公开(公告)号：US4384870A

公开(公告)日：1983-05-24

申请号：US287082

申请日：1981-07-27

申请人： Francois Benguerel

发明人： Francois Benguerel

IPC分类号： C09B31/065 ,  C09B43/18 ,  C09B43/28 ,  C09B31/06 ,  D06P3/00

CPC分类号： C09B43/28 ,  C09B31/065 ,  C09B43/18 ,  Y10S534/01

摘要： Compounds of the formula ##STR1## in which A is the radical of a sulpho group-containing diazo component of the aniline or 1- or 2-aminonaphthalene series,K is a coupling component radical of the phenol series, having a free hydroxy group or an etherified or acylated hydroxy group,R.sub.1 is hydrogen C.sub.1-4 alkoxy, C.sub.1-4 alkyl or C.sub.1-4 haloalkyl,R.sub.2 is C.sub.1-4 alkyl, C.sub.1-6 alkyl-CO-, C.sub.1-6 alkyl-O-CO-, -CONH.sub.2, C.sub.1-6 alkyl-NH-CO-, di-(C.sub.1-6 alkyl)N-CO-, 2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)-NH-CO- or (2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)).sub.2 N-CO-, andR.sub.10 is hydrogen or C.sub.1-4 alkyl,and mixtures thereof, which compounds are in free acid or salt form and are useful for dyeing or printing anionic dyeable substrates such as leather, natural and synthetic polyamides, polyurethanes and polyolefins modified to contain basic groups, especially nylon.

摘要翻译： 其中A是苯胺或1-或2-氨基萘系列的含磺基的重氮组分的基团的式“IMAGE”的化合物，K是具有游离羟基的酚系的偶联组分基团， 醚化或酰化羟基，R 1是氢C 1-4烷氧基，C 1-4烷基或C 1-4卤代烷基，R 2是C 1-4烷基，C 1-6烷基-CO-，C 1-6烷基-O-CO-，-CONH 2，C 1-6烷基 -NH-CO-，二 - （C 1-6烷基）N -CO-，2-，3-，4-，5-或6-羟基（C 2-6烷基）-NH-CO-或（2-， ，4-，5-或6-羟基（C 2-6烷基））2N-CO-，R 10为氢或C 1-4烷基，及其混合物，其化合物为游离酸或盐形式，可用于染色或印刷 阴离子可染色基材如皮革，天然和合成聚酰胺，聚氨酯和改性成含有碱性基团的聚烯烃，特别是尼龙。

公开(公告)号：US4323498A

公开(公告)日：1982-04-06

申请号：US2226

申请日：1979-01-09

申请人： Francois Benguerel

发明人： Francois Benguerel

IPC分类号： C09B31/08 ,  C09B31/04 ,  C09B29/04

CPC分类号： C09B31/08

摘要： Compounds of the formula ##STR1## in which D is ##STR2## in which R.sub.1 is trifluoromethyl, --COOM.sub.1 --COOR.sub.2 ; or a group of the formula or --NHR.sub.3, --NR.sub.3 R.sub.4 or --NR.sub.5 COR.sub.6 in a position meta or para to the azo group, ring A being optionally further substituted by a total of up to two further substituents selected from halogen, (C.sub.1-4)alkyl, (C.sub.1-4)alkoxy and trifluoromethyl (only one further trifluoromethyl group),R.sub.2 is (C.sub.1-12)alkyl,each of R.sub.3 and R.sub.4, independently, is (C.sub.1-6)alkyl,R.sub.5 is hydrogen or (C.sub.1-4)alkyl,R.sub.6 is (C.sub.1-6)alkyl, (C.sub.1-6)alkoxy or (C.sub.1-6)alkyl monosubstituted by chlorine or methoxy,B is a divalent radical of the 1,4-phenylene, 1,4-naphthylene or 1,2,3,4-tetrahydronaphthylene-5,8 series, andeach of M and M.sub.1, independently, is hydrogen or an equivalent of a non-chromophoric cation, with the proviso that the molecule contains a single --SO.sub.3 M group which is in the 5- or 6-position, and mixtures thereof, which compounds and mixtures are useful as anionic dyestuffs for substrates such as natural and synthetic polyamides, polyolefins modified to contain basic groups, polyurethanes and leather. They are well-soluble in water, exhaust from a neutral dyebath, build-up well and yield intense, even dyeings possessing notable fastness to washing, sweat, rubbing and light.

摘要翻译： 其中D为的式“IMAGE”的化合物，其中R 1为三氟甲基，-COOM 1 -COOR 2; 或一组式或-NHR 3，-NR 3 R 4或-NR 5 COR 6位于偶氮基的间位或对位，环A任选进一步被总共多至两个选自卤素，（C 1-4）烷基的另外的取代基取代， 烷基，（C 1-4）烷氧基和三氟甲基（仅一个另外的三氟甲基），R 2是（C 1-12）烷基，R 3和R 4各自独立地是（C 1-6）烷基，R 5是氢或（C 1〜 4）烷基，R6是（C1-6）烷基，（C1-6）烷氧基或被氯或甲氧基单取代的（C1-6）烷基，B是1,4-亚苯基，1,4-亚萘基的二价基团 或1,2,3,4-四氢苊-5,8系，M和M1各自独立地为氢或等价的非发色阳离子，条件是分子含有单个-SO 3 M基团， 是5-或6-位，以及它们的混合物，该化合物和混合物可用作底物的阴离子染料，例如天然和合成聚酰胺，被改性成含有碱性基团的聚烯烃，聚氨酯和聚氨酯 r。 它们易溶于水，从中性染浴中排出，积聚良好，产生强烈的均匀染色，具有显着的洗涤牢度，汗水，摩擦和光泽。

公开(公告)号：US4081438A

公开(公告)日：1978-03-28

申请号：US572765

申请日：1975-04-29

申请人： Francois Benguerel ,  Jean-Jacques Salzmann

发明人： Francois Benguerel ,  Jean-Jacques Salzmann

IPC分类号： C09B29/033 ,  C09B29/00 ,  C09B31/02 ,  C09B43/11 ,  C09B43/24 ,  C09B43/28 ,  C09B31/14

CPC分类号： C09B43/28 ,  C09B29/0055 ,  C09B31/025 ,  C09B43/11 ,  C09B43/24

摘要： Disclosed are azo dyes containing a diazo component radical of the formula ##STR1## wherein each of Z and Z.sub.1 is independently hydrogen or sulfo,With the proviso that at least one of Z and Z.sub.1 is hydrogen,For example monoazo and disazo dyes of the formula ##STR2## and salts thereof, WHEREINK is a coupling component radical of the aromatic carbocyclic, active methylene group-containing aliphatic or aromatic heterocyclic series, andZ and Z.sub.1 are as defined above, with the proviso that the dyes contain one or two sulfo groups, and the use thereof for the dyeing and printing of anionic dyeable substrates, particularly polyamide substrates.

摘要翻译： 公开了含有下式的重氮组分基团的偶氮染料，其中Z和Z1各自独立地为氢或磺基，其中Z和Z1的至少一个为氢，对于制剂的实施例MONOAZO和DISAZO DYES 其中，K是芳族碳环，含活性亚甲基的脂族或芳族杂环系列的偶联组分基团，Z和Z1如上所定义，条件是染料含有一个或两个磺基 基团，以及其用于染色和印刷阴离子可染色基材，特别是聚酰胺基材的用途。

公开(公告)号：US4685934A

公开(公告)日：1987-08-11

申请号：US754533

申请日：1985-07-12

申请人： Francois Benguerel ,  Roland Mislin

发明人： Francois Benguerel ,  Roland Mislin

IPC分类号： C09B29/036 ,  C09B29/00 ,  D06P1/39 ,  C09B29/09 ,  C09B29/30 ,  C09B29/36

CPC分类号： D06P1/39 ,  C09B29/0037 ,  Y10S8/929

摘要： Monoazo compounds of formula ##STR1## wherein R.sub.1 is a coupling component radical,R.sub.1 is C.sub.1-6 alkyl; C.sub.1-6 alkyl substituted by 1 or 2 substituents selected from chloro, cyano, hydroxy, C.sub.1-4 alkoxy, phenyl and phenyl substituted by 1 or 2 substituents selected from chloro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, carboxy, sulfo, sulfamoyl and acetamido; C.sub.5-7 cycloalkyl; C.sub.5-7 cycloalkyl substituted by 1 to 3 C.sub.1-4 alkyl groups; phenyl; phenyl substituted by 1 to 3 substituents selected from chloro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, acetamido (maximum of 1), carboxy (maximum of 1), sulfo (maximum of 1) and --SO.sub.2 NR.sub.7 R.sub.8 (maximum of 1); 1- or 2-naphthyl or 1- or 2-naphthyl substituted by sulfo,whereineach of R.sub.7 and R.sub.8 is independently hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy or phenyl; cyclohexyl; phenyl or phenyl monosubstituted by chloro, methyl or methoxy, or--NR.sub.7 R.sub.8 is a 5- or 6-membered saturated or unsaturated ring containing 1 or 2 hetero atoms,R.sub.2 is hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy, chloro, cyano, C.sub.1-4 alkoxy, phenyl or phenyl substituted by 1 or 2 substituents selected from chloro, methyl, methoxy, sulfo and sulfamoyl; C.sub.1-4 alkoxy; cyano; phenyl; phenoxy; or phenyl or phenoxy monosubstituted by chloro, methyl, methoxy or sulfo, andR.sub.3 is cyano, carbamoyl, --COOR.sub.4, sulfo or --CO.sub.2 NR.sub.5 R.sub.6,whereinR.sub.4 is hydrogen, C.sub.1-4 alkyl, phenyl or phenyl(C.sub.1-4 alkyl), andeach of R.sub.5 and R.sub.6 is independently hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy or phenyl; cyclohexyl; phenyl or phenyl monosubstituted by chloro, methyl or methoxy, or--NR.sub.5 R.sub.6 is a 5- or 6-membered saturated or unsaturated ring containing 1 or 2 hetero atoms,with the provisos that (i) the total number of sulfo groups is 1 or 2 and (ii) R.sub.1, R.sub.2 or R.sub.3 must contain a sulfo group when K.sub.1 is a coupling component radical of the aminobenzene series the amino group of which is substituted by an alkylene radical having a terminal sulfo or sulfato group, by a bridge member-containing alkylene radical having a terminal sulfo or sulfato group or by a phenylalkyl group the phenyl group of which has a sulfo substituent, are useful for dyeing or printing anionically dyeable substrates such as natural or synthetic polyamides, especially nylon carpet.

公开(公告)号：US4185013A

公开(公告)日：1980-01-22

申请号：US739493

申请日：1976-11-08

申请人： Francois Benguerel ,  Jean-Jacques Salzmann

发明人： Francois Benguerel ,  Jean-Jacques Salzmann

IPC分类号： C09B29/00 ,  C09B31/02 ,  C09B43/11 ,  C09B43/24 ,  C09B43/28 ,  C09B29/12 ,  C09B35/38 ,  C09B35/40 ,  C09B35/42

CPC分类号： C09B29/0055 ,  C09B31/025 ,  C09B43/11 ,  C09B43/24 ,  C09B43/28

摘要： Disclosed are azo dyes containing, a diazo component radical of the formula ##STR1## wherein each of Z and Z.sub.1 is independently hydrogen or sulfo, with the proviso that at least one of Z and Z.sub.1 is hydrogen, for example monoazo and disazo dyes of the formula ##STR2## and salts thereof, wherein K is a coupling component radical of the aromatic carbocyclic, active methylene group-containing aliphatic or aromatic heterocyclic series, andZ and Z.sub.1 are as defined above, with the proviso that the dyes contain one or two sulfo groups, and the use thereof for the dyeing and printing of anionic dyeable substrates, particularly polyamide substrates.

摘要翻译： 公开了含有下式的重氮组分基团的偶氮染料，其中Z和Z1各自独立地为氢或磺基，条件是Z和Z1中的至少一个为氢，例如，单偶氮和双偶氮染料 其中K是芳族碳环，含活性亚甲基的脂族或芳族杂环系列的偶联组分基团，Z和Z1如上所定义，条件是染料含有一个或两个 磺基，以及其用于染色和印染阴离子可染色基材，特别是聚酰胺基材的用途。