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公开(公告)号：US4772679A
公开(公告)日：1988-09-20
申请号：US808502
申请日：1985-12-13
申请人： Isaburo Fukawa , Haruyuki Yoneda , Hisaya Sakurai
发明人： Isaburo Fukawa , Haruyuki Yoneda , Hisaya Sakurai
CPC分类号： C08G61/127 , C08G75/024 , C08G75/0272
摘要： Crystalline aromatic polyketones having a linear polymer structure comprising repeating units [I] of ##STR1## and repeating units [II] of ##STR2## the repeating units [I] and [II] are bonded alternately, and the polymer has an intrinsic viscosity of at least 0.4, has excellent properties, particularly heat resistance, and can be used as shaped articles, coatings, films, fibers, etc.
摘要翻译： 具有包含重复单元[I]＆lt; IMAGE＆gt;＆gt;和重复单元[II]的重复单元[I]和[II]的线性聚合物结构的结晶芳族聚酮交替键合，聚合物 特性粘度至少为0.4，具有优异的性能，特别是耐热性，可用作成型制品，涂料，薄膜，纤维等。
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公开(公告)号：US4255280A
公开(公告)日：1981-03-10
申请号：US19674
申请日：1979-03-12
CPC分类号： C08F10/00
摘要： Catalysts for polymerization of olefin which comprise a solid catalyst component (A) and an organometallic compound with a heterocyclic carboxylic acid ester (B), wherein the solid catalyst component (A) is obtained by reacting or/and grinding an organomagnesium compound (1), of the formulaM.sub..alpha. Mg.sub..beta. R.sub.p.sup.1 R.sub.q.sup.2 X.sub.rwherein.alpha., p, q and r each independently .gtoreq.0,.beta.>0,p+q+r=m.alpha.+2.beta.M is Al, Zn, B or Be,m is the valence of M,R.sup.1 and R.sup.2 are the same or different hydrocarbon groups having 1-20 carbon atoms, andX is a halogen atom,or of the reaction product of M.sub..alpha. Mg.sub..beta. R.sub.p.sup.1 R.sub.q.sup.2 X.sub.r with an electron donor, with 0.01 to 100 moles of (ii) a chlorosilane compound containing Si-H bonds and of the formulaH.sub.a SiClR.sub.4-(a+b).sup.3wherein0
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公开(公告)号：US4330650A
公开(公告)日：1982-05-18
申请号：US135069
申请日：1980-03-28
CPC分类号： C08F10/00
摘要： Catalysts for polymerization of olefin which comprise a solid catalyst component (A) and an organometallic compound with a heterocyclic carboxylic acid ester (B), wherein the solid catalyst component (A) is obtained by reacting or/and grinding a special magnesium compound (1), a titanium halide (2) and a carboxylic acid ester (3); and the heterocyclic carboxylic acid ester is N-, S- or O-containing heterocyclic compound, and processes for polymerization of olefin employing such a catalyst.
摘要翻译： 用于使包含固体催化剂组分（A）和带有杂环羧酸酯（B）的有机金属化合物的烯烃聚合的催化剂，其中固体催化剂组分（A）通过使特殊的镁化合物（1） ），卤化钛（2）和羧酸酯（3）; 并且杂环羧酸酯是含有N-，S-或O-的杂环化合物，以及使用这种催化剂聚合烯烃的方法。
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4.发明授权Crystalline aromatic polyketone copolymer produced from 4-mercaptophenol, dihaloterephtalophenone, and hydroquinone or dihydroxybenzophenone 失效由4-巯基苯酚，二卤代对苯二酚和氢醌或二羟基二苯甲酮制得的结晶芳族聚酮共聚物
公开(公告)号：US4804735A
公开(公告)日：1989-02-14
申请号：US24031
申请日：1987-03-10
申请人： Isaburo Fukawa , Haruyuki Yoneda
发明人： Isaburo Fukawa , Haruyuki Yoneda
CPC分类号： C08G75/12 , C08G65/4056
摘要： A copolymer which can be employed for various molded articles, particularly for uses which require a high nonflammability, which copolymer is a crystalline aromatic polyketone type copolymer which has an intrinsic viscosity of not less than 0.40 and has a linear polymer structure comprising structural units (A) represented by the formula (A) ##STR1## structural units (B) represented by the formula (B) ##STR2## and structural units (C) represented by the formula (C.sub.1) ##STR3## or by the formula (C.sub.2) ##STR4## the molar ratio of said units (B) to said units (C) being in the range from 30:70 to 99:1, and the unit (A) and either the unit (B) or the unit (C) being linked alternately; and a process producing the same.
摘要翻译： 可用于各种模制品的共聚物，特别是需要高不可燃性的用途，该共聚物是特性粘度不低于0.40并且具有包含结构单元（A）的直链聚合物结构的结晶芳族聚酮型共聚物 ）由式（A）表示的结构单元（B）由式（B）表示的结构单元（B）和由式（C1）或式（C2）表示的结构单元（C） 所述单元（B）与所述单元（C）的摩尔比在30:70至99:1的范围内，单元（A）和单元（B）或单元（C）的摩尔比为 交替交替 及其制造方法。
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公开(公告)号：US4451573A
公开(公告)日：1984-05-29
申请号：US385221
申请日：1982-06-04
CPC分类号： C08F10/00
摘要： A catalyst suitable for use in the polymerization of olefins is disclosed. This catalyst contains:[A] a solid catalyst component obtained by calcining a reaction product of (a) at least one compound selected from an amine compound, a phosphoric acid amide, a hydrocarbyloxy compound of titanium, vanadium, hafnium or zirconium, and a germanium compound having the general formula:R.sup.1 R.sup.2 R.sup.3 R.sup.4 Gewherein (i) R.sup.1, R.sup.2 and R.sup.3 are each independently a hydrocarbon group having 1 through 10 carbon atoms, and R.sup.4 is a hydrogen atom, a halogen atom, a --OH group, or a --OGeR.sup.1 R.sup.2 R.sup.3 group, or (ii) R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently --OR.sup.5 wherein R.sup.5 is a hydrocarbon group having 1 through 10 carbon atoms, or a halogen atom, and a tin compound having the general formula:R.sup.1 R.sup.2 R.sup.3 R.sup.6 Snwherein R.sup.1, R.sup.2 and R.sup.3 are the same as defined above and R.sup.6 is a halogen atom, or --OH group, with (b) at least one chromium compound, said reaction product being supported on an inorganic oxide carrier; and[B] an organometallic compound component.
摘要翻译： 公开了一种适用于烯烃聚合的催化剂。 该催化剂含有：[A]通过煅烧（a）至少一种选自胺化合物，磷酸酰胺，钛，钒，铪或锆的烃氧基化合物的化合物和 具有以下通式的锗化合物：R1R2R3R4Ge其中（i）R1，R2和R3各自独立地为具有1至10个碳原子的烃基，R4为氢原子，卤素原子，-OH基团或-OGeR1R2R3 基团，或（ii）R 1，R 2，R 3和R 4各自独立地为-OR 5，其中R 5为具有1至10个碳原子的烃基或卤素原子，以及具有以下通式的锡化合物：R1R2R3R6Sn其中R1，R2 和R 3与上述定义相同，R 6为卤原子或-OH基团，（b）至少一种铬化合物，所述反应产物负载在无机氧化物载体上; 和[B]有机金属化合物组分。
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6.发明授权
公开(公告)号：US5225526A
公开(公告)日：1993-07-06
申请号：US667398
申请日：1991-03-29
申请人： Isaburo Fukawa , Haruyuki Yoneda , Hiroshi Hachiya
发明人： Isaburo Fukawa , Haruyuki Yoneda , Hiroshi Hachiya
摘要： The present invention relates to an aromatic polycarbonate composition which is stabilized by adding to an aromatic polycarbonate (containing substantially no chlorine atom) a very slight amount of at least one compound selected from a phosphorous acid diester and a phosphorous acid monoester and at least one compound selected from a phenolic antioxidant, a phosphorous acid triester and an organic phosphonite. This composition has the characteristics that molded products made therefrom are superior in hot-water resistance and steam resistance and recycling molding thereof causes substantially no coloration. Thus, this composition is high in industrial applicability.
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公开(公告)号：US4312783A
公开(公告)日：1982-01-26
申请号：US169234
申请日：1980-07-16
CPC分类号： C08F10/00
摘要： A catalyst comprising (A) a solid catalyst component obtained by reacting a titanium compound having a hydrocarbyloxy group with an organoaluminum compound in the presence of an ether to give a liquid material or to give a solid titanium component (a) which is solubilized by addition of a tetravalent titanium halide with or without an ether without separation or after separation from the reaction mixture, and heat treating the liquid material at a temperature of 70.degree. to 180.degree. C. with or without addition of a tetravalent titanium halide, and (B) an organoaluminum compound is effective for polymerization or copolymerization of olefins with high stereoregularity and has high polymerization activity.
摘要翻译： 一种催化剂，其包含（A）通过使具有烃氧基的钛化合物与有机铝化合物在醚存在下反应而获得的固体催化剂组分，得到液体材料或得到通过加成溶解的固体钛组分（a） 的四价钛卤化物，无需分离或不与反应混合物分离，并在70℃至180℃的温度下加热或不加入四价卤化钛，和（B ）有机铝化合物对于具有高立构规整性的烯烃的聚合或共聚有效，并且具有高聚合活性。
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