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公开(公告)号：US4097583A
公开(公告)日：1978-06-27
申请号：US777451
申请日：1977-03-14
申请人： Hermann Niermann , Franz Mainzer
发明人： Hermann Niermann , Franz Mainzer
CPC分类号： C01B25/00
摘要： Production of phosphorus pentasulfide from phosphorus and sulfur at elevated temperature in a reactor of which the walls are in heat exchange with a substance kept at the temperature necessary for cooling or heating reaction mixture. The heat exchange in the bottom portion of the reactor is more particularly effected with the use of a system functioning separately and independently from the heat exchange system surrounding the lateral walls of the reactor.
摘要翻译： 在其中壁与保持在冷却或加热反应混合物所需温度的物质进行热交换的反应器中，在高温下从磷和硫生产五硫化二磷。
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2.发明授权Method and apparatus for controlling and optionally regulating the level of liquid P.sub.2 S.sub.5 in a cooling device 失效用于控制和可选地调节冷却装置中的液体P2S5的水平的方法和装置
公开(公告)号：US4386503A
公开(公告)日：1983-06-07
申请号：US235050
申请日：1981-02-17
申请人： Gunter Reichert , Franz Mainzer , Kurt Lehmann , Hermann Niermann
发明人： Gunter Reichert , Franz Mainzer , Kurt Lehmann , Hermann Niermann
CPC分类号： G01F23/165 , C01B25/14
摘要： The invention relates to a method for controlling and optionally regulating the level of liquid P.sub.2 S.sub.5 in a cooling device. To this end, an inert gas is introduced into the cooling apparatus arranged in inclined position. More particularly, the inert gas is introduced into the cooling apparatus' lower end portion through an inlet opening thereinto near a P.sub.2 S.sub.5 -feed inlet, and forced to bubble through the liquid P.sub.2 S.sub.5. The pressure difference which establishes in accordance with the P.sub.2 S.sub.5 liquid level in the device is measured and variations in the respective pressure difference are utilized for regulating the supply of liquid P.sub.2 S.sub.5 to the cooling device so as to maintain a predetermined liquid level therein.
摘要翻译： 本发明涉及一种用于控制和可选地调节冷却装置中液体P2S5的水平的方法。 为此，将惰性气体引入设置在倾斜位置的冷却装置中。 更具体地说，惰性气体通过P2S5进料口附近的入口被引入冷却装置的下端部分，并且被迫气泡通过液体P2S5。 测量根据装置中的P2S5液位建立的压力差，并且利用各压力差的变化来调节向冷却装置供应液体P2S5，以便保持其中的预定液位。
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3.发明授权Method for controlling and optionally regulating the level of liquid P.sub.2 S.sub.5 in a cooling device 失效用于控制和可选地调节冷却装置中液体P2S5的水平的方法
公开(公告)号：US4520631A
公开(公告)日：1985-06-04
申请号：US609518
申请日：1984-05-14
申请人： Gunter Reichert , Franz Mainzer , Kurt Lehmann , Hermann Niermann
发明人： Gunter Reichert , Franz Mainzer , Kurt Lehmann , Hermann Niermann
CPC分类号： G01F23/165 , C01B25/14
摘要： The invention relates to a method for controlling and optionally regulating the level of liquid P.sub.2 S.sub.5 in a cooling device. To this end, an inert gas is introduced into the cooling apparatus arranged in inclined position. More particularly, the inert gas is introduced into the cooling apparatus' lower end portion through an inlet opening thereinto near a P.sub.2 S.sub.5 -feed inlet, and forced to bubble through the liquid P.sub.2 S.sub.5. The pressure difference which establishes in accordance with the P.sub.2 S.sub.5 liquid level in the device is measured and variations in the respective pressure difference are utilized for regulating the supply of liquid P.sub.2 S.sub.5 to the cooling device so as to maintain a predetermined liquid level therein.
摘要翻译： 本发明涉及一种用于控制和可选地调节冷却装置中液体P2S5的水平的方法。 为此，将惰性气体引入设置在倾斜位置的冷却装置中。 更具体地说，惰性气体通过P2S5进料口附近的入口被引入冷却装置的下端部分，并且被迫气泡通过液体P2S5。 测量根据装置中的P2S5液位建立的压力差，并且利用各压力差的变化来调节向冷却装置供应液体P2S5，以便保持其中的预定液位。
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公开(公告)号：US4473538A
公开(公告)日：1984-09-25
申请号：US487998
申请日：1983-04-29
IPC分类号： C01B25/14
CPC分类号： C01B25/14
摘要： The invention provides a process and an apparatus for removing molten phosphorus pentasulfide, via an overflow, from a reactor, wherein phosphorus is reacted with sulfur at temperatures higher than 300.degree. C.To this end, the reactor is supplied with phosphorus and sulfur from dosing vessels which are given the dimensions necessary (a) to receive the quantity of phosphorus and sulfur, respectively, which are required to produce phosphorus pentasulfide with a preselected quantitative ratio of P:S, (b) to provide a total filling volume corresponding to that of a P.sub.2 S.sub.5 -receiving tank. The quantity of the phosphorus and sulfur feed materials in the respective dosing vessels is in each case fully emptied into the reactor and a corresponding quantity of molten P.sub.2 S.sub.5 is simultaneously discharged directly from the reactor, via the overflow, into the respective P.sub.2 S.sub.5 -receiving tank, whose filling volume exactly corresponds, to that of the dosing vessels.
摘要翻译： 本发明提供一种通过溢流从反应器中除去五硫化二磷的方法和装置，其中磷在高于300℃的温度下与硫反应。为此，向反应器中加入磷和硫 给定尺寸所需的尺寸（a）分别接收以预选的P：S定量比例生产五硫化二磷所需的磷和硫量，（b），以提供与该P 的P2S5接收罐。 在各个配量容器中的磷和硫进料的量在每种情况下都完全排空到反应器中，并且相应量的熔融P2S5同时从反应器经由溢流排放到相应的P2S5接收罐中， 其填充体积与计量容器的填充体积完全相符。
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公开(公告)号：US4173621A
公开(公告)日：1979-11-06
申请号：US863081
申请日：1977-12-22
IPC分类号： C01B25/14
CPC分类号： C01B25/14
摘要： The reactivity of phosphorus pentasulfide produced by reacting phosphorus and sulfur at a temperature higher than the melting point of phosphorus pentasulfide and allowing the resulting melt to cool and solidify on a cooling device is improved. To this end, liquid phosphorus pentasulfide is placed on, or introduced into, a cooling device; an upper liquid P.sub.2 S.sub.5 -layer portion A is separated immediately from a solidified lower P.sub.2 S.sub.5 -layer portion B which is in direct contact with the cooling surface area of the cooling device; the upper P.sub.2 S.sub.5 -layer portion A is recycled to a P.sub.2 S.sub.5 melt; the lower P.sub.2 S.sub.5 -layer portion B is removed from the cooling device and collected as final product; the reactivity of the collected P.sub.2 S.sub.5 -layer portion B is increased to the same extent as the quantitative ratio of the P.sub.2 S.sub.5 -layer portion A to the P.sub.2 S.sub.5 -layer portion B is increased.
摘要翻译： 通过在高于五硫化二磷的熔点的温度下使磷和硫反应产生的五硫化二磷的反应性得到改善，并使所得的熔体在冷却装置上冷却和固化。 为此，将五硫化二磷液体放置在冷却装置上或引入冷却装置中; 立即从与冷却装置的冷却表面区域直接接触的凝固的下P2S5层部分B分离上液体P2S5层部分A; 上P2S5层部分A再循环到P2S5熔体中; 将较低的P2S5层部分B从冷却装置中取出并收集成最终产品; 收集的P2S5层部分B的反应性增加到与P2S5层部分A与P2S5层部分B的量比增加的程度相同的程度。
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