公开(公告)号：US4294734A

公开(公告)日：1981-10-13

申请号：US107709

申请日：1979-12-27

申请人： Giovanni Corrado ,  Elvio Bertotti ,  Bruno Sopino

发明人： Giovanni Corrado ,  Elvio Bertotti ,  Bruno Sopino

IPC分类号： C08G63/676 ,  C08K7/14 ,  C08L91/00 ,  C08G63/52

CPC分类号： C08G63/676 ,  C08K3/40 ,  C08K7/14

摘要： A low viscosity unsaturated polyester resin for making glass fiber reinforced products is described, which comprises an alkyd prepared by esterification of maleic anhydride and/or acid and/or fumaric acid, optionally together with phthalic anhydride and/or acid, with one or more glycols, essentially comprising dipropylene glycol, and further comprises 27-34% by weight (of the total resin) of an ethylenically unsaturated monomer copolymerizable with the alkyd, essentially chosen among styrene and vinyl toluene, the alkyd having a molecular weight/double bond factor between 200 and 360 and an amount of free functional groups between 80 and 100 mg of KOH per g of alkyd inclusive. The products obtainable from said resin by conventional processing techniques are also described. The low viscosity of the resin results in better workability and better behavior of the resin during molding while the mechanical properties of the finished products are very good.

摘要翻译： 描述了用于制备玻璃纤维增​​强产品的低粘度不饱和聚酯树脂，其包括通过马来酸酐和/或酸和/或富马酸（任选与邻苯二甲酸酐和/或酸）与一种或多种二醇酯化而制备的醇酸树脂 ，基本上包含二丙二醇，并且还包含27-34重量％（总树脂）的可与醇酸树脂共聚的烯属不饱和单体，基本上选自苯乙烯和乙烯基甲苯，该醇酸树酯具有分子量/双键因子介于 200和360，并且每克醇酸酯包括80和100mg KOH之间的游离官能团的量。 还描述了通过常规加工技术从所述树脂获得的产品。 树脂的低粘度导致成型时树脂的更好的加工性和更好的性能，而成品的机械性能非常好。

公开(公告)号：US4292218A

公开(公告)日：1981-09-29

申请号：US107710

申请日：1979-12-27

申请人： Giovanni Corrado ,  Elvio Bertotti ,  Bruno Sopino

发明人： Giovanni Corrado ,  Elvio Bertotti ,  Bruno Sopino

IPC分类号： C08G63/00 ,  B29D19/04 ,  C08G63/52 ,  C08G63/676 ,  C08L91/00

CPC分类号： C08G63/676 ,  B29D19/04

摘要： A low viscosity unsaturated polyester resin for making buttons is described, which comprises an alkyd prepared by esterification of maleic anhydride and/or acid and/or fumaric acid, optionally together with phthalic anhydride and/or acid and/or adipic, sebacic, azelaic or dodecanedioic acid, with one or more glycols, essentially comprising dipropylene glycol, and further comprises 20-30% by weight of the total resins of an ethylenically unsaturated monomer copolymerizable with the alkyd, essentially chosen among styrene and vinyl toluene, the alkyd having a molecular weight/double bond factor between 300 and 390 and an amount of free functional groups between 80 and 100 mg of KOH per g of alkyd inclusive. The buttons obtainable from said resin are also described. The disc blanks made from said resin have better workability and cause less wear of the tools than those of the prior art and the finished buttons have greater impact strength, and better lustre, greater color stability when exposed to sun light.

摘要翻译： 描述了用于制造纽扣的低粘度不饱和聚酯树脂，其包括通过马来酸酐和/或酸和/或富马酸的酯化制备的醇酸树脂，任选与邻苯二甲酸酐和/或酸和/或己二酸，癸二酸，壬二酸或/ 十二烷二酸与一种或多种二醇，基本上包含二丙二醇，并且还包含20-30重量％的可与醇酸树脂共聚的烯属不饱和单体的总树脂，基本上选自苯乙烯和乙烯基甲苯，醇酸树脂具有分子 重量/双键因子在300和390之间，游离官能团的量在80至100mg的KOH / g醇酸树脂之间。 还描述了可从所述树脂获得的按钮。 由所述树脂制成的圆盘坯料具有更好的可加工性，并且比现有技术的工具具有更少的磨损，并且完成的按钮具有更大的冲击强度，并且在暴露于阳光下时具有更好的光泽，更大的颜色稳定性。

公开(公告)号：US4312978A

公开(公告)日：1982-01-26

申请号：US143419

申请日：1980-04-24

申请人： Marzio Ligutti ,  Elvio Bertotti

发明人： Marzio Ligutti ,  Elvio Bertotti

IPC分类号： C08G63/676 ,  C08G63/66

CPC分类号： C08G63/676

摘要： A process for the preparation of an unsaturated polyester from a glycol and tetrahydrophthalic anhydride, maleic anhydride and/or fumaric acid, suitable for the production of an unsaturated polyester resin rapidly loosing its surface tackiness after cross-linking, and furnishing very flexible materials which are resistant to creasing, is described. The glycol employed has at least two ether bridges regularly alternated with --CH.sub.2 --CH.sub.2 -- groups. The reaction is carried out in such a way as to obtain an alkyd essentially exempt from free tetrahydrophthalic anhydride. The resins thus prepared are adapted to the production of putties free from surface tackiness and having good finishing properties for application by spraying and/or by putty knife.

摘要翻译： 用于从二醇和四氢邻苯二甲酸酐，马来酸酐和/或富马酸制备不饱和聚酯的方法，适于生产不饱和聚酯树脂，其在交联后迅速失去其表面粘性，并提供非常柔软的材料， 描述了抗压痕。 所用的二醇具有至少两个与-CH 2 -CH 2 - 基定期交替的醚桥。 该反应以获得基本上不含游离四氢邻苯二甲酸酐的醇酸树脂的方式进行。 如此制备的树脂适于生产不含表面粘性的油灰，并且具有通过喷雾施用和/或通过油灰刀施加的良好的整理性能。

公开(公告)号：US4294748A

公开(公告)日：1981-10-13

申请号：US107708

申请日：1979-12-27

申请人： Giovanni Corrado ,  Elvio Bertotti ,  Bruno Sopino

发明人： Giovanni Corrado ,  Elvio Bertotti ,  Bruno Sopino

IPC分类号： C08G63/00 ,  C08G63/52 ,  C08G63/676 ,  C08L91/00

CPC分类号： C08G63/676 ,  C08K3/40

摘要： A low viscosity unsaturated polyester resin for making products, optionally reinforced with glass fibers is described, which comprises an alkyd prepared by esterification of maleic anhydride and/or acid and/or fumaric acid in association with isophtalic acid, with one or more glycols, essentially comprising dipropylene glycol, and further comprises 25-40% by weight of the total resin of an ethylenically unsaturated monomer copolymerizable with the alkyd essentially chosen among styrene and vinyl toluene, the alkyd having a molecular weight/double bond factor between 300 and 390 and an amount of free functional groups between 50 and 85 mg of KOH per g of alkyd inclusive. The products obtainable from said resin are also described. The resin behaves better in processing has lower heat development and shrinkage than the comparable prior art resins while the mechanical properties of the finished products are very good.

摘要翻译： 描述了用于制造产品的低粘度不饱和聚酯树脂，其任选地用玻璃纤维增​​强，其包括通过马来酸酐和/或酸和/或富马酸与间苯二甲酸酯化制备的醇酸树脂与一种或多种二醇，基本上 包括二丙二醇，并且还包含25-40重量％的总树脂，其可与基本上选自苯乙烯和乙烯基甲苯的醇酸树脂共聚的烯键式不饱和单体，醇酸树酯的分子量/双键因子在300和390之间， 每克醇酸包括50至85毫克KOH之间的游离官能团的含量。 还描述了可从所述树脂获得的产品。 与现有技术的树脂相比，树脂在加工中表现较好，发热和收缩率低，而成品的机械性能非常好。

公开(公告)号：US4530783A

公开(公告)日：1985-07-23

申请号：US356344

申请日：1982-03-09

申请人： Luigi Arcuri ,  Elvio Bertotti ,  Giancarlo Carignani ,  Aldo Cipriani ,  Aldo Donato ,  Giuseppe Grossi

发明人： Luigi Arcuri ,  Elvio Bertotti ,  Giancarlo Carignani ,  Aldo Cipriani ,  Aldo Donato ,  Giuseppe Grossi

IPC分类号： C08G63/00 ,  C08F299/00 ,  C08F299/04 ,  C08G63/52 ,  C08L67/00 ,  C08L67/06 ,  G21F9/00 ,  G21F9/16 ,  G21F9/30

CPC分类号： G21F9/167 ,  C08K3/00

摘要： A composition of matter suitable for solidifying radioactive wastes is formed of unsaturated polyester resins comprising a polyester (I) obtained polycondensing (a) maleic anhydride and/or maleic and/or fumaric acid, (b) isophthalic and/or terephthalic acid, (c) neopentylglycol, (d) optionally one or more conventional glycols, wherein the amount of (c) is at least 50% by moles with respect to (c)+(d); another polyester (II) obtained polycondensing (a) maleic anhydride and/or maleic and/or fumaric acid, (b) isopropylidene-bis-(phenylene-oxypropanol-2), (c) optionally one or more conventional glycols, wherein the amount of (b) is at least 50% by moles with respect to (b)+(c); an ethylenically unsaturated monomer (III) capable of copolymerizing with (I) and (II); inhibitors, initiators, accelerators, glass fibers and other conventional additives and fillers the weight ratio of component (I) to (II) being from 100:0 to 20:80.

摘要翻译： 适用于固化放射性废物的物质组合物由不饱和聚酯树脂形成，所述不饱和聚酯树脂包含获得的缩聚（a）马来酸酐和/或马来酸和/或富马酸的聚酯（I），（b）间苯二甲酸和/或对苯二甲酸，（c ）新戊二醇，（d）任选的一种或多种常规二醇，其中（c）的量相对于（c）+（d）为至少50摩尔％; 获得缩聚（a）马来酸酐和/或马来酸和/或富马酸的另一种聚酯（II），（b）异亚丙基 - 双 - （亚苯基 - 氧基丙醇-2），（c）任选的一种或多种常规二醇，其中 （b）相对于（b）+（c）为至少50摩尔％; 能够与（I）和（II）共聚的烯属不饱和单体（III）; 抑制剂，引发剂，促进剂，玻璃纤维和其它常规添加剂和填料，组分（I）与（II）的重量比为100:0至20:80。