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1.发明授权Aromatic amide groups-containing diamines and polymers in which these diamines are incorporated 失效含有芳酰胺基团的二胺和其中加入这些二胺的聚合物
公开(公告)号：US4980444A
公开(公告)日：1990-12-25
申请号：US372327
申请日：1989-06-28
IPC分类号： C07C67/00 , C07C231/00 , C07C231/02 , C07C231/12 , C07C233/64 , C07C233/78 , C07C313/00 , C07C315/06 , C07C317/22 , C07C317/36 , C07C323/20 , C07C323/42 , C07C323/62 , C08G18/38 , C08G69/26 , C08G69/32 , C08G69/44 , C08G73/10 , C08G73/14 , C08G73/16
CPC分类号： C08G18/3825 , C08G69/32 , C08G69/44 , C08G73/14 , C08G73/16
摘要： There is provided a new class of diamines of the formula ##STR1## wherein X=NH or O, and R represents a divalent, substituted or unsubstituted organic group having at the most 20 carbon atoms.The diamines, wherein X has the meaning of an O-atom, may be converted with diacids, diacid dichlorides, aromatic carboxylic acid anhydrides or diisocyanates into poly(esteraramid) amides, poly(esteraramid) imides, or poly(esteraramid) urea or, when X stands for an --NH-group, into poly(amidaramid) amides, poly(amidaramid) imides, or poly(amidaramid) urea.The wholly or largely aromatic polyamides, polyurea or polyimides are of an iterative structure. They can be melt-processed into shaped objects displaying a very good resistance to high temperatures, particularly when use is made of diamines having meta-substituted amide groups or diamines of a non-aromatic structure for the --XRX-- group, or of a non-aromatic structure of the diacids, diacid dichlorides, aromatic carboxylic acid anhydrides or diisocyanates to be linked to the diamines. By altering the chemical structure of the diamines on the one hand and the diamine-linkable bifunctional compounds on the other, both the melting performance and the level of crystallinity of the end product may be influenced.
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公开(公告)号：US5162489A
公开(公告)日：1992-11-10
申请号：US532401
申请日：1990-06-04
IPC分类号： C07C233/80 , C08G69/26 , C08G69/32 , C08G73/10 , C08G73/14
CPC分类号： C08G73/10 , C07C233/80 , C08G69/26 , C08G69/32 , C08G73/14 , C07C2102/08
摘要： Diamines having a 1,1,3-trimethylphenylindane dicarboxylic moiety linked on both sides to phenylene diamine by an amide bond (PIDA diamines) are disclosed. By reacting these diamines with aromatic difunctional acid derivatives, amorphous polymers having high glass transition temperatures (Tg) can be prepared. If aliphatic diacid derivatives are used the resulting polymers have a lower Tg, but have the advantage of melt-processability. The PIDA-diamines can also be used in the preparation of polyimides, being reacted either with tri-or tetracarboxylic anhydrides or with imide group-containing acid derivatives.
摘要翻译： 公开了具有通过酰胺键（PIDA二胺）两端连接到苯二胺的1,1,3-三甲基苯基茚基二羧基部分的二胺。 通过使这些二胺与芳族二官能酸衍生物反应，可以制备具有高玻璃化转变温度（Tg）的无定形聚合物。 如果使用脂族二酸衍生物，则所得聚合物具有较低的Tg，但具有熔融加工性的优点。 PIDA-二胺也可用于制备聚酰亚胺，与三酸酐或四羧酸酐或与含酰亚胺基的酸衍生物反应。
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公开(公告)号：US5565546A
公开(公告)日：1996-10-15
申请号：US435264
申请日：1995-05-05
申请人： Paul K. Hanna , Andrzej M. Piotrowski , Bert J. Lommerts , Steven R. Leijenaar , Gerrit Hoentjen
发明人： Paul K. Hanna , Andrzej M. Piotrowski , Bert J. Lommerts , Steven R. Leijenaar , Gerrit Hoentjen
CPC分类号： C08G67/02
摘要： Copolymers comprising carbon monoxide and ethylene contain at least one type of ketal structure and possess enhanced thermal stability so as to be useful in the melt processing of fibers. These novel copolymers, as well as known polyketones with ketal structures, can be formed by treating a copolymer of carbon monoxide and at least one olefin with a mixture of acid, such as a sulfonic acid, which acts as a catalyst or catalyst/reagent, and alcohol, such as a lower alkanol.
摘要翻译： 包含一氧化碳和乙烯的共聚物含有至少一种缩酮结构并具有增强的热稳定性，以便可用于纤维的熔融加工。 这些新型共聚物以及具有缩酮结构的已知聚酮可以通过用作为催化剂或催化剂/试剂的酸如磺酸的混合物处理一氧化碳和至少一种烯烃的共聚物来形成， 和醇，如低级链烷醇。
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4.发明授权Aromatic amide groups-containing diamines and polymers in which these diamines are incorporated 失效含有芳酰胺基团的二胺和其中加入这些二胺的聚合物
公开(公告)号：US4851562A
公开(公告)日：1989-07-25
申请号：US120931
申请日：1987-11-16
IPC分类号： C07C67/00 , C07C231/00 , C07C231/02 , C07C231/12 , C07C233/64 , C07C233/78 , C07C313/00 , C07C315/06 , C07C317/22 , C07C317/36 , C07C323/20 , C07C323/42 , C07C323/62 , C08G18/38 , C08G69/26 , C08G69/32 , C08G69/44 , C08G73/10 , C08G73/14 , C08G73/16
CPC分类号： C08G18/3825 , C08G69/32 , C08G69/44 , C08G73/14 , C08G73/16
摘要： There is provided a new class of diamines of the formula ##STR1## wherein X=NH or O, and R represents a divalent, substituted or unsubstituted organic group having at the most 20 carbon atoms.The diamines, wherein X has the meaning of an O-atom, may be converted with diacids, diacid dichlorides, aromatic carboxylic acid anhydrides or diisocyanates into poly(esteraramid) amides, poly(esteraramid) imides, or poly(esteraramid) urea or, when X stands for an --NH--group, into poly(amidaramid) amides, poly(amidaramid) imides, or poly(amidaramid) urea.The wholly or largely aromatic polyamides, polyurea or polyimides are of an iterative structure. They can be melt-processed into shaped objects displaying a very good resistance to high temperatures, particularly when use is made of diamines having meta-substituted amide groups or diamines of a non-aromatic structure for the --XRX-- group, or of a non-aromatic structure of the diacids, diacid dichlorides, aromatic carboxylic acid anhydrides or diisocyanate to be linked to the diamines. By alterning the chemical structure of the diamines on the one hand and the diamine-linkable bifunctional compounds on the other, both are melting performance and the level of crystallinity of the end product may be influenced.
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5.发明授权
公开(公告)号：US4980504A
公开(公告)日：1990-12-25
申请号：US387201
申请日：1989-07-28
IPC分类号： C07D209/48 , C07C233/80 , C08G69/26 , C08G69/32 , C08G73/10 , C08G73/14
CPC分类号： C08G73/14 , C07C233/80 , C08G69/26 , C08G69/32 , C08G73/10 , C07C2102/08
摘要： Diamines having a 1,1,3-trimethylphenylindane dicarboxylic moiety linked on both sides to phenylene diamine by an amide bond (PIDA diamines) are disclosed. By reacting these diamines with aromatic difunctional acid derivatives, amorphous polymers having high glass transition temperatures (Tg) can be prepared. If aliphatic diacid derivatives are used the resulting polymers have a lower Tg, but have the advantage of melt-processability. The PIDA-diamines can also be used in the preparation of polyimides, being reacted either with tri- or tetracarboxylic anhydrides or with imide group-containing acid derivatives.
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公开(公告)号：US4284772A
公开(公告)日：1981-08-18
申请号：US37568
申请日：1979-05-09
IPC分类号： C07D251/26
CPC分类号： C07D251/26
摘要： Novel monochloro-s-triazine derivatives of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are independently alkyl or substituted alkyl of 6 to 20 carbon atoms, alkenyl having 6 to 20 carbon atoms, cycloalkyl having 6 carbon atoms, or furfuryl, and which derivatives provide antioxidants and UV stabilizers for polymers such as polyolefins are prepared by reacting an alcohol with cyanuric chloride in the presence of an acid acceptor having a pK.sub.b .ltoreq.3, in an organic solvent which is inert to the reaction components.
摘要翻译： 新型一氯平三嗪衍生物，其分子式为：其中R 1和R 2独立地为具有6至20个碳原子的烷基或取代的烷基，具有6至20个碳原子的烯基，具有6个碳原子的环烷基或糠基， 衍生物为聚合物（例如聚烯烃）提供抗氧化剂和紫外线稳定剂，其通过在具有pKb 3的酸受体存在下，使氰基酰氯与氰尿酰氯反应，在对反应组分呈惰性的有机溶剂中反应。
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公开(公告)号：US4204060A
公开(公告)日：1980-05-20
申请号：US818371
申请日：1977-07-25
IPC分类号： C07D251/26
CPC分类号： C07D251/26
摘要： Novel monochloro-s-triazine derivatives of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are independently alkyl or substituted alkyl of 6 to 20 carbon atoms, alkenyl having 6 to 20 carbon atoms, cycloalkyl having 6 carbon atoms, or furfuryl, and which derivatives provide antioxidants and UV stabilizers for polymers such as polyolefins are prepared by reacting an alcohol with cyanuric chloride in the presence of an acid acceptor having a pK.sub.b .ltoreq.3, in an organic solvent which is inert to the reaction components.
摘要翻译： 新型一氯平三嗪衍生物，其分子式为：其中R 1和R 2独立地为具有6至20个碳原子的烷基或取代的烷基，具有6至20个碳原子的烯基，具有6个碳原子的环烷基或糠基， 衍生物为聚合物（例如聚烯烃）提供抗氧化剂和紫外线稳定剂，其通过在具有pKb 3的酸受体存在下，使氰基酰氯与氰尿酰氯反应，在对反应组分呈惰性的有机溶剂中反应。
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