摘要:
There is disclosed a canister for interim storage and subsequent consolidation of waste materials via hot pressing. In an embodiment, the canister comprises at least one ion exchange material, and is configured to: house the ion exchange material after it is exchanged with a contaminating ion without releasing the contaminating ion; and consolidate via hot-isostatic pressing. There is also disclosed a contacting a fluid waste with an ion exchange material, wherein the ion exchange material is located in a canister; evacuating the canister; and hot isostatically pressing (HIP) the canister until it collapses under HIP conditions.
摘要:
The present invention is a method for eliminating radioactive iodine using a hydrophilic resin that adsorbs radioactive iodine, wherein the hydrophilic resin is at least one selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin and has a hydrophilic segment and, in the principal chain and/or a side chain in the structure thereof, has a tertiary amino group or has a tertiary amino group and polysiloxane segment. By means of the present invention, a novel method for eliminating radioactive iodine is provided that is simple and low-cost, furthermore does not require an energy source such as electricity, moreover can take in and stably immobilize the eliminated radioactive iodine within a solid, and is capable of reducing the volume of radioactive waste as necessary.
摘要:
The present invention intends to provide a method for removing radioactive cesium, or radioactive iodine and radioactive cesium that is simple and low-cost, further does not require an energy source such as electricity, moreover can take in and stably immobilize the removed radioactive substances within a solid, and can reduce the volume of radioactive waste as necessary, and to provide a hydrophilic resin composition using for the method for removing radioactive cesium, or radioactive iodine and radioactive cesium, and the object of the present invention is achieved by using a hydrophilic resin composition containing: at least one hydrophilic resin selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin each having at least a hydrophilic segment; and a zeolite dispersed therein in a ratio of at least 1 to 200 mass parts relative to 100 mass parts of the hydrophilic resin.
摘要:
The present invention provides an encapment process for rapidly stabilizing and substantially reducing the volume of moisture bearing radioactive and mixed hazardous waste materials. The present process effectively utilizes polyacrylate encapsulating material in combination with equipment or systems which deliver the encapsulates to the waste material being processed. The polyacrylates may be dispersed from a pressurized vessel to stop leaks and spills, added to solid waste material to produce waste material which has no free standing liquids, or added to liquid waste material and dried to significantly reduce the volume of the waste material and produce a waste product having no free standing liquids.
摘要:
There is disclosed a method and apparatus for waste disposal by hydraulic embedment in a subterranean formation. A method in accordance with the present invention comprises the steps of drilling into stable geologic formations thousands of feet below ground, fracturing those formations, pumping a mixture of hazardous waste in solid, liquid, or sludge form and a selected transport medium into the fractured formations, and preventing migration of the waste. Although a suitable transport medium can be selected based on a number of factors, transport media selected in accordance with one aspect of the present invention prevent migration of the waste by reacting chemically or to either heat or pressure or both to become highly viscous or solid. In other aspects of the present invention, the method prevents waste migration by either pumping a fluid for sealing the fractured underground formation before the mixture is pumped or encapsulating the waste prior to mixture with the transport medium and injection into the fractured formation. Apparatus for carrying out the method is also disclosed.
摘要:
A method is disclosed of immobilizing actinide metal oxide ions. A liquid composition is prepared of the actinide metal oxide ions and a monomer which is capable during electropolymerization of complexing with the actinide metal ions. An optional polar solvent may be included in the composition if it is necessary to dissolve a solid monomer. The monomer is then electropolymerized to form a polymeric complex with the actinide metal oxide ion. The polymeric complex can be separated from the remainder of the liquid composition by the addition of a non-solvent for the polymeric complex which results in its precipitation. Vinylimidazoles have been found to be suitable monomers for use in this process.
摘要:
Solutions or slurries of waste material in water are dewatered and encapsulated within a polymer for disposal, comprising the operations of removing water therefrom with azeotropic mixture evaporation and encasing the dewatered waste residue in an organic polymer. The method and system disclosed are especially useful for the safe disposal of radioactive waste.
摘要:
A method of disposing of wastes, especially wastes containing radioactive or toxic substances, such as the wastes generated in the water associated with nuclear power production is described. A feature of the invention is to incorporate the waste into a hardenable setting mass when mixed with water, comprising calcium sulfate hemihydrate, water soluble melamine formaldehyde resin which when cured is hydrophobic, and a cross-linking agent for curing the resin.
摘要:
Radioactive organic liquids are converted to a form suitable for burial by the process wherein the liquid is contacted with insoluble, swellable polymer particles to form swollen gelled particles which are dispersed in an unsaturated polyester, vinyl ester resin or mixture thereof which is then cured to a solid state with the gelled particles encased therein.
摘要:
Liquid-containing radioactive wastes are bound into thermoplastic material by introducing particles of thermoplastic material at a non-sticking temperature into a kneading machine, heating the thermoplastic material in the absence of radioactive wastes to at least 100.degree. C., adding the liquid-containing wastes to the heated thermoplastic material, mixing and concurrently increasing the temperature of the mixture to a temperature of about 200.degree. C. or more to vaporize liquid in the mixture, maintaining the mixture at a vaporization temperature to dry to the mixture, releasing evolved vapors and discharging the dried mixture from the kneading machine. Difficulties due to clogging of the kneading machine and fluctuations in the consistency of the dried end product are minimized.