Method for preparing polyether polymers of predetermined molecular
    2.
    发明授权
    Method for preparing polyether polymers of predetermined molecular 有权
    制备预定分子的聚醚聚合物的方法

    公开(公告)号:US06265521B1

    公开(公告)日:2001-07-24

    申请号:US09632675

    申请日:2000-08-07

    IPC分类号: C08G7310

    CPC分类号: C08G73/12

    摘要: Polyether polymers such as polyetherimides are prepared by a two-step reaction. The first step is the reaction between an alkali metal salt of a dihydroxy-substituted aromatic hydrocarbon, such as bisphenol A disodium salt, and a substituted aromatic compound such as 1,3-bis[N-(4-chlorophthalimido)]benzene, the alkali metal salt being employed in an amount less than stoichiometric. The intermediate low molecular weight polymer thus produced then undergoes reaction with additional alkali metal salt. By this method, a polyether polymer of closely controlled molecular weight can be conveniently prepared.

    摘要翻译: 聚醚聚合物如聚醚酰亚胺通过两步反应制备。 第一步是二羟基取代的芳族烃如双酚A二钠盐的碱金属盐与1,3-双[N-(4-氯苯二酰亚氨基)]苯等取代的芳香族化合物的反应, 碱金属盐的用量小于化学计量。 由此制备的中间体低分子量聚合物随后与另外的碱金属盐反应。 通过这种方法,可以方便地制备密度受控分子量的聚醚聚合物。