公开(公告)号：US20120183988A1

公开(公告)日：2012-07-19

申请号：US13387207

申请日：2010-07-30

申请人： G. Tayhas R. Palmore ,  Vince Siu

发明人： G. Tayhas R. Palmore ,  Vince Siu

IPC分类号： G01N21/64 ,  C07K14/35

CPC分类号： G01N33/82

摘要： This invention is directed to an intein-based vitamin D fluorescent biosensor that accurately and rapidly measures 1α,25-hydroxyvitamin D3. Measurement at picomolar quantities is noted. Particular reference is made to the use of Escherichia coli (E. coli) as a sensor organism, although yeast and mammalian host organisms are also contemplated.

摘要翻译： 本发明涉及准确和快速地测量1α，25-羟基维生素D 3的内含肽维生素D荧光生物传感器。 注意皮摩尔量的测量。 尽管也考虑了酵母和哺乳动物宿主生物，但特别提到使用大肠杆菌（E.coli）作为传感器生物体。

公开(公告)号：US08435696B2

公开(公告)日：2013-05-07

申请号：US12905398

申请日：2010-10-15

申请人： G. Tayhas R. Palmore ,  Jiangfeng Fei ,  Hyun-Kon Song

发明人： G. Tayhas R. Palmore ,  Jiangfeng Fei ,  Hyun-Kon Song

IPC分类号： H01M8/10

CPC分类号： H01M8/16 ,  H01M4/8807 ,  H01M4/8853 ,  H01M4/9008 ,  Y02E60/527

摘要： The present invention is directed to a redox-active, conducting polymer energy storage system, said system including an electrode and a counter electrode, wherein the electrode comprises a first conducting polymer and the counter electrode comprises a second conducting polymer, wherein the first conducting polymer is doped by at least one or more first redox-active compounds and/or by a polymer and/or a co-polymer of the one or more first redox-active compounds and the second conducting polymer is doped by at least one or more second redox-active compounds and/or by a polymer and/or a co-polymer of the one or more second redox-active compounds, and wherein there is a potential difference between the dopant for the electrode and the dopant for the counter electrode. In one preferred embodiment, the first or the second redox-active compound is 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonate) (ABTS). In another preferred embodiment, an exemplary redox-active compound is a polymerizable derivative of ABTS or a polymer or co-polymer of this monomer.

摘要翻译： 本发明涉及氧化还原活性导电聚合物储能系统，所述系统包括电极和对电极，其中所述电极包括第一导电聚合物，所述对电极包括第二导电聚合物，其中所述第一导电聚合物 由至少一种或多种第一氧化还原活性化合物和/或通过一种或多种第一种氧化还原活性化合物和第二导电聚合物的聚合物和/或共聚物掺杂至少一个或多个第二 氧化还原活性化合物和/或一种或多种第二种氧化还原活性化合物的聚合物和/或共聚物，并且其中在电极的掺杂剂和对电极的掺杂剂之间存在电位差。 在一个优选的实施方案中，第一或第二氧化还原活性化合物是2,2'-氮杂双（3-乙基苯并噻唑啉-6-磺酸盐）（ABTS）。 在另一个优选的实施方案中，示例性氧化还原活性化合物是ABTS的可聚合衍生物或该单体的聚合物或共聚物。

公开(公告)号：US20130244123A1

公开(公告)日：2013-09-19

申请号：US13642608

申请日：2011-04-19

申请人： G. Tayhas R. Palmore ,  Sung Yeol Kim

发明人： G. Tayhas R. Palmore ,  Sung Yeol Kim

IPC分类号： H01M14/00 ,  H01M8/16

CPC分类号： H01M14/005 ,  B82Y10/00 ,  H01G9/2018 ,  H01G9/2031 ,  H01L51/0093 ,  H01M4/90 ,  H01M8/16 ,  H01M12/00 ,  Y02E10/542 ,  Y02E60/527 ,  Y02P70/56

摘要： A system for harvesting electric energy from illumination by photons by photo- and bioelectrocatalysis includes an electrode coated with conducting polymer matrix containing the oxidoreductase, laccase, and a redox mediator, 2,2′-azino-bis(3-ethylbenzothiaxoline-6-sulfonic acid (ABTS). The photo-anode is based on nanocrystalline TlO2 (Degussa, P25) adhered to a fluorine tin oxide (FTO) electrode. The device operation is based on a continuous photocatalytic oxidation of water to oxygen at a TiO2-photoanode and bioelectrocatalytic reduction of oxygen to water at a biocathode under illumination with light.

摘要翻译： 通过光生物电催化由光子从照明中收集电能的系统包括涂覆有含有氧化还原酶，漆酶和氧化还原介体的导电聚合物基质的电极，2,2'-偶氮双（3-乙基苯并三唑啉-6-磺酸 酸性（ABTS），光阳极基于粘附到氟氧化锡（FTO）电极上的纳米晶体TlO2（Degussa，P25），器件操作是基于在TiO 2光电阳极上水与氧的连续光催化氧化， 在用光照射下在生物阴极处生物电催化还原氧气到水。

公开(公告)号：US20110031440A1

公开(公告)日：2011-02-10

申请号：US12905398

申请日：2010-10-15

申请人： G. Tayhas R. Palmore ,  Jiangfeng Fei ,  Hyun-Kon Song

发明人： G. Tayhas R. Palmore ,  Jiangfeng Fei ,  Hyun-Kon Song

IPC分类号： H01B1/12

CPC分类号： H01M8/16 ,  H01M4/8807 ,  H01M4/8853 ,  H01M4/9008 ,  Y02E60/527

摘要： The present invention is directed to a redox-active, conducting polymer energy storage system, said system including an electrode and a counter electrode, wherein the electrode comprises a first conducting polymer and the counter electrode comprises a second conducting polymer, wherein the first conducting polymer is doped by at least one or more first redox-active compounds and/or by a polymer and/or a co-polymer of the one or more first redox-active compounds and the second conducting polymer is doped by at least one or more second redox-active compounds and/or by a polymer and/or a co-polymer of the one or more second redox-active compounds, and wherein there is a potential difference between the dopant for the electrode and the dopant for the counter electrode. In one preferred embodiment, the first or the second redox-active compound is 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonate) (ABTS). In another preferred embodiment, an exemplary redox-active compound is a polymerizable derivative of ABTS or a polymer or co-polymer of this monomer.

摘要翻译： 本发明涉及氧化还原活性导电聚合物储能系统，所述系统包括电极和对电极，其中所述电极包括第一导电聚合物，所述对电极包括第二导电聚合物，其中所述第一导电聚合物 由至少一种或多种第一氧化还原活性化合物和/或通过一种或多种第一种氧化还原活性化合物和第二导电聚合物的聚合物和/或共聚物掺杂至少一个或多个第二 氧化还原活性化合物和/或一种或多种第二种氧化还原活性化合物的聚合物和/或共聚物，并且其中在电极的掺杂剂和对电极的掺杂剂之间存在电位差。 在一个优选的实施方案中，第一或第二氧化还原活性化合物是2,2'-氮杂双（3-乙基苯并噻唑啉-6-磺酸盐）（ABTS）。 在另一个优选的实施方案中，示例性氧化还原活性化合物是ABTS的可聚合衍生物或该单体的聚合物或共聚物。

公开(公告)号：US07838687B2

公开(公告)日：2010-11-23

申请号：US11512430

申请日：2006-08-29

申请人： G. Tayhas R. Palmore ,  Jiangfeng Fei ,  Hyun-Kon Song

发明人： G. Tayhas R. Palmore ,  Jiangfeng Fei ,  Hyun-Kon Song

IPC分类号： C07D293/00 ,  C07D417/02

CPC分类号： H01M8/16 ,  H01M4/8807 ,  H01M4/8853 ,  H01M4/9008 ,  Y02E60/527

摘要： The present invention provides a monomer comprising the structure: wherein R1 and/or R1′ are selected from the group consisting of MeO, EtO, COF3, SO4H, SO3−, SO3H, H, CHNO4S2F3, C5H4N2O6S2F6, C10H10N4S2, CH3, n-Bu, Cl, NH2, EtN, Br, alkyl, ether, ester, sulfonate, ammonium, carboxylate, phosphonate and any combination thereof, R2 and/or R2′, are selected from the group consisting of EtO, SO3H, H, C10H10N4S2, CH3, Cl, C6H14N2S and any combination thereof, R3 and/or R3′ are selected from the group consisting of CH3, Cl, H and any combination thereof, and R4 and/or R4′ are selected from the group consisting of CH3, H, C2H5, C4H9, C6H5, C8H17, C2H5S, C3H7S, C4H8Br, C10H23N, C20H21N2, C18H25N2, C21H23N2, C31H29N2O2, C22H25N4, C20H25N2, C3H7OS, and any combination thereof.

摘要翻译： 本发明提供一种包含以下结构的单体：其中R1和/或R1'选自MeO，EtO，COF3，SO4H，SO3-，SO3H，H，CHNO4S2F3，C5H4N2O6S2F6，C10H10N4S2，CH3，n-Bu ，Cl，NH2，EtN，Br，烷基，醚，酯，磺酸盐，铵，羧酸盐，膦酸盐及其任何组合，R2和/或R2'选自EtO，SO3H，H，C10H10N4S2，CH3 ，Cl，C 6 H 14 N 2 S及其任何组合，R 3和/或R 3'选自CH 3，Cl，H及其任何组合，并且R 4和/或R 4'选自CH 3，H， C2H5，C4H9，C6H5，C8H17，C2H5S，C3H7S，C4H8Br，C10H23N，C20H21N2，C18H25N2，C21H23N2，C31H29N2O2，C22H25N4，C20H25N2，C3H7OS及其任意组合。