摘要:
A TiC-based cermet body includes TiC and WC so that the atomic ratio Ti/W is between 2 to 5, and cobalt as the binder phase is present in an amount of between 5 to 25 vol %. Further, the cermet body has at least one element from group V of the periodic table, Mx, so that the atomic ratio Ti/Mx is between 4 to 20 and the atomic ratio W/Mx is between 1 to 6. The cermet body also has Cr in an amount such that the atomic Cr/Co ratio is from 0.025 to 0.14. The cermet body includes both undissolved TiC cores with a rim of (Ti,W,Mx)C alloy as well as (Ti,W,Mx)C grains which have been formed during sintering. A method of making a cermet body is also disclosed.
摘要:
A TiC-based cermet body includes TiC and WC so that the atomic ratio Ti/W is between 2 to 5, and cobalt as the binder phase is present in an amount of between 5 to 25 vol %. Further, the cermet body has at least one element from group V of the periodic table, Mx, so that the atomic ratio Ti/Mx is between 4 to 20 and the atomic ratio W/Mx is between 1 to 6. The cermet body also has Cr in an amount such that the atomic Cr/Co ratio is from 0.025 to 0.14. The cermet body includes both undissolved TiC cores with a rim of (Ti,W,Mx)C alloy as well as (Ti,W,Mx)C grains which have been formed during sintering. A method of making a cermet body is also disclosed.
摘要:
The present invention relates to a method for manufacturing a sintered body of carbonitride alloy with titanium as the main component and cobalt as the binder phase and which does not have any compositional gradients or center porosity concentration after sintering. This is achieved by processing the material in a specific manner to obtain a lower melting point of the liquid phase in the interior of the body than in the surface while balancing the gas atmosphere outside the body with the alloy composition during all stages of the liquid phase sintering.
摘要:
The present invention relates to a sintered body of titanium-based carbonitride alloy comprising hard constituents containing at least tungsten in addition to titanium in a binder phase based on cobalt. There are four distinctly different microstructural components, namely: A) cores which are remnants of and have a metal composition determined by the raw material powder; B) tungsten-rich cores formed during the sintering; C) outer rims with intermediate tungsten content formed during the sintering; and D) a binder phase of a solid solution of at least titanium and tungsten in cobalt. Toughness and wear resistance are varied by adding WC, (Ti,W)C, and/or (Ti,W)(C,N) in varying amounts as raw materials.
摘要:
A sintered body of titanium based carbonitride alloy containing hard constituents based on, in addition to titanium, one or more of the metals Zr, Hf, V, Nb, Ta, Cr, No or W in 5-30% binder phase based on Co and/or Ni is disclosed. The body has a binder phase enriched surface zone with a higher binder phase content than in the inner portion of the body in combination with an enrichment of simple hard constituents, i.e., the share of grains with core-rim structure is lower in the surface zone than in the inner of the body. A method of manufacturing the sintered carbonitride alloy is also provided which comprises forming a powder mixture containing binder phase containing Co and/or Ni and hard constituents of carbides and nitrides with titanium as a main component, the mixture having composition which is substoichiometric regarding an interstitial balance and sintering the mixture to completely transform the substoichiometric phases to stoichiometric by heating a) in vacuum to 1100-1200 C., b) in vacuum at about 1200 C. for about 30 minutes, c) in deoxidizing H.sub.2 -atmosphere for 15-30 minutes at about 1200 C., d) in N.sub.2 -atmosphere during heating to sintering temperature 1400-1600 C., and e) cooling to room temperature in vacuum or inert gas.
摘要:
There is provided a sintered titanium-based carbonitride alloy for metal cutting containing hard constituents based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and 3-30% binder phase based on Co and/or Ni. The structure contains 10-50% by weight well-dispersed Ti-rich hard constituent grains essentially without core-rim structure with a mean grain size of 0.8-5 .mu.m in a conventional carbonitride alloy matrix with a mean grain size of the hard constituents of 1-2 .mu.m. The Ti-rich hard constituent grains are essentially rounded, non-angular grains with an approximately logarithmic normal grain size distribution with a standard deviation of
摘要:
The invention relates to a cermet body essentially free from nitrogen where the binder phase is Co in an amount of from about 5 to about 25 vol % Co, further comprising TiC and WC in amounts so that the atomic Ti:W ratio is from about 2.5 to about 10. The cermet body further comprising Cr in an amount such that the atomic Cr:Co ratio is from about 0.025 to about 0.14. The cermet body is free from nucleated of Ti—W—C cores. The invention also relates to a method of making a cermet body.
摘要:
A titanium based carbonitride alloy contains Ti, Nb, W, C, N and Co. The alloy also contains, in addition to Ti, Co with only impurity levels of Ni and Fe, 4-7 at % Nb, 3-8 at % W and has a C/(C+N) ratio of 0.50-0.75. The Co content is 9-
摘要:
A titanium based carbonitride alloy containing Ti, Nb, W, C, N and Co. The alloy also contains, in addition to Ti, 9-14 at % Co with only impurity levels of Ni and Fe, 1-
摘要:
A sintered body of a carbonitride alloy with titanium as main component which has improved properties particularly when used as cutting tool material in light finishing cutting operations at high cutting speed. This has been achieved by combining a carbonitride based hard phase of specific chemical composition with an extremely solution hardened Co-based binder phase.