公开(公告)号：US07230040B1

公开(公告)日：2007-06-12

申请号：US10836625

申请日：2004-05-03

Applicant: Steven R. Carlo ,  Eva M. Maya ,  Arthur W. Snow ,  Richard Gork Sim Pong

Inventor： Steven R. Carlo ,  Eva M. Maya ,  Arthur W. Snow ,  Richard Gork Sim Pong

IPC: C08K5/16

CPC classification number: C08K5/0041 ,  C08J3/205

Abstract: High concentrations of dye may be prepared in combination with thermoplastic polymers and used in optical polymers as monomeric and dimeric molecular solutions. The method of preparing high concentration levels allows the control over the aggregation of dye molecules that is required to maintain effective nonlinear operation. The present invention is applicable to many systems and is essential to the successful production of working optical limiting devices and other optically transparent polymeric devices, as well as other photonic applications, such as nonlinear optics.

Abstract translation: 可以与热塑性聚合物组合制备高浓度的染料，并将其用作光学聚合物作为单体和二聚体分子溶液。 制备高浓度水平的方法允许控制维持有效非线性操作所需的染料分子聚集。 本发明可应用于许多系统，并且对于成功生产工作光学限制装置和其它光学透明聚合物装置以及其它光子应用（例如非线性光学器件）是必需的。

公开(公告)号：US06933402B2

公开(公告)日：2005-08-23

申请号：US10253601

申请日：2002-09-25

Applicant: Arthur W. Snow ,  James S Shirk ,  Eva M Maya ,  Richard G. S. Pong ,  Steven R. Flom

Inventor： Arthur W. Snow ,  James S Shirk ,  Eva M Maya ,  Richard G. S. Pong ,  Steven R. Flom

IPC: C07F7/08 ,  C08G77/58 ,  C08K5/34 ,  C09B62/00 ,  G02C7/10 ,  C07C255/51 ,  C07C255/54

CPC classification number: C08G77/58 ,  C07F7/0838

Abstract: The present invention is phthalocyanine compounds with peripheral siloxane substitution, as well as methods for making these compounds and various uses thereof, having the basic structure: wherein —W—X—Y-Z are peripheral groups comprising individual W, X, Y, and Z subgroups; W is a linkage represented by the formula: -D-(R1)0,1—, where D=S or O; X is: —(CH2)n—, n=2 to 8; Y is a siloxane chain; Z is an aryl or alkyl terminal cap; M is two protons or a metal ion; and forms a transparent film of high optical quality with large nonlinear absorption and thermal refraction, free of scattering from solid or liquid crystalline domains making them highly suitable for use as the active component in thin films, protective eye wear, and optical data storage applications.

Abstract translation: 本发明是具有外围硅氧烷取代性的酞菁化合物，以及具有以下基本结构的制备这些化合物及其各种用途的方法：其中-W-X-Y-Z是包含单独的W，X，Y和Z亚组的外围基团; W是由下式表示的键：-D-（R 1）0,1 ... - ，其中D = S或O; X为： - （CH 2）n - ，n = 2〜8; Y是硅氧烷链; Z是芳基或烷基末端帽; M是两个质子或金属离子; 并形成具有大的非线性吸收和热折射的高光学质量的透明膜，不受固体或液晶畴的散射，使得它们非常适合用作薄膜，保护眼睛磨损和光学数据存储应用中的活性成分。

公开(公告)号：US07652078B2

公开(公告)日：2010-01-26

申请号：US11746499

申请日：2007-05-09

Applicant: Steven R. Carlo ,  Eva M. Maya ,  Arthur W. Snow ,  Richard G. S. Pong

Inventor： Steven R. Carlo ,  Eva M. Maya ,  Arthur W. Snow ,  Richard G. S. Pong

IPC: C08K5/16

CPC classification number: C08K5/0041 ,  C08J3/205

Abstract: High concentrations of dye may be prepared in combination with thermoplastic polymers and used in optical polymers as monomeric and dimeric molecular solutions. The method of preparing high concentration levels allows the control over the aggregation of dye molecules that is required to maintain effective nonlinear operation. The present invention is applicable to many systems and is essential to the successful production of working optical limiting devices and other optically transparent polymeric devices, as well as other photonic applications, such as nonlinear optics.

Abstract translation: 可以与热塑性聚合物组合制备高浓度的染料，并将其用作光学聚合物作为单体和二聚体分子溶液。 制备高浓度水平的方法允许控制维持有效非线性操作所需的染料分子聚集。 本发明可应用于许多系统，并且对于成功生产工作光学限制装置和其它光学透明聚合物装置以及其它光子应用（例如非线性光学器件）是必需的。

公开(公告)号：US07550586B2

公开(公告)日：2009-06-23

申请号：US11108146

申请日：2005-04-12

Applicant: Arthur W. Snow ,  James S Shirk ,  Eva M Maya ,  Richard G. S. Pong ,  Steven R. Flom

Inventor： Arthur W. Snow ,  James S Shirk ,  Eva M Maya ,  Richard G. S. Pong ,  Steven R. Flom

IPC: C07B47/00 ,  C07D487/22

CPC classification number: C08G77/58 ,  C07F7/0838

Abstract: The present invention is phthalocyanine compounds with peripheral siloxane substitution, as well as methods for making these compounds and various uses thereof, having the basic structure: wherein —W—X—Y—Z are peripheral groups comprising individual W, X, Y, and Z subgroups; W is a linkage represented by the formula: —D—(R1)0.1—, where D═S or O; X is: —(CH2)n—, n=2 to 8; Y is a siloxane chain; Z is an aryl or alkyl terminal cap; M is two protons or a metal ion; and forms a transparent film of high optical quality with large nonlinear absorption and thermal refraction, free of scattering from solid or liquid crystalline domains making them highly suitable for use as the active component in thin films protective eye wear, and optical data storage applications.

Abstract translation: 本发明是具有外围硅氧烷取代性的酞菁化合物，以及具有以下基本结构的制备这些化合物及其各种用途的方法：其中-W-X-Y-Z是包含单独的W，X，Y和Z亚组的外围基团; W是由以下通式表示的键：-D-（R1）0.1-，其中D-S或O; X是： - （CH 2）n - ，n = 2〜8; Y是硅氧烷链; Z是芳基或烷基末端帽; M是两个质子或金属离子; 并形成具有大的非线性吸收和热折射的高光学质量的透明膜，不受固体或液晶畴的散射，使得它们非常适合用作薄膜保护眼睛磨损和光学数据存储应用中的有源成分。

公开(公告)号：US06498249B1

公开(公告)日：2002-12-24

申请号：US09886039

申请日：2001-06-22

Applicant: Arthur W. Snow ,  James S. Shirk ,  Eva M. Maya ,  Richard G. S. Pong ,  Steven R. Flom

Inventor： Arthur W. Snow ,  James S. Shirk ,  Eva M. Maya ,  Richard G. S. Pong ,  Steven R. Flom

IPC: C07D48722

CPC classification number: C08G77/58 ,  C07F7/0838

Abstract: The present invention is phthalocyanine compounds with peripheral siloxane substitution, as well as methods for making these compounds and various uses thereof, having the basic structure: wherein —W—X—Y—Z are peripheral groups comprising individual W, X, Y, and Z subgroups; W is a linkage represented by the formula: —D—(R1)0,1—, where D=S or O; X is: —(CH2)n—, n=2 to 8; Y is a siloxane chain; Z is an aryl or alkyl terminal cap; M is two protons or a metal ion; and forms a transparent film of high optical quality with large nonlinear absorption and thermal refraction, free of scattering from solid or liquid crystalline domains making them highly suitable for use as the active component in thin films, protective eye wear, and optical data storage applications.

Abstract translation: 本发明是具有外围硅氧烷取代基的酞菁化合物，以及具有以下基本结构的制备这些化合物及其各种用途的方法：其中-WXYZ是包含单独的W，X，Y和Z亚组的外围基团; W是 其中D = S或O; X为： - （CH 2）n - ，n = 2-8; Y为硅氧烷链; Z为芳基 或烷基末端帽; M是两个质子或金属离子;并形成具有大的非线性吸收和热折射的高光学质量的透明膜，不受固体或液晶畴的散射，使得它们非常适合用作活性组分 在薄膜，防护眼睛磨损和光学数据存储应用中。