X表示氮或C-R10; R1，R2，R3，R4，R5，R6，R7，R8和R10独立地表示氢，卤素，氰基，氨基，任选取代的芳基，任选取代的杂芳基，硫酸酯，-COOH，烷氧基 基团，羰基，C1-C10卤代烷基，C1-C12烷基，C2-C10烯基，C2-C10炔基，C3-C20环烷基，C3-C20环烯基，C1 -C 20杂环烷基或C 1 -C 20杂环烯基; R9表示氢或碱金属。

公开(公告)号：US20130018189A1

公开(公告)日：2013-01-17

申请号：US13618210

申请日：2012-09-14

申请人： Yun Chi ,  Chien-Wei Hsu ,  Shu-Te Ho

发明人： Yun Chi ,  Chien-Wei Hsu ,  Shu-Te Ho

IPC分类号： C07F15/00 ,  C07D409/14 ,  C07D401/04

CPC分类号： C07F15/0046 ,  C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0061 ,  H01L51/0068 ,  H01L51/0086 ,  Y02E10/542

摘要： A 2-phenyl-6-azolylpyridine-based ligand is represented by the following formula (I): wherein, X represents nitrogen or C—R10; R1, R2, R3, R4, R5, R6, R7, R8 and R10 independently represent hydrogen, halogen, a cyano group, an amino group, an optionally substituted aryl group, an optionally substituted heteroaryl group, sulfate, —COOH, an alkoxy group, a carbonyl group, a C1-C10 haloalkyl group, a C1-C12 alkyl group, a C2-C10 alkenyl group, a C2-C10 alkynyl group, a C3-C20 cycloalkyl group, a C3-C20 cycloalkenyl group, a C1-C20 heterocycloalkyl group, or a C1-C20 heterocycloalkenyl group; and R9 represents hydrogen or alkali metal.

摘要翻译： 2-苯基-6-吡唑基吡啶类配体由下式（I）表示：其中，X表示氮或C-R10; R1，R2，R3，R4，R5，R6，R7，R8和R10独立地表示氢，卤素，氰基，氨基，任选取代的芳基，任选取代的杂芳基，硫酸酯，-COOH，烷氧基 基团，羰基，C1-C10卤代烷基，C1-C12烷基，C2-C10烯基，C2-C10炔基，C3-C20环烷基，C3-C20环烯基，C1 -C 20杂环烷基或C 1 -C 20杂环烯基; R9表示氢或碱金属。

公开(公告)号：US20090209756A1

公开(公告)日：2009-08-20

申请号：US12385864

申请日：2009-04-22

申请人： Yun Chi ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

发明人： Yun Chi ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

IPC分类号： C07F15/00 ,  C07F9/6541 ,  C07F9/6539 ,  C07F9/6558 ,  C07F9/6547 ,  C07F9/6544

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical carbon-nitrogen (ĈN) or nitrogen-nitrogen (N̂N) chromophoric ligands being incorporated into a coordination sphere thereof with a transition metal, and one carbon-phosphorus (ĈP) chelate being incorporated into the coordination sphere; or ii) one carbon-nitrogen (ĈN) or nitrogen-nitrogen (N̂N) chromophoric ligand forming a coordination sphere thereof with a transition metal, and two identical carbon-phosphorus (ĈP) chelates being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the chromophoric ligands possess a relatively lower energy gap in comparison with that of the non-chromophoric chelate, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that bright phosphorescence can be observed. The architecture and energy gap of the present molecular designs are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明公开了一种磷光三螯合过渡金属络合物，其包括i）两个相同的碳氮（ĈN）或氮 - 氮（NN）发色配体与过渡金属掺入其配位球中，并且一个碳 - 磷 ĈP）螯合物被并入配位球; 或ii）一个碳 - 氮（ĈN）或氮 - 氮（NN）发色配体与过渡金属形成配位球，并且两个相同的碳 - 磷（ĈP）螯合物被并入配位球中，其中金属是 铱，铂，锇或钌，并且发色配体与非发色螯合物相比具有相对较低的能隙，后者为抑制配体与配体电荷转移过程提供了有效的屏障，使得光亮 可观察到磷光。 本分子设计的结构和能量差异适用于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US08822818B2

公开(公告)日：2014-09-02

申请号：US13306609

申请日：2011-11-29

申请人： Yun Chi ,  Cheng-Xuan Li ,  Shen-Han Yang ,  Hsin-Pei Wu ,  Kuan-Lin Wu ,  Chien-Wei Hsu ,  Shih-Han Chang

发明人： Yun Chi ,  Cheng-Xuan Li ,  Shen-Han Yang ,  Hsin-Pei Wu ,  Kuan-Lin Wu ,  Chien-Wei Hsu ,  Shih-Han Chang

IPC分类号： C07D401/14 ,  C07D409/14 ,  C07D495/04 ,  C07F15/00 ,  H01L51/00 ,  H01G9/20

CPC分类号： C07D401/14 ,  C07D409/14 ,  C07D495/04 ,  C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0037 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

摘要： Disclosed is a 4,4′-dicarboxy-2,2′-bipyridine derived tridentate ligand represented by formula (I): wherein definitions of Y1, Y2, and R are the same as those defined in the specification. Also disclosed are a metal complex containing the aforesaid tridentate ligand and a dye-sensitized solar cell containing the metal complex.

摘要翻译： 公开了由式（I）表示的4,4'-二羧基-2,2'-联吡啶衍生的三齿配体：其中Y1，Y2和R的定义与说明书中定义的相同。 还公开了含有上述三齿配体的金属络合物和含有金属络合物的染料敏化太阳能电池。

公开(公告)号：US08557988B2

公开(公告)日：2013-10-15

申请号：US13602672

申请日：2012-09-04

申请人： Yun Chi ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

发明人： Yun Chi ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

IPC分类号： C07F15/00 ,  C07F3/12

CPC分类号： C07F15/0033

摘要： The present invention provides a phosphorescent tris-chelated transition metal complex having one carbon-nitrogen (C^N) or nitrogen-nitrogen (N^N) chromophoric ligand forming a coordination sphere thereof with a transition metal, and two identical carbon-phosphorus (C^P) chelates being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the chromophoric ligands possess a relatively lower energy gap in comparison with that of the non-chromophoric chelate, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that bright phosphorescence can be observed. The architecture and energy gap of the present molecular designs are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明提供一种具有一个碳 - 氮（C ^ N）或氮 - 氮（N）N）发色配体的磷光三螯合过渡金属配合物，其与过渡金属形成配位球，和两个相同的碳 - 磷 C ^ P）螯合物掺入配位球中，其中金属是铱，铂，锇或钌，并且发色配体与非发色螯合物相比具有相对较低的能隙，后者提供了有效的 用于抑制配体 - 配体电荷转移过程的屏障，使得可以观察到明亮的磷光。 本分子设计的结构和能量差异适用于产生高效率的蓝，绿，甚红色发射。

公开(公告)号：US20130119764A1

公开(公告)日：2013-05-16

申请号：US13346537

申请日：2012-01-09

申请人： Chien-Wei Hsu ,  Chia-Hao Chang ,  Chia-Wen Hsu ,  Hao-Yen Kuanch

发明人： Chien-Wei Hsu ,  Chia-Hao Chang ,  Chia-Wen Hsu ,  Hao-Yen Kuanch

IPC分类号： H02J4/00

CPC分类号： G06F1/188 ,  G06F1/20 ,  G06F1/26 ,  Y10T307/50

摘要： A modularized power control device for a computer system includes an upper plate, a lower plate, a first connecting unit and a second connecting unit. The upper plate has a first voltage converter for converting a first voltage into a plurality of first operating voltages. The lower plate has a second voltage converter and a fan control module. The second voltage converter is configured to receive a second voltage and convert the second voltage into a plurality of second operating voltages. The fan control module is configured to control operations of a plurality of heat dissipation fans inside the computer system. The first connecting unit is configured to connect a plurality of power lines of the upper plate and power lines of the lower plate. The second connecting unit is configured to connect a plurality of signal lines of the upper plate and signal lines of the lower plate.

摘要翻译： 一种用于计算机系统的模块化功率控制装置，包括上板，下板，第一连接单元和第二连接单元。 上板具有用于将第一电压转换成多个第一工作电压的第一电压转换器。 下板具有第二电压转换器和风扇控制模块。 第二电压转换器被配置为接收第二电压并将第二电压转换成多个第二工作电压。 风扇控制模块被配置为控制计算机系统内的多个散热风扇的操作。 第一连接单元被配置为连接上板的多个电源线和下板的电力线。 第二连接单元被配置为连接下板的上板和信号线的多条信号线。

公开(公告)号：US08288543B2

公开(公告)日：2012-10-16

申请号：US12385864

申请日：2009-04-22

申请人： Yun Chi ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

发明人： Yun Chi ,  Jui-Yi Hung ,  Cheng-Huei Lin ,  Pi-Tai Chou ,  I-Hsuan Pai ,  Chien-Wei Hsu

IPC分类号： C07F15/00 ,  C07F3/12

CPC分类号： C07F15/0033

摘要： The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical carbon-nitrogen (C^N) or nitrogen-nitrogen (N^N) chromophoric ligands being incorporated into a coordination sphere thereof with a transition metal, and one carbon-phosphorus (C^P) chelate being incorporated into the coordination sphere; or ii) one carbon-nitrogen (C^N) or nitrogen-nitrogen (N^N) chromophoric ligand forming a coordination sphere thereof with a transition metal, and two identical carbon-phosphorus (C^P) chelates being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the chromophoric ligands possess a relatively lower energy gap in comparison with that of the non-chromophoric chelate, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that bright phosphorescence can be observed. The architecture and energy gap of the present molecular designs are suitable for generation of high efficiency blue, green and even red emissions.

摘要翻译： 本发明公开了一种磷光三螯合过渡金属络合物，其包括i）两个相同的碳 - 氮（C 3 N）或氮 - 氮（N 2 N）发色配体与过渡金属掺入其配位球中，一个 碳 - 磷（C ^ P）螯合物掺入配位球; 或ii）一个碳 - 氮（C 3 N）或氮 - 氮（N 2 N）发色配体与过渡金属形成配位球，并且将两个相同的碳 - 磷（C ^ P）螯合物并入协调 球，其中金属是铱，铂，锇或钌，并且发色配体与非发色螯合物相比具有相对较低的能隙，后者为抑制配体与配体的电荷提供了有效的屏障 转移过程，使得可以观察到明亮的磷光。 本分子设计的结构和能量差异适用于产生高效率的蓝，绿，甚红色发射。